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Title: Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells

Authors:
 [1];  [2];  [2];  [2];  [1];  [2];  [2];  [2];  [2];  [2];  [2];  [1];  [2];  [2]
  1. Department of Materials Science and Engineering and Chemistry and Argonne-Northwestern, Solar Energy Research (ANSER) Center, Northwestern University, 2145 Sheridan Road Evanston IL 60208 USA
  2. Department of Chemistry and Argonne-Northwestern, Solar Energy Research (ANSER) Center, Northwestern University, 2145 Sheridan Road Evanston IL 60208 USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1383488
DOE Contract Number:  
SC0001059
Resource Type:
Journal Article
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 4; Journal Issue: 3; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)

Citation Formats

Zhou, Nanjia, Lin, Hui, Lou, Sylvia J., Yu, Xinge, Guo, Peijun, Manley, Eric F., Loser, Stephen, Hartnett, Patrick, Huang, Hui, Wasielewski, Michael R., Chen, Lin X., Chang, Robert P. H., Facchetti, Antonio, and Marks, Tobin J. Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells. United States: N. p., 2013. Web. doi:10.1002/aenm.201300785.
Zhou, Nanjia, Lin, Hui, Lou, Sylvia J., Yu, Xinge, Guo, Peijun, Manley, Eric F., Loser, Stephen, Hartnett, Patrick, Huang, Hui, Wasielewski, Michael R., Chen, Lin X., Chang, Robert P. H., Facchetti, Antonio, & Marks, Tobin J. Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells. United States. doi:10.1002/aenm.201300785.
Zhou, Nanjia, Lin, Hui, Lou, Sylvia J., Yu, Xinge, Guo, Peijun, Manley, Eric F., Loser, Stephen, Hartnett, Patrick, Huang, Hui, Wasielewski, Michael R., Chen, Lin X., Chang, Robert P. H., Facchetti, Antonio, and Marks, Tobin J. Wed . "Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells". United States. doi:10.1002/aenm.201300785.
@article{osti_1383488,
title = {Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells},
author = {Zhou, Nanjia and Lin, Hui and Lou, Sylvia J. and Yu, Xinge and Guo, Peijun and Manley, Eric F. and Loser, Stephen and Hartnett, Patrick and Huang, Hui and Wasielewski, Michael R. and Chen, Lin X. and Chang, Robert P. H. and Facchetti, Antonio and Marks, Tobin J.},
abstractNote = {},
doi = {10.1002/aenm.201300785},
journal = {Advanced Energy Materials},
issn = {1614-6832},
number = 3,
volume = 4,
place = {United States},
year = {2013},
month = {10}
}

Works referenced in this record:

Solar cell fill factors: General graph and empirical expressions
journal, August 1981


Conjugated-Polymer Blends for Optoelectronics
journal, October 2009

  • McNeill, Christopher R.; Greenham, Neil C.
  • Advanced Materials, Vol. 21, Issue 38–39
  • DOI: 10.1002/adma.200900783

A high-mobility electron-transporting polymer for printed transistors
journal, January 2009

  • Yan, He; Chen, Zhihua; Zheng, Yan
  • Nature, Vol. 457, Issue 7230, p. 679-686
  • DOI: 10.1038/nature07727

High-Efficiency Polymer Solar Cells Enhanced by Solvent Treatment
journal, January 2013

  • Zhou, Huiqiong; Zhang, Yuan; Seifter, Jason
  • Advanced Materials, Vol. 25, Issue 11
  • DOI: 10.1002/adma.201204306

Solar Cell Efficiency, Self-Assembly, and Dipole–Dipole Interactions of Isomorphic Narrow-Band-Gap Molecules
journal, September 2012

  • Takacs, Christopher J.; Sun, Yanming; Welch, Gregory C.
  • Journal of the American Chemical Society, Vol. 134, Issue 40
  • DOI: 10.1021/ja3050713

All-Polymer Photovoltaic Devices of Poly(3-(4- n -octyl)-phenylthiophene) from Grignard Metathesis (GRIM) Polymerization
journal, October 2009

  • Holcombe, Thomas W.; Woo, Claire H.; Kavulak, David F. J.
  • Journal of the American Chemical Society, Vol. 131, Issue 40
  • DOI: 10.1021/ja9059359

