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Title: Synthesis and reactivity of molybdenum and tungsten bis(dinitrogen) complexes supported by diphosphine chelates containing pendant amines

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/c2dt12224c· OSTI ID:1383893
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Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1383893
Journal Information:
Dalton Transactions, Vol. 41, Issue 15; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming; ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (36)

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A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia journal December 2010
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Catalytic reduction of dinitrogen to ammonia at a single molybdenum center journal November 2006
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Spectroscopic and chemical properties of nitrogen-15-enriched molybdenum dinitrogen complexes trans,mer-Mo(N2)2(L)(PMePh2)3 journal October 1986
Improved Electrochemistry in Low-Polarity Media Using Tetrakis(pentafluorophenyl)borate Salts as Supporting Electrolytes journal January 2000
A rare terminal dinitrogen complex of chromium journal January 2011
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[Ni(Et 2 PCH 2 NMeCH 2 PEt 2 ) 2 ] 2+ as a Functional Model for Hydrogenases journal January 2003
STRUCTURE: Nitrogenase Reveals Its Inner Secrets journal September 2002
Catalytic Synthesis of Ammonia—A “Never-Ending Story”? journal May 2003
Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation journal December 2009
The mechanism of formation of hydrazido(2—)- and hydrido-complexes by the reaction of dinitrogen complexes with acids in tetrahydrofuran journal January 1982
Mechanism of Molybdenum Nitrogenase journal January 1996
Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis journal August 2008
Improved Preparations of Molybdenum Coordination Compounds from Tetrachlorobis(diethyl ether)molybdenum(IV) journal September 2001
Synthesis, Structures, and Reactions of Manganese Complexes Containing Diphosphine Ligands with Pendant Amines journal October 2010
Mo– and W–N2 and –CO complexes with novel mixed P/N ligands: Structural properties and implications to synthetic nitrogen fixation journal March 2008
[1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate) journal April 2008
A direct one-step preparation of bis(dinitrogen) complexes of molybdenum(0) from molybdenum(V) chloride journal June 1978
Recent Advances in the Chemistry of Dinitrogen Complexes journal June 1995
One-step synthesis of Mo(0) and W(0) bis(dinitrogen) complexes with the linear tetraphosphine ligand prP4: stereoselective formation of cis-[M(N2)2(rac-prP4)] and trans-[M(N2)2(meso-prP4)]; M = Mo, W journal January 2011
Diazenido-complexes of molybdenum and tungsten journal January 1976

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Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
solar (fuels)
bio-inspired
energy storage (including batteries and capacitors)
hydrogen and fuel cells
charge transport
materials and chemistry by design
synthesis (novel materials)