High-Temperature-Stable and Regenerable Catalysts: Platinum Nanoparticles in Aligned Mesoporous Silica Wells

Xiao, Chaoxian; Maligal-Ganesh, Raghu V.; Li, Tao; Qi, Zhiyuan; Guo, Zhiyong; Brashler, Kyle T.; Goes, Shannon; Li, Xinle; Goh, Tian Wei; Winans, Randall E.; Huang, Wenyu

doi:10.1002/cssc.201300524

Title: High-Temperature-Stable and Regenerable Catalysts: Platinum Nanoparticles in Aligned Mesoporous Silica Wells

Journal Article · Thu Aug 22 00:00:00 EDT 2013 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201300524· OSTI ID:1383147

Xiao, Chaoxian; Maligal-Ganesh, Raghu V.; Li, Tao; Qi, Zhiyuan; Guo, Zhiyong; Brashler, Kyle T.; Goes, Shannon; Li, Xinle; Goh, Tian Wei; Winans, Randall E.; Huang, Wenyu

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Institute for Atom-efficient Chemical Transformations (IACT)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1383147

Journal Information:: ChemSusChem, Vol. 6, Issue 10; Related Information: IACT partners with Argonne National Laboratory (lead); Brookhaven National Laboratory; Northwestern University; Purdue University; University of Wisconsin at Madison; ISSN 1864-5631

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

References (45)