Efficient photovoltaic cells from semiconducting polymer heterojunctions
journal, October 2000

  • Jenekhe, Samson A.; Yi, Shujian
  • Applied Physics Letters, Vol. 77, Issue 17
  • DOI: 10.1063/1.1320022

Polymer/Polymer Blend Solar Cells Improved by Using High-Molecular-Weight Fluorene-Based Copolymer as Electron Acceptor
journal, June 2012

  • Mori, Daisuke; Benten, Hiroaki; Ohkita, Hideo
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 7, p. 3325-3329
  • DOI: 10.1021/am300623f

Small-Molecule, Nonfullerene Acceptors for Polymer Bulk Heterojunction Organic Photovoltaics
journal, February 2011

  • Anthony, John E.
  • Chemistry of Materials, Vol. 23, Issue 3, p. 583-590
  • DOI: 10.1021/cm1023019

Conjugated Polymer-Based Organic Solar Cells
journal, April 2007

  • Günes, Serap; Neugebauer, Helmut; Sariciftci, Niyazi Serdar
  • Chemical Reviews, Vol. 107, Issue 4, p. 1324-1338
  • DOI: 10.1021/cr050149z

Polymer–Fullerene Composite Solar Cells
journal, January 2008

  • Thompson, Barry C.; Fréchet, Jean M. J.
  • Angewandte Chemie International Edition, Vol. 47, Issue 1, p. 58-77
  • DOI: 10.1002/anie.200702506

n-Type Naphthalene Diimide–Biselenophene Copolymer for All-Polymer Bulk Heterojunction Solar Cells
journal, November 2012

  • Hwang, Ye-Jin; Ren, Guoqiang; Murari, Nishit M.
  • Macromolecules, Vol. 45, Issue 22
  • DOI: 10.1021/ma3020239

The dedicated high-resolution grazing-incidence X-ray scattering beamline 8-ID-E at the Advanced Photon Source
journal, June 2012

  • Jiang, Zhang; Li, Xuefa; Strzalka, Joseph
  • Journal of Synchrotron Radiation, Vol. 19, Issue 4
  • DOI: 10.1107/S0909049512022017

Fabrication and processing of polymer solar cells: A review of printing and coating techniques
journal, April 2009


Morphology of all-polymer solar cells
journal, January 2012

  • McNeill, Christopher R.
  • Energy & Environmental Science, Vol. 5, Issue 2
  • DOI: 10.1039/c2ee03071c

Molecular Order in High-Efficiency Polymer/Fullerene Bulk Heterojunction Solar Cells
journal, September 2011

  • Hammond, Matthew R.; Kline, R. Joseph; Herzing, Andrew A.
  • ACS Nano, Vol. 5, Issue 10
  • DOI: 10.1021/nn202951e

Bithiophene Imide and Benzodithiophene Copolymers for Efficient Inverted Polymer Solar Cells
journal, March 2012

  • Zhou, Nanjia; Guo, Xugang; Ortiz, Rocio Ponce
  • Advanced Materials, Vol. 24, Issue 17, p. 2242-2248
  • DOI: 10.1002/adma.201103948

Light-emitting diodes with variable colours from polymer blends
journal, December 1994

  • Berggren, M.; Inganäs, O.; Gustafsson, G.
  • Nature, Vol. 372, Issue 6505
  • DOI: 10.1038/372444a0

Influence of Aggregation on the Performance of All-Polymer Solar Cells Containing Low-Bandgap Naphthalenediimide Copolymers
journal, January 2012

  • Schubert, Marcel; Dolfen, Daniel; Frisch, Johannes
  • Advanced Energy Materials, Vol. 2, Issue 3
  • DOI: 10.1002/aenm.201100601

Polymer solar cells with enhanced fill factors
journal, August 2013


Correlating the Efficiency and Nanomorphology of Polymer Blend Solar Cells Utilizing Resonant Soft X-ray Scattering
journal, December 2011

  • Yan, Hongping; Collins, Brian A.; Gann, Eliot
  • ACS Nano, Vol. 6, Issue 1
  • DOI: 10.1021/nn204150f

Effect of traps on the performance of bulk heterojunction organic solar cells
journal, December 2007

  • Mandoc, M. M.; Kooistra, F. B.; Hummelen, J. C.
  • Applied Physics Letters, Vol. 91, Issue 26
  • DOI: 10.1063/1.2821368

