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Title: Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1383955
DOE Contract Number:  
ERKCC61
Resource Type:
Journal Article
Journal Name:
Microscopy and Microanalysis
Additional Journal Information:
Journal Volume: 20; Journal Issue: 04; Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia; Journal ID: ISSN 1431-9276
Publisher:
Microscopy Society of America (MSA)
Country of Publication:
United States
Language:
English
Subject:
catalysis (heterogeneous), solar (fuels), energy storage (including batteries and capacitors), hydrogen and fuel cells, electrodes - solar, mechanical behavior, charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Unocic, Raymond R., Sun, Xiao-Guang, Sacci, Robert L., Adamczyk, Leslie A., Alsem, Daan Hein, Dai, Sheng, Dudney, Nancy J., and More, Karren L. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy. United States: N. p., 2014. Web. doi:10.1017/S1431927614012744.
Unocic, Raymond R., Sun, Xiao-Guang, Sacci, Robert L., Adamczyk, Leslie A., Alsem, Daan Hein, Dai, Sheng, Dudney, Nancy J., & More, Karren L. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy. United States. doi:10.1017/S1431927614012744.
Unocic, Raymond R., Sun, Xiao-Guang, Sacci, Robert L., Adamczyk, Leslie A., Alsem, Daan Hein, Dai, Sheng, Dudney, Nancy J., and More, Karren L. Fri . "Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy". United States. doi:10.1017/S1431927614012744.
@article{osti_1383955,
title = {Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy},
author = {Unocic, Raymond R. and Sun, Xiao-Guang and Sacci, Robert L. and Adamczyk, Leslie A. and Alsem, Daan Hein and Dai, Sheng and Dudney, Nancy J. and More, Karren L.},
abstractNote = {},
doi = {10.1017/S1431927614012744},
journal = {Microscopy and Microanalysis},
issn = {1431-9276},
number = 04,
volume = 20,
place = {United States},
year = {2014},
month = {7}
}

Works referenced in this record:

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010


Electron microscopy of specimens in liquid
journal, October 2011

  • de Jonge, Niels; Ross, Frances M.
  • Nature Nanotechnology, Vol. 6, Issue 11, p. 695-704
  • DOI: 10.1038/nnano.2011.161

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes
journal, January 1997

  • Peled, E.
  • Journal of The Electrochemical Society, Vol. 144, Issue 8
  • DOI: 10.1149/1.1837858

In Situ Observation of Solid Electrolyte Interphase Formation in Ordered Mesoporous Hard Carbon by Small-Angle Neutron Scattering
journal, March 2012

  • Bridges, Craig A.; Sun, Xiao-Guang; Zhao, Jinkui
  • The Journal of Physical Chemistry C, Vol. 116, Issue 14
  • DOI: 10.1021/jp3012393

Controlled Growth of Nanoparticles from Solution with In Situ Liquid Transmission Electron Microscopy
journal, July 2011

  • Evans, James E.; Jungjohann, Katherine L.; Browning, Nigel D.
  • Nano Letters, Vol. 11, Issue 7
  • DOI: 10.1021/nl201166k

Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories
journal, June 2009


A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries
journal, January 1999

  • Bar-Tow, D.
  • Journal of The Electrochemical Society, Vol. 146, Issue 3
  • DOI: 10.1149/1.1391688

Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents
journal, January 2009

  • Tasaki, Ken; Goldberg, Alex; Lian, Jian-Jie
  • Journal of The Electrochemical Society, Vol. 156, Issue 12
  • DOI: 10.1149/1.3239850

Direct visualization of initial SEI morphology and growth kinetics during lithium deposition by in situ electrochemical transmission electron microscopy
journal, January 2014

  • Sacci, Robert L.; Dudney, Nancy J.; More, Karren L.
  • Chemical Communications, Vol. 50, Issue 17
  • DOI: 10.1039/c3cc49029g

Electron microscopy of whole cells in liquid with nanometer resolution
journal, January 2009

  • Jonge, N. d.; Peckys, D. B.; Kremers, G. J.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 7
  • DOI: 10.1073/pnas.0809567106

Chemical Distribution and Bonding of Lithium in Intercalated Graphite: Identification with Optimized Electron Energy Loss Spectroscopy
journal, January 2011

  • Wang, Feng; Graetz, Jason; Moreno, M. Sergio
  • ACS Nano, Vol. 5, Issue 2
  • DOI: 10.1021/nn1028168

Quantifying Electrochemical Nucleation and Growth of Nanoscale Clusters Using Real-Time Kinetic Data
journal, February 2006

  • Radisic, Aleksandar; Vereecken, Philippe M.; Hannon, James B.
  • Nano Letters, Vol. 6, Issue 2
  • DOI: 10.1021/nl052175i

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
journal, September 1999


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry
journal, May 2012

  • Owejan, Jeanette E.; Owejan, Jon P.; DeCaluwe, Steven C.
  • Chemistry of Materials, Vol. 24, Issue 11
  • DOI: 10.1021/cm3006887

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


Dynamic microscopy of nanoscale cluster growth at the solid–liquid interface
journal, July 2003

  • Williamson, M. J.; Tromp, R. M.; Vereecken, P. M.
  • Nature Materials, Vol. 2, Issue 8
  • DOI: 10.1038/nmat944

In Situ Transmission Electron Microscopy of Lead Dendrites and Lead Ions in Aqueous Solution
journal, June 2012

  • White, Edward R.; Singer, Scott B.; Augustyn, Veronica
  • ACS Nano, Vol. 6, Issue 7
  • DOI: 10.1021/nn3017469

Main aging mechanisms in Li ion batteries
journal, August 2005


Visualization of Electrode–Electrolyte Interfaces in LiPF 6 /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM
journal, March 2014

  • Zeng, Zhiyuan; Liang, Wen-I; Liao, Hong-Gang
  • Nano Letters, Vol. 14, Issue 4
  • DOI: 10.1021/nl403922u

Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells
journal, January 1990

  • Fong, Rosamaría
  • Journal of The Electrochemical Society, Vol. 137, Issue 7
  • DOI: 10.1149/1.2086855

Electrochemical SPM investigation of the solid electrolyte interphase film formed on HOPG electrodes
journal, June 2000