Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

Unocic, Raymond R.; Sun, Xiao-Guang; Sacci, Robert L.; Adamczyk, Leslie A.; Alsem, Daan Hein; Dai, Sheng; Dudney, Nancy J.; More, Karren L.

doi:10.1017/S1431927614012744

Title: Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

Journal Article · Fri Jul 04 00:00:00 EDT 2014 · Microscopy and Microanalysis

DOI:https://doi.org/10.1017/S1431927614012744· OSTI ID:1383955

Unocic, Raymond R.; Sun, Xiao-Guang; Sacci, Robert L.; Adamczyk, Leslie A.; Alsem, Daan Hein; Dai, Sheng; Dudney, Nancy J.; More, Karren L.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: ERKCC61

OSTI ID:: 1383955

Journal Information:: Microscopy and Microanalysis, Vol. 20, Issue 04; Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia; ISSN 1431-9276

Publisher:: Microscopy Society of America (MSA)

Country of Publication:: United States

Language:: English

References (31)

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries Verma, Pallavi; Maire, Pascal; Novák, Petr Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341 https://doi.org/10.1016/j.electacta.2010.05.072	journal	September 2010
Electron microscopy of specimens in liquid de Jonge, Niels; Ross, Frances M. Nature Nanotechnology, Vol. 6, Issue 11, p. 695-704 https://doi.org/10.1038/nnano.2011.161	journal	October 2011
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions Aurbach, D. Solid State Ionics, Vol. 148, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00080-2	journal	June 2002
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes Peled, E. Journal of The Electrochemical Society, Vol. 144, Issue 8 https://doi.org/10.1149/1.1837858	journal	January 1997
In Situ Observation of Solid Electrolyte Interphase Formation in Ordered Mesoporous Hard Carbon by Small-Angle Neutron Scattering Bridges, Craig A.; Sun, Xiao-Guang; Zhao, Jinkui The Journal of Physical Chemistry C, Vol. 116, Issue 14 https://doi.org/10.1021/jp3012393	journal	March 2012
Controlled Growth of Nanoparticles from Solution with In Situ Liquid Transmission Electron Microscopy Evans, James E.; Jungjohann, Katherine L.; Browning, Nigel D. Nano Letters, Vol. 11, Issue 7 https://doi.org/10.1021/nl201166k	journal	July 2011
Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories Zheng, H.; Smith, R. K.; Jun, Y. -w. Science, Vol. 324, Issue 5932 https://doi.org/10.1126/science.1172104	journal	June 2009
A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries Bar-Tow, D. Journal of The Electrochemical Society, Vol. 146, Issue 3 https://doi.org/10.1149/1.1391688	journal	January 1999
Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents Tasaki, Ken; Goldberg, Alex; Lian, Jian-Jie Journal of The Electrochemical Society, Vol. 156, Issue 12 https://doi.org/10.1149/1.3239850	journal	January 2009
Direct visualization of initial SEI morphology and growth kinetics during lithium deposition by in situ electrochemical transmission electron microscopy Sacci, Robert L.; Dudney, Nancy J.; More, Karren L. Chemical Communications, Vol. 50, Issue 17 https://doi.org/10.1039/c3cc49029g	journal	January 2014
Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes Gu, Meng; Parent, Lucas R.; Mehdi, B. Layla Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl403402q	journal	November 2013
Electron microscopy of whole cells in liquid with nanometer resolution Jonge, N. d.; Peckys, D. B.; Kremers, G. J. Proceedings of the National Academy of Sciences, Vol. 106, Issue 7 https://doi.org/10.1073/pnas.0809567106	journal	January 2009
Chemical Distribution and Bonding of Lithium in Intercalated Graphite: Identification with Optimized Electron Energy Loss Spectroscopy Wang, Feng; Graetz, Jason; Moreno, M. Sergio ACS Nano, Vol. 5, Issue 2 https://doi.org/10.1021/nn1028168	journal	January 2011
Quantifying Electrochemical Nucleation and Growth of Nanoscale Clusters Using Real-Time Kinetic Data Radisic, Aleksandar; Vereecken, Philippe M.; Hannon, James B. Nano Letters, Vol. 6, Issue 2 https://doi.org/10.1021/nl052175i	journal	February 2006
