Crossing the divide between homogeneous and heterogeneous catalysis in water oxidation

Vannucci, A. K.; Alibabaei, L.; Losego, M. D.; Concepcion, J. J.; Kalanyan, B.; Parsons, G. N.; Meyer, T. J.

doi:10.1073/pnas.1319832110

Title: Crossing the divide between homogeneous and heterogeneous catalysis in water oxidation

Journal Article · Mon Nov 25 00:00:00 EST 2013 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1319832110· OSTI ID:1383167

Vannucci, A. K.; Alibabaei, L.; Losego, M. D.; Concepcion, J. J.; Kalanyan, B.; Parsons, G. N.; Meyer, T. J.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Catalytic Hydrocarbon Functionalization (CCHF)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001298

OSTI ID:: 1383167

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Vol. 110, Issue 52; Related Information: CCHF partners with University of Virginia (lead); Brigham Young University; California Institute of Technology; Colorado School of Mines; University of Maryland; University of North Carolina, Chapel Hill; University of North Texas; Princeton University; The Scripps Research Institute; Yale University; ISSN 0027-8424

Publisher:: National Academy of Sciences, Washington, DC (United States)

Country of Publication:: United States

Language:: English

References (39)

Single-Site, Catalytic Water Oxidation on Oxide Surfaces Chen, Zuofeng; Concepcion, Javier J.; Jurss, Jonah W. Journal of the American Chemical Society, Vol. 131, Issue 43, p. 15580-15581 https://doi.org/10.1021/ja906391w	journal	November 2009
Distance Dependence of Plasmon-Enhanced Photocurrent in Dye-Sensitized Solar Cells Standridge, Stacey D.; Schatz, George C.; Hupp, Joseph T. Journal of the American Chemical Society, Vol. 131, Issue 24 https://doi.org/10.1021/ja9022072	journal	June 2009
Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells Swierk, John R.; Mallouk, Thomas E. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35246J	journal	January 2013
Structure–Property Relationships in Phosphonate-Derivatized, Ru ^II Polypyridyl Dyes on Metal Oxide Surfaces in an Aqueous Environment Hanson, Kenneth; Brennaman, M. Kyle; Ito, Akitaka The Journal of Physical Chemistry C, Vol. 116, Issue 28 https://doi.org/10.1021/jp304088d	journal	July 2012
Catalytic Water Oxidation by Single-Site Ruthenium Catalysts Concepcion, Javier J.; Jurss, Jonah W.; Norris, Michael R. Inorganic Chemistry, Vol. 49, Issue 4, p. 1277-1279 https://doi.org/10.1021/ic901437e	journal	February 2010
Concepts in homogeneous catalysis: the industrial view Cornils, Boy; Herrmann, Wolfgang A. Journal of Catalysis, Vol. 216, Issue 1-2 https://doi.org/10.1016/S0021-9517(02)00128-8	journal	May 2003
Photostability of Phosphonate-Derivatized, Ru ^II Polypyridyl Complexes on Metal Oxide Surfaces Hanson, Kenneth; Brennaman, M. Kyle; Luo, Hanlin ACS Applied Materials & Interfaces, Vol. 4, Issue 3 https://doi.org/10.1021/am201717x	journal	February 2012
Covalent Modification of Carbon Surfaces by Aryl Radicals Generated from the Electrochemical Reduction of Diazonium Salts Allongue, Philippe; Delamar, Michel; Desbat, Bernard Journal of the American Chemical Society, Vol. 119, Issue 1 https://doi.org/10.1021/ja963354s	journal	January 1997
Reaction selectivity in heterogeneous catalysis: An invited review Somorjai, Gabor A.; Kliewer, Christopher J. Reaction Kinetics and Catalysis Letters, Vol. 96, Issue 2 https://doi.org/10.1007/s11144-009-5531-7	journal	April 2009
Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge? Cokoja, Mirza; Bruckmeier, Christian; Rieger, Bernhard Angewandte Chemie International Edition, Vol. 50, Issue 37 https://doi.org/10.1002/anie.201102010	journal	August 2011
Quantum mechanics/molecular mechanics minimum free-energy path for accurate reaction energetics in solution and enzymes: Sequential sampling and optimization on the potential of mean force surface Hu, Hao; Lu, Zhenyu; Parks, Jerry M. The Journal of Chemical Physics, Vol. 128, Issue 3 https://doi.org/10.1063/1.2816557	journal	January 2008
Stabilization of a Ruthenium(II) Polypyridyl Dye on Nanocrystalline TiO ₂ by an Electropolymerized Overlayer Lapides, Alexander M.; Ashford, Dennis L.; Hanson, Kenneth Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja4055977	journal	October 2013
Supercritical Fluids in Heterogeneous Catalysis Baiker, Alfons Chemical Reviews, Vol. 99, Issue 2 https://doi.org/10.1021/cr970090z	journal	February 1999
Proton-coupled electron transfer at modified electrodes by multiple pathways Chen, Z.; Vannucci, A. K.; Concepcion, J. J. Proceedings of the National Academy of Sciences, Vol. 108, Issue 52 https://doi.org/10.1073/pnas.1115769108	journal	December 2011
Instability of the oxidation catalysts ([(bpy)2(py)Ru(O)]2+) and oxo(1,10-phenanthroline)(2,2',2"-terpyridine) ruthenium(2+) ([(trpy)(phen)Ru(O)]2+) in basic solution Roecker, Lee; Kutner, Wlodzimierz; Gilbert, John A. Inorganic Chemistry, Vol. 24, Issue 23 https://doi.org/10.1021/ic00217a018	journal	November 1985
Photoinduced Stepwise Oxidative Activation of a Chromophore–Catalyst Assembly on TiO ₂ Song, Wenjing; Glasson, Christopher R. K.; Luo, Hanlin The Journal of Physical Chemistry Letters, Vol. 2, Issue 14 https://doi.org/10.1021/jz200773r	journal	June 2011
Catalytic water oxidation on derivatized nanoITO Chen, Zuofeng; Concepcion, Javier J.; Hull, Jonathan F. Dalton Transactions, Vol. 39, Issue 30 https://doi.org/10.1039/c0dt00362j	journal	January 2010
Progress and future directions for atomic layer deposition and ALD-based chemistry Parsons, Gregory N.; George, Steven M.; Knez, Mato MRS Bulletin, Vol. 36, Issue 11 https://doi.org/10.1557/mrs.2011.238	journal	November 2011
Divide and conquer Mallouk, Thomas E. Nature Chemistry, Vol. 5, Issue 5 https://doi.org/10.1038/nchem.1634	journal	April 2013
Characterization of electrochemically pretreated glassy carbon electrodes Engstrom, Royce C.; Strasser, Vernon A. Analytical Chemistry, Vol. 56, Issue 2 https://doi.org/10.1021/ac00266a005	journal	February 1984
Toward solar fuels: Water splitting with sunlight and “rust”? Katz, Michael J.; Riha, Shannon C.; Jeong, Nak Cheon Coordination Chemistry Reviews, Vol. 256, Issue 21-22 https://doi.org/10.1016/j.ccr.2012.06.017	journal	November 2012
Transition metal complexes that catalyze oxygen formation from water: 1979–2010 Liu, Xien; Wang, Fengying Coordination Chemistry Reviews, Vol. 256, Issue 11-12 https://doi.org/10.1016/j.ccr.2012.01.015	journal	June 2012
Concerted O atom-proton transfer in the O--O bond forming step in water oxidation Chen, Z.; Concepcion, J. J.; Hu, X. Proceedings of the National Academy of Sciences, Vol. 107, Issue 16, p. 7225-7229 https://doi.org/10.1073/pnas.1001132107	journal	April 2010
Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts Concepcion, Javier J.; Tsai, Ming-Kang; Muckerman, James T. Journal of the American Chemical Society, Vol. 132, Issue 5, p. 1545-1557 https://doi.org/10.1021/ja904906v	journal	February 2010
Thermal and light-induced reduction of the ruthenium complex cation Ru(bpy)33+ in aqueous solution Ghosh, Pushpito K.; Brunschwig, Bruce S.; Chou, Mei Journal of the American Chemical Society, Vol. 106, Issue 17 https://doi.org/10.1021/ja00329a022	journal	August 1984