Automobile exhaust emission control by catalysts Belton, David N.; Taylor, Kathleen C. Current Opinion in Solid State and Materials Science, Vol. 4, Issue 1 https://doi.org/10.1016/S1359-0286(99)80017-5	journal	February 1999
Size Control of Monodispersed Pt Nanoparticles and Their 2D Organization by Electrophoretic Deposition Teranishi, T.; Hosoe, M.; Tanaka, T. The Journal of Physical Chemistry B, Vol. 103, Issue 19 https://doi.org/10.1021/jp983478m	journal	May 1999
The Impact of Nanoscience on Heterogeneous Catalysis Bell, A. T. Science, Vol. 299, Issue 5613 https://doi.org/10.1126/science.1083671	journal	March 2003
Thermally stable Pt/mesoporous silica core–shell nanocatalysts for high-temperature reactions Joo, Sang Hoon; Park, Jeong Young; Tsung, Chia-Kuang Nature Materials, Vol. 8, Issue 2 https://doi.org/10.1038/nmat2329	journal	November 2008
High-Surface-Area Catalyst Design: Synthesis, Characterization, and Reaction Studies of Platinum Nanoparticles in Mesoporous SBA-15 Silica ^† Rioux, R. M.; Song, H.; Hoefelmeyer, J. D. The Journal of Physical Chemistry B, Vol. 109, Issue 6 https://doi.org/10.1021/jp048867x	journal	February 2005
Ethylene Hydrogenation over Platinum Nanoparticle Array Model Catalysts Fabricated by Electron Beam Lithography: Determination of Active Metal Surface Area Grunes, Jeff; Zhu, Ji; Anderson, Erik A. The Journal of Physical Chemistry B, Vol. 106, Issue 44 https://doi.org/10.1021/jp021641e	journal	November 2002
The Unique Role of CaO in Stabilizing the Pt/Al₂O₃ Catalyst for the Dehydrogenation of Cyclohexane Yu, Jiafeng; Wang, Rui; Ren, Shiyuan ChemCatChem, Vol. 4, Issue 9 https://doi.org/10.1002/cctc.201200067	journal	May 2012
Solvent-Free Oxidation of Primary Carbon-Hydrogen Bonds in Toluene Using Au-Pd Alloy Nanoparticles Kesavan, L.; Tiruvalam, R.; Rahim, M. H. A. Science, Vol. 331, Issue 6014 https://doi.org/10.1126/science.1198458	journal	January 2011
A new family of mesoporous molecular sieves prepared with liquid crystal templates Beck, J. S.; Vartuli, J. C.; Roth, W. J. Journal of the American Chemical Society, Vol. 114, Issue 27, p. 10834-10843 https://doi.org/10.1021/ja00053a020	journal	December 1992
Synthesis of uniform, spherical sub-100nm silica particles using a conceptual modification of the classic LaMer model Huang, Yuan; Pemberton, Jeanne E. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 360, Issue 1-3, p. 175-183 https://doi.org/10.1016/j.colsurfa.2010.02.031	journal	May 2010
Structure sensitivity of catalytic reactions Somorjai, Gabor A.; Carrazza, Jose Industrial & Engineering Chemistry Fundamentals, Vol. 25, Issue 1 https://doi.org/10.1021/i100021a009	journal	February 1986
n-Butane dehydrogenation on Pt, PtSn and PtGe supported on γ-Al2O3 deposited on spheres of α-Al2O3 by washcoating Ballarini, Adriana D.; Zgolicz, Patricia; Vilella, Irene M. J. Applied Catalysis A: General, Vol. 381, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.03.053	journal	June 2010
Tailored Core−Shell−Shell Nanostructures: Sandwiching Gold Nanoparticles between Silica Cores and Tunable Silica Shells Shi, Yan-Li; Asefa, Tewodros Langmuir, Vol. 23, Issue 18 https://doi.org/10.1021/la700863g	journal	July 2007
Supported Pt–Sn catalysts highly selective for isobutane dehydrogenation: preparation, characterization and catalytic behavior Llorca, J.; Homs, N.; León, J. Applied Catalysis A: General, Vol. 189, Issue 1 https://doi.org/10.1016/S0926-860X(99)00253-7	journal	November 1999
Single Gold Nanoparticles Encapsulated in Monodispersed Regular Spheres of Mesostructured Silica Produced by Pseudomorphic Transformation Botella, Pablo; Corma, Avelino; Navarro, María Teresa Chemistry of Materials, Vol. 19, Issue 8 https://doi.org/10.1021/cm0629457	journal	April 2007
Superlattice of Rodlike Virus Particles Formed in Aqueous Solution through Like-Charge Attraction Li, Tao; Winans, Randall E.; Lee, Byeongdu Langmuir, Vol. 27, Issue 17 https://doi.org/10.1021/la202121s	journal	September 2011
Changing Catalytic Activity during Colloidal Platinum Nanocatalysis Due to Shape Changes: Electron-Transfer Reaction Narayanan, Radha; El-Sayed, Mostafa A. Journal of the American Chemical Society, Vol. 126, Issue 23 https://doi.org/10.1021/ja0486061	journal	June 2004
Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? Cavani, F.; Ballarini, N.; Cericola, A. Catalysis Today, Vol. 127, Issue 1-4, p. 113-131 https://doi.org/10.1016/j.cattod.2007.05.009	journal	September 2007
Progresses in the Preparation of Coke Resistant Ni-based Catalyst for Steam and CO2 Reforming of Methane Liu, Chang-jun; Ye, Jingyun; Jiang, Jiaojun ChemCatChem, Vol. 3, Issue 3 https://doi.org/10.1002/cctc.201000358	journal	February 2011
Effect of organic capping layers over monodisperse platinum nanoparticles upon activity for ethylene hydrogenation and carbon monoxide oxidation Kuhn, John N.; Tsung, Chia-Kuang; Huang, Wenyu Journal of Catalysis, Vol. 265, Issue 2 https://doi.org/10.1016/j.jcat.2009.05.001	journal	July 2009
Catalytic properties of Cu/SBA-3 in oxidative dehydrogenation of methanol—The effect of the support composition Florek-Milewska, Justyna; Decyk, Piotr; Ziolek, Maria Applied Catalysis A: General, Vol. 393, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.12.005	journal	February 2011
Control over the permeation of silica nanoshells by surface-protected etching with water Hu, Yongxing; Zhang, Qiao; Goebl, James Physical Chemistry Chemical Physics, Vol. 12, Issue 38, Article No. 11836 https://doi.org/10.1039/c0cp00031k	journal	January 2010
