skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks with Fluorite Topology

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1383274
DOE Contract Number:  
SC0001015
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 53; Journal Issue: 3; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Zhang, Muwei, Chen, Ying-Pin, Bosch, Mathieu, Gentle, Thomas, Wang, Kecheng, Feng, Dawei, Wang, Zhiyong U., and Zhou, Hong-Cai. Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks with Fluorite Topology. United States: N. p., 2013. Web. doi:10.1002/anie.201307340.
Zhang, Muwei, Chen, Ying-Pin, Bosch, Mathieu, Gentle, Thomas, Wang, Kecheng, Feng, Dawei, Wang, Zhiyong U., & Zhou, Hong-Cai. Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks with Fluorite Topology. United States. doi:10.1002/anie.201307340.
Zhang, Muwei, Chen, Ying-Pin, Bosch, Mathieu, Gentle, Thomas, Wang, Kecheng, Feng, Dawei, Wang, Zhiyong U., and Zhou, Hong-Cai. Mon . "Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks with Fluorite Topology". United States. doi:10.1002/anie.201307340.
@article{osti_1383274,
title = {Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks with Fluorite Topology},
author = {Zhang, Muwei and Chen, Ying-Pin and Bosch, Mathieu and Gentle, Thomas and Wang, Kecheng and Feng, Dawei and Wang, Zhiyong U. and Zhou, Hong-Cai},
abstractNote = {},
doi = {10.1002/anie.201307340},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 3,
volume = 53,
place = {United States},
year = {2013},
month = {11}
}

Works referenced in this record:

High capacity gas storage by a 4,8-connected metal–organic polyhedral framework
journal, January 2011

  • Tan, Chenrong; Yang, Sihai; Champness, Neil R.
  • Chemical Communications, Vol. 47, Issue 15
  • DOI: 10.1039/c1cc10378d

A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives
journal, March 2009


Structure and Charge Control in Metal-Organic Frameworks Based on the Tetrahedral Ligand Tetrakis(4-tetrazolylphenyl)methane
journal, November 2008

  • Dincǎ, Mircea; Dailly, Anne; Long, Jeffrey R.
  • Chemistry - A European Journal, Vol. 14, Issue 33
  • DOI: 10.1002/chem.200801336

Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals
journal, May 2011

  • Schaate, Andreas; Roy, Pascal; Godt, Adelheid
  • Chemistry - A European Journal, Vol. 17, Issue 24
  • DOI: 10.1002/chem.201003211

Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging
journal, December 2009

  • Horcajada, Patricia; Chalati, Tamim; Serre, Christian
  • Nature Materials, Vol. 9, Issue 2
  • DOI: 10.1038/nmat2608

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

  • Morris, William; Volosskiy, Boris; Demir, Selcuk
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
  • DOI: 10.1021/ic300825s

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012


Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures
journal, August 2001

  • Kim, Jaheon; Chen, Banglin; Reineke, Theresa M.
  • Journal of the American Chemical Society, Vol. 123, Issue 34, p. 8239-8247
  • DOI: 10.1021/ja010825o

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010


An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
journal, June 2010

  • Yuan, Daqiang; Zhao, Dan; Sun, Daofeng
  • Angewandte Chemie International Edition, Vol. 49, Issue 31, p. 5357-5361
  • DOI: 10.1002/anie.201001009

Tuning the Topology and Functionality of Metal−Organic Frameworks by Ligand Design
journal, February 2011

  • Zhao, Dan; Timmons, Daren J.; Yuan, Daqiang
  • Accounts of Chemical Research, Vol. 44, Issue 2
  • DOI: 10.1021/ar100112y

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
journal, June 2005

  • Wu, Chuan-De; Hu, Aiguo; Zhang, Lin
  • Journal of the American Chemical Society, Vol. 127, Issue 25
  • DOI: 10.1021/ja052431t

A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core
journal, March 2010

  • Stylianou, Kyriakos C.; Heck, Romain; Chong, Samantha Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4119-4130
  • DOI: 10.1021/ja906041f

Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4-Connected Metal-Organic Frameworks
journal, November 2009


Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

  • Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
  • Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456
  • DOI: 10.1002/ange.201204475

Metal–Organic Replica of Fluorite Built with an Eight-Connecting Tetranuclear Cadmium Cluster and a Tetrahedral Four-Connecting Ligand
journal, February 2004

  • Chun, Hyungphil; Kim, Dongwoo; Dybtsev, Danil N.
  • Angewandte Chemie International Edition, Vol. 43, Issue 8
  • DOI: 10.1002/anie.200353139

Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites
journal, September 2011

  • Bloch, Eric D.; Murray, Leslie J.; Queen, Wendy L.
  • Journal of the American Chemical Society, Vol. 133, Issue 37
  • DOI: 10.1021/ja205976v

Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate)
journal, November 2000

  • Chen, Banglin; Eddaoudi, M.; Reineke, T. M.
  • Journal of the American Chemical Society, Vol. 122, Issue 46, p. 11559-11560
  • DOI: 10.1021/ja003159k

Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal–Organic Frameworks
journal, August 2012

  • Jiang, Hai-Long; Feng, Dawei; Liu, Tian-Fu
  • Journal of the American Chemical Society, Vol. 134, Issue 36
  • DOI: 10.1021/ja3063919

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
  • DOI: 10.1021/ja8057953

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives
journal, January 2009

  • Lan, Anjian; Li, Kunhao; Wu, Haohan
  • Angewandte Chemie International Edition, Vol. 48, Issue 13, p. 2334-2338
  • DOI: 10.1002/anie.200804853

Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4-Connected Metal–Organic Frameworks
journal, December 2009

  • Ma, Liqing; Jin, Athena; Xie, Zhigang
  • Angewandte Chemie International Edition, Vol. 48, Issue 52
  • DOI: 10.1002/anie.200904983

Mixed-Linker Hybrid Superpolyhedra for the Production of a Series of Large-Pore Iron(III) Carboxylate Metal-Organic Frameworks
journal, April 2013

  • Chevreau, Hubert; Devic, Thomas; Salles, Fabrice
  • Angewandte Chemie International Edition, Vol. 52, Issue 19
  • DOI: 10.1002/anie.201300057

Single-crystal structure validation with the program PLATON
journal, January 2003


Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012

  • Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon
  • Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021
  • DOI: 10.1021/ja3055639

Fluorite Topology in Lanthanoid Coordination Polymers with Di- and Trimetallic Building Blocks
journal, August 2012

  • Gotthardt, Jan M.; White, Keith F.; Abrahams, Brendan F.
  • Crystal Growth & Design, Vol. 12, Issue 9
  • DOI: 10.1021/cg3006103

Abundance of chemical elements in the continental crust: a new table
journal, August 1964


Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012

  • McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
  • Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
  • DOI: 10.1021/ja300034j

A Porous Coordination Copolymer with over 5000 m 2 /g BET Surface Area
journal, April 2009

  • Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 131, Issue 12
  • DOI: 10.1021/ja809985t

Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)
journal, July 2013

  • Batten, Stuart R.; Champness, Neil R.; Chen, Xiao-Ming
  • Pure and Applied Chemistry, Vol. 85, Issue 8
  • DOI: 10.1351/PAC-REC-12-11-20

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

  • Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
  • Angewandte Chemie International Edition, Vol. 51, Issue 41
  • DOI: 10.1002/anie.201204475

Low-Energy Selective Capture of Carbon Dioxide by a Pre-designed Elastic Single-Molecule Trap
journal, September 2012

  • Wriedt, Mario; Sculley, Julian P.; Yakovenko, Andrey A.
  • Angewandte Chemie International Edition, Vol. 51, Issue 39
  • DOI: 10.1002/anie.201202992

An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
journal, June 2010


Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011

  • O’Keeffe, Michael; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 675-702
  • DOI: 10.1021/cr200205j