On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries Aurbach, D.; Markovsky, B.; Weissman, I. Electrochimica Acta, Vol. 45, Issue 1-2 https://doi.org/10.1016/S0013-4686(99)00194-2	journal	September 1999
Correlation between surface chemistry, morphology, cycling efficiency and interfacial properties of Li electrodes in solutions containing different Li salts Aurbach, D.; Weissman, I.; Zaban, A. Electrochimica Acta, Vol. 39, Issue 1 https://doi.org/10.1016/0013-4686(94)85010-0	journal	January 1994
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
In Situ Transmission Electron Microscopy Observation of Microstructure and Phase Evolution in a SnO ₂ Nanowire during Lithium Intercalation Wang, Chong-Min; Xu, Wu; Liu, Jun Nano Letters, Vol. 11, Issue 5 https://doi.org/10.1021/nl200272n	journal	May 2011
Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry Owejan, Jeanette E.; Owejan, Jon P.; DeCaluwe, Steven C. Chemistry of Materials, Vol. 24, Issue 11 https://doi.org/10.1021/cm3006887	journal	May 2012
The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries Aurbach, Doron Journal of The Electrochemical Society, Vol. 141, Issue 3 https://doi.org/10.1149/1.2054777	journal	January 1994
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
In situ electrochemical wet cell transmission electron microscopy characterization of solid–liquid interactions between Ni and aqueous NiCl2 Chen, X.; Noh, K. W.; Wen, J. G. Acta Materialia, Vol. 60, Issue 1 https://doi.org/10.1016/j.actamat.2011.09.047	journal	January 2012
Dynamic microscopy of nanoscale cluster growth at the solid–liquid interface Williamson, M. J.; Tromp, R. M.; Vereecken, P. M. Nature Materials, Vol. 2, Issue 8 https://doi.org/10.1038/nmat944	journal	July 2003
In Situ Transmission Electron Microscopy of Lead Dendrites and Lead Ions in Aqueous Solution White, Edward R.; Singer, Scott B.; Augustyn, Veronica ACS Nano, Vol. 6, Issue 7 https://doi.org/10.1021/nn3017469	journal	June 2012
Main aging mechanisms in Li ion batteries Broussely, M.; Biensan, Ph.; Bonhomme, F. Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.172	journal	August 2005
Visualization of Electrode–Electrolyte Interfaces in LiPF ₆ /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM Zeng, Zhiyuan; Liang, Wen-I; Liao, Hong-Gang Nano Letters, Vol. 14, Issue 4 https://doi.org/10.1021/nl403922u	journal	March 2014
Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells Fong, Rosamaría Journal of The Electrochemical Society, Vol. 137, Issue 7 https://doi.org/10.1149/1.2086855	journal	January 1990
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model Peled, E. Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128859	journal	January 1979
Electrochemical SPM investigation of the solid electrolyte interphase film formed on HOPG electrodes Alliata, D. Electrochemistry Communications, Vol. 2, Issue 6 https://doi.org/10.1016/S1388-2481(00)00056-4	journal	June 2000

Similar Records

Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

Journal Article · Fri Jul 04 00:00:00 EDT 2014 · Microsc Microanal · OSTI ID:1383955

Unocic, R. R.; Sun, X-G.; Sacci, Robert L.; +5 more

Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

Journal Article · Fri Aug 01 00:00:00 EDT 2014 · Microscopy and Microanalysis · OSTI ID:1383955

Unocic, Raymond R.; Sun, Xiao-Guang; Sacci, Robert L.; +5 more

Direct Visualization of Initial SEI Morphology and Growth Kinetics During Lithium Deposition by in situ Electrochemical Transmission Electron Microscopy

Journal Article · Wed Jan 01 00:00:00 EST 2014 · ChemComm · OSTI ID:1383955

Sacci, Robert L.; Dudney, Nancy; More, Karren; +4 more

Related Subjects

catalysis (heterogeneous)
solar (fuels)
energy storage (including batteries and capacitors)
hydrogen and fuel cells
electrodes - solar
mechanical behavior
charge transport
materials and chemistry by design
synthesis (novel materials)

Title: Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

Citation Formats

References (31)

Similar Records

Related Subjects