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects Lei, Y.; Mehmood, F.; Lee, S. Science, Vol. 328, Issue 5975, p. 224-228 https://doi.org/10.1126/science.1185200	journal	April 2010
Surface-Protected Etching of Mesoporous Oxide Shells for the Stabilization of Metal Nanocatalysts Zhang, Qiao; Lee, Ilkeun; Ge, Jianping Advanced Functional Materials, Vol. 20, Issue 14 https://doi.org/10.1002/adfm.201000428	journal	June 2010
The Nanoscience Revolution: Merging of Colloid Science, Catalysis and Nanoelectronics Somorjai, Gabor A.; Tao, Feng; Park, Jeong Young Topics in Catalysis, Vol. 47, Issue 1-2 https://doi.org/10.1007/s11244-007-9028-1	journal	February 2008
Highly Active and Sinter-Resistant Pd-Nanoparticle Catalysts Encapsulated in Silica Park, Jung-Nam; Forman, Arnold J.; Tang, Wei Small, Vol. 4, Issue 10 https://doi.org/10.1002/smll.200800895	journal	October 2008
Assembly of reconfigurable one-dimensional colloidal superlattices due to a synergy of fundamental nanoscale forces Young, K. L.; Jones, M. R.; Zhang, J. Proceedings of the National Academy of Sciences, Vol. 109, Issue 7 https://doi.org/10.1073/pnas.1119301109	journal	January 2012
Multifunctional Mesoporous Composite Microspheres with Well-Designed Nanostructure: A Highly Integrated Catalyst System Deng, Yonghui; Cai, Yue; Sun, Zhenkun Journal of the American Chemical Society, Vol. 132, Issue 24 https://doi.org/10.1021/ja1025744	journal	June 2010
Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature Wittstock, A.; Zielasek, V.; Biener, J. Science, Vol. 327, Issue 5963 https://doi.org/10.1126/science.1183591	journal	January 2010
Yolk/shell nanoparticles: new platforms for nanoreactors, drug delivery and lithium-ion batteries Liu, Jian; Qiao, Shi Zhang; Chen, Jun Song Chemical Communications, Vol. 47, Issue 47 https://doi.org/10.1039/c1cc13658e	journal	January 2011
Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition Lu, Junling; Fu, Baosong; Kung, Mayfair C. Science, Vol. 335, Issue 6073 https://doi.org/10.1126/science.1212906	journal	March 2012
Core-Satellite Nanocomposite Catalysts Protected by a Porous Silica Shell: Controllable Reactivity, High Stability, and Magnetic Recyclability Ge, Jianping; Zhang, Qiao; Zhang, Tierui Angewandte Chemie International Edition, Vol. 47, Issue 46 https://doi.org/10.1002/anie.200803968	journal	November 2008
Green Gold Catalysis Christensen, C. H.; Norskov, J. K. Science, Vol. 327, Issue 5963 https://doi.org/10.1126/science.1184203	journal	January 2010
Recent Progress on Silica Coating of Nanoparticles and Related Nanomaterials Guerrero-Martínez, Andrés; Pérez-Juste, Jorge; Liz-Marzán, Luis M. Advanced Materials, Vol. 22, Issue 11 https://doi.org/10.1002/adma.200901263	journal	March 2010
Dehydrogenation of cyclohexane on catalysts containing noble metals and their combinations with platinum on alumina support Ali, Laila I.; Ali, Abdel-Ghaffar A.; Aboul-Fotouh, S. M. Applied Catalysis A: General, Vol. 177, Issue 1 https://doi.org/10.1016/S0926-860X(98)00248-8	journal	February 1999
Structure Sensitivity of Oxidative Dehydrogenation of Cyclohexane over FeO _x and Au/Fe ₃ O ₄ Nanocrystals Goergen, S.; Yin, C.; Yang, M. ACS Catalysis, Vol. 3, Issue 4 https://doi.org/10.1021/cs3007582	journal	February 2013
A cationic surfactant assisted selective etching strategy to hollow mesoporous silica spheres Fang, Xiaoliang; Chen, Cheng; Liu, Zhaohui Nanoscale, Vol. 3, Issue 4 https://doi.org/10.1039/c0nr00893a	journal	January 2011
Green chemistry Poliakoff, Martyn; Licence, Pete Nature, Vol. 450, Issue 7171 https://doi.org/10.1038/450810a	journal	December 2007
Optical properties of metal nanoparticle coated silica spheres: a simple effective medium approach Pastoriza-Santos, Isabel; Gomez, Daniel; Pérez-Juste, Jorge Phys. Chem. Chem. Phys., Vol. 6, Issue 21 https://doi.org/10.1039/B405157B	journal	January 2004
Hollow Mesoporous Aluminosilica Spheres with Perpendicular Pore Channels as Catalytic Nanoreactors Fang, Xiaoliang; Liu, Zhaohui; Hsieh, Ming-Feng ACS Nano, Vol. 6, Issue 5 https://doi.org/10.1021/nn3011703	journal	April 2012
Core-Satellite Nanocomposite Catalysts Protected by a Porous Silica Shell: Controllable Reactivity, High Stability, and Magnetic Recyclability Ge, Jianping; Zhang, Qiao; Zhang, Tierui Angewandte Chemie, Vol. 120, Issue 46 https://doi.org/10.1002/ange.200803968	journal	November 2008
The Catalytic Activity of ?Naked? Gold Particles Comotti, Massimiliano; Della Pina, Cristina; Matarrese, Roberto Angewandte Chemie International Edition, Vol. 43, Issue 43 https://doi.org/10.1002/anie.200460446	journal	November 2004
CO2-Reforming of Methane over Transition Metals Rostrupnielsen, J. R.; Hansen, J. H. B. Journal of Catalysis, Vol. 144, Issue 1 https://doi.org/10.1006/jcat.1993.1312	journal	November 1993
Automotive catalytic converters: current status and some perspectives Kašpar, Jan; Fornasiero, Paolo; Hickey, Neal Catalysis Today, Vol. 77, Issue 4 https://doi.org/10.1016/S0920-5861(02)00384-X	journal	January 2003
Structure Sensitivity of Carbon−Nitrogen Ring Opening: Impact of Platinum Particle Size from below 1 to 5 nm upon Pyrrole Hydrogenation Product Selectivity over Monodisperse Platinum Nanoparticles Loaded onto Mesoporous Silica Kuhn, John N.; Huang, Wenyu; Tsung, Chia-Kuang Journal of the American Chemical Society, Vol. 130, Issue 43 https://doi.org/10.1021/ja805050c	journal	October 2008