Recombination in polymer-fullerene bulk heterojunction solar cells
journal, December 2010


Inverted Polymer Solar Cells Integrated with a Low-Temperature-Annealed Sol-Gel-Derived ZnO Film as an Electron Transport Layer
journal, February 2011

  • Sun, Yanming; Seo, Jung Hwa; Takacs, Christopher J.
  • Advanced Materials, Vol. 23, Issue 14, p. 1679-1683
  • DOI: 10.1002/adma.201004301

Efficient Solution-Processed Small-Molecule Solar Cells with Inverted Structure
journal, March 2013

  • Kyaw, Aung Ko Ko; Wang, Dong Hwan; Gupta, Vinay
  • Advanced Materials, Vol. 25, Issue 17
  • DOI: 10.1002/adma.201300295

Modeling geminate pair dissociation in organic solar cells: high power conversion efficiencies achieved with moderate optical bandgaps
journal, January 2012

  • Servaites, Jonathan D.; Savoie, Brett M.; Brink, Joseph B.
  • Energy & Environmental Science, Vol. 5, Issue 8
  • DOI: 10.1039/c2ee21376a

Efficient photodiodes from interpenetrating polymer networks
journal, August 1995

  • Halls, J. J. M.; Walsh, C. A.; Greenham, N. C.
  • Nature, Vol. 376, Issue 6540, p. 498-500
  • DOI: 10.1038/376498a0

Two‐layer organic photovoltaic cell
journal, January 1986

  • Tang, C. W.
  • Applied Physics Letters, Vol. 48, Issue 2
  • DOI: 10.1063/1.96937

Solution-processed small-molecule solar cells with 6.7% efficiency
journal, November 2011

  • Sun, Yanming; Welch, Gregory C.; Leong, Wei Lin
  • Nature Materials, Vol. 11, Issue 1, p. 44-48
  • DOI: 10.1038/nmat3160

Origin of the Reduced Fill Factor and Photocurrent in MDMO-PPV:PCNEPV All-Polymer Solar Cells
journal, July 2007

  • Mandoc, M. M.; Veurman, W.; Koster, L. J. A.
  • Advanced Functional Materials, Vol. 17, Issue 13
  • DOI: 10.1002/adfm.200601110

Theory of space-charge-limited current enhanced by Frenkel effect
journal, February 1970


All-polymer solar cells utilizing low band gap polymers as donor and acceptor
journal, December 2012

  • Tang, Yaqi; McNeill, Christopher R.
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 6
  • DOI: 10.1002/polb.23233

Charge extraction analysis of charge carrier densities in a polythiophene/fullerene solar cell: Analysis of the origin of the device dark current
journal, November 2008

  • Shuttle, C. G.; Maurano, A.; Hamilton, R.
  • Applied Physics Letters, Vol. 93, Issue 18
  • DOI: 10.1063/1.3006316

For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4%
journal, May 2010

  • Liang, Yongye; Xu, Zheng; Xia, Jiangbin
  • Advanced Materials, Vol. 22, Issue 20, p. E135-E138
  • DOI: 10.1002/adma.200903528

Non-Basic High-Performance Molecules for Solution-Processed Organic Solar Cells
journal, June 2012

  • van der Poll, Thomas S.; Love, John A.; Nguyen, Thuc-Quyen
  • Advanced Materials, Vol. 24, Issue 27
  • DOI: 10.1002/adma.201201127

High-efficiency inverted dithienogermole–thienopyrrolodione-based polymer solar cells
journal, December 2011

  • Small, Cephas E.; Chen, Song; Subbiah, Jegadesan
  • Nature Photonics, Vol. 6, Issue 2, p. 115-120
  • DOI: 10.1038/nphoton.2011.317

Polymer donor–polymer acceptor (all-polymer) solar cells
journal, April 2013


Scherrer grain-size analysis adapted to grazing-incidence scattering with area detectors
journal, October 2009


Efficient Polythiophene/Polyfluorene Copolymer Bulk Heterojunction Photovoltaic Devices: Device Physics and Annealing Effects
journal, August 2008

  • McNeill, Christopher R.; Halls, Jonathan J. M.; Wilson, Richard
  • Advanced Functional Materials, Vol. 18, Issue 16
  • DOI: 10.1002/adfm.200800182