Application of High Surface Area Tin-Doped Indium Oxide Nanoparticle Films as Transparent Conducting Electrodes Hoertz, Paul G.; Chen, Zuofeng; Kent, Caleb A. Inorganic Chemistry, Vol. 49, Issue 18 https://doi.org/10.1021/ic100719r	journal	September 2010
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis Dau, Holger; Limberg, Christian; Reier, Tobias ChemCatChem, Vol. 2, Issue 7 https://doi.org/10.1002/cctc.201000126	journal	June 2010
Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies Concepcion, Javier J.; Jurss, Jonah W.; Hoertz, Paul G. Angewandte Chemie International Edition, Vol. 48, Issue 50 https://doi.org/10.1002/anie.200901279	journal	November 2009
Stabilization of [Ru(bpy) ₂ (4,4′-(PO ₃ H ₂ )bpy)] ²⁺ on Mesoporous TiO ₂ with Atomic Layer Deposition of Al ₂ O ₃ Hanson, Kenneth; Losego, Mark D.; Kalanyan, Berç Chemistry of Materials, Vol. 25, Issue 1 https://doi.org/10.1021/cm303172w	journal	December 2012
Electrochemical Water Oxidation with Carbon-Grafted Iridium Complexes deKrafft, Kathryn E.; Wang, Cheng; Xie, Zhigang ACS Applied Materials & Interfaces, Vol. 4, Issue 2 https://doi.org/10.1021/am2018095	journal	February 2012
Stabilizing molecular sensitizers in aqueous environs Losego, Mark D.; Hanson, Kenneth Nano Energy, Vol. 2, Issue 5 https://doi.org/10.1016/j.nanoen.2013.07.007	journal	September 2013
Electrogenerated IrO _x Nanoparticles as Dissolved Redox Catalysts for Water Oxidation Nakagawa, Takaaki; Bjorge, Natalie S.; Murray, Royce W. Journal of the American Chemical Society, Vol. 131, Issue 43 https://doi.org/10.1021/ja9063298	journal	November 2009
Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis Costentin, Cyrille; Drouet, Samuel; Robert, Marc Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242 https://doi.org/10.1021/ja303560c	journal	June 2012
A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II Duan, Lele; Bozoglian, Fernando; Mandal, Sukanta Nature Chemistry, Vol. 4, Issue 5 https://doi.org/10.1038/nchem.1301	journal	March 2012
Electron Transfer Dynamics of Iridium Oxide Nanoparticles Attached to Electrodes by Self-Assembled Monolayers Gambardella, Alessa A.; Feldberg, Stephen W.; Murray, Royce W. Journal of the American Chemical Society, Vol. 134, Issue 13 https://doi.org/10.1021/ja301212r	journal	March 2012
Visible light-driven water oxidation—from molecular catalysts to photoelectrochemical cells Duan, Lele; Tong, Lianpeng; Xu, Yunhua Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01276b	journal	January 2011
Dye Stabilization and Enhanced Photoelectrode Wettability in Water-Based Dye-Sensitized Solar Cells through Post-assembly Atomic Layer Deposition of TiO ₂ Son, Ho-Jin; Prasittichai, Chaiya; Mondloch, Joseph E. Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja406538a	journal	July 2013
Water Oxidation Intermediates Applied to Catalysis: Benzyl Alcohol Oxidation Vannucci, Aaron K.; Hull, Jonathan F.; Chen, Zuofeng Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja210718u	journal	February 2012
Stabilization of Ruthenium Sensitizers to TiO ₂ Surfaces through Cooperative Anchoring Groups Brown, Douglas G.; Schauer, Phil A.; Borau-Garcia, Javier Journal of the American Chemical Society, Vol. 135, Issue 5 https://doi.org/10.1021/ja310965h	journal	January 2013

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Title: Crossing the divide between homogeneous and heterogeneous catalysis in water oxidation

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