Similar Records

High-Temperature-Stable and Regenerable Catalysts: Platinum Nanoparticles in Aligned Mesoporous Silica Wells

Journal Article · Thu Aug 22 00:00:00 EDT 2013 · ChemSusChem (Online) · OSTI ID:1383147

Xiao, Chaoxian; Maligal-Ganesh, Raghu V.; Li, Tao; +8 more

Thermally Stable Nanocatalyst for High Temperature Reactions: Pt-Mesoporous Silica Core-Shell Nanoparticles

Journal Article · Sat Oct 25 00:00:00 EDT 2008 · Nature Materials · OSTI ID:1383147

Joo, Sang Hoon; Park, J Y; Tsung, C -K; +3 more

Aerobic Epoxidation of Olefin by Platinum Catalysts Supported on Mesoporous Silica Nanoparticles

Journal Article · Wed Jun 15 00:00:00 EDT 2016 · ACS Catalysis · OSTI ID:1383147

Munz, Dominik; Wang, Daoyong; Moyer, Megan M.; +6 more

Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
biofuels (including algae and biomass)
bio-inspired
materials and chemistry by design
synthesis (novel materials)
synthesis (scalable processing)

Title: High-Temperature-Stable and Regenerable Catalysts: Platinum Nanoparticles in Aligned Mesoporous Silica Wells

Citation Formats

References (45)

Similar Records

Related Subjects