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Title: Redox-active cyclopentadienyl Ni complexes with quinoid N-heterocyclic carbene ligands for the electrocatalytic hydrogen release from chemical fuels

Journal Article · · New Journal of Chemistry
DOI:https://doi.org/10.1039/c3nj00276d· OSTI ID:1382893
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Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Electrocatalysis, Transport Phenomena and Materials for Innovative Energy Storage (CETM)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001055
OSTI ID:
1382893
Journal Information:
New Journal of Chemistry, Vol. 37, Issue 11; Related Information: CETM partners with General Electric Global Research (lead); Lawrence Berkeley National Laboratory; Stanford University; Yale University; ISSN 1144-0546
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (9)

Redox Catalysis for Dehydrogenation of Liquid Hydrogen Carrier Fuels for Energy Storage and Conversion journal April 2011
Cover Picture: Champagne and Fireworks: Angewandte Chemie Celebrates Its Birthday (Angew. Chem. Int. Ed. 1/2013) journal December 2012
Quinone-Annulated N-Heterocyclic Carbene−Transition-Metal Complexes:  Observation of π-Backbonding Using FT-IR Spectroscopy and Cyclic Voltammetry
  • Sanderson, Matthew D.; Kamplain, Justin W.; Bielawski, Christopher W.
  • Journal of the American Chemical Society, Vol. 128, Issue 51 https://doi.org/10.1021/ja067475w
journal December 2006
Palladium(II) complexes of imidazolin-2-ylidene N-heterocyclic carbene ligands with redox-active dimethoxyphenyl or (hydro)quinonyl substituents journal May 2011
Homogeneous dehydrogenation of liquid organic hydrogen carriers catalyzed by an iridium PCP complex journal January 2011
Similarities between the reactions of dioxygen and alkenes with palladium(0): Relevance to the use of benzoquinone and molecular oxygen as stoichiometric oxidants in palladium-catalyzed oxidation reactions journal May 2006
Hydrogen storage in liquid organic heterocycles journal January 2008
DDQ as an electrocatalyst for amine dehydrogenation, a model system for virtual hydrogen storage journal January 2011
Redox-active ligands in catalysis journal January 2013

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Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
energy storage (including batteries and capacitors)
hydrogen and fuel cells
charge transport
membrane
synthesis (novel materials)