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Title: All-scale hierarchical thermoelectrics: MgTe in PbTe facilitates valence band convergence and suppresses bipolar thermal transport for high performance

Authors:
; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Revolutionary Materials for Solid State Energy Conversion (RMSSEC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1382594
DOE Contract Number:  
SC0001054
Resource Type:
Journal Article
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 6; Journal Issue: 11; Related Information: RMSSEC partners with Michigan State University (lead); University of California, Los Angeles; University of Michigan; Northwestern University; Oak Ridge National Laboratory; Ohio State University; Wayne State University; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
solar (thermal), phonons, thermal conductivity, thermoelectric, mechanical behavior, charge transport, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Zhao, L. D., Wu, H. J., Hao, S. Q., Wu, C. I., Zhou, X. Y., Biswas, K., He, J. Q., Hogan, T. P., Uher, C., Wolverton, C., Dravid, V. P., and Kanatzidis, M. G. All-scale hierarchical thermoelectrics: MgTe in PbTe facilitates valence band convergence and suppresses bipolar thermal transport for high performance. United States: N. p., 2013. Web. doi:10.1039/C3EE42187B.
Zhao, L. D., Wu, H. J., Hao, S. Q., Wu, C. I., Zhou, X. Y., Biswas, K., He, J. Q., Hogan, T. P., Uher, C., Wolverton, C., Dravid, V. P., & Kanatzidis, M. G. All-scale hierarchical thermoelectrics: MgTe in PbTe facilitates valence band convergence and suppresses bipolar thermal transport for high performance. United States. doi:10.1039/C3EE42187B.
Zhao, L. D., Wu, H. J., Hao, S. Q., Wu, C. I., Zhou, X. Y., Biswas, K., He, J. Q., Hogan, T. P., Uher, C., Wolverton, C., Dravid, V. P., and Kanatzidis, M. G. Tue . "All-scale hierarchical thermoelectrics: MgTe in PbTe facilitates valence band convergence and suppresses bipolar thermal transport for high performance". United States. doi:10.1039/C3EE42187B.
@article{osti_1382594,
title = {All-scale hierarchical thermoelectrics: MgTe in PbTe facilitates valence band convergence and suppresses bipolar thermal transport for high performance},
author = {Zhao, L. D. and Wu, H. J. and Hao, S. Q. and Wu, C. I. and Zhou, X. Y. and Biswas, K. and He, J. Q. and Hogan, T. P. and Uher, C. and Wolverton, C. and Dravid, V. P. and Kanatzidis, M. G.},
abstractNote = {},
doi = {10.1039/C3EE42187B},
journal = {Energy & Environmental Science},
issn = {1754-5692},
number = 11,
volume = 6,
place = {United States},
year = {2013},
month = {1}
}

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Nanoscale design to enable the revolution in renewable energy
journal, January 2009

  • Baxter, Jason; Bian, Zhixi; Chen, Gang
  • Energy & Environmental Science, Vol. 2, Issue 6
  • DOI: 10.1039/b821698c

High performance bulk thermoelectrics via a panoscopic approach
journal, May 2013


Coherent and incoherent phase stabilities of thermoelectric rocksalt IV-VI semiconductor alloys
journal, October 2012


Microstructure-Lattice Thermal Conductivity Correlation in Nanostructured PbTe 0.7 S 0.3 Thermoelectric Materials
journal, March 2010

  • He, Jiaqing; Girard, Steven N.; Kanatzidis, Mercouri G.
  • Advanced Functional Materials, Vol. 20, Issue 5
  • DOI: 10.1002/adfm.200901905

Raising the Thermoelectric Performance of p-Type PbS with Endotaxial Nanostructuring and Valence-Band Offset Engineering Using CdS and ZnS
journal, September 2012

  • Zhao, Li-Dong; He, Jiaqing; Hao, Shiqiang
  • Journal of the American Chemical Society, Vol. 134, Issue 39
  • DOI: 10.1021/ja306527n

The Electrical Conductivity and Thermoelectric Power of Bismuth Telluride
journal, April 1958


Thermoelectrics with Earth Abundant Elements: High Performance p-type PbS Nanostructured with SrS and CaS
journal, April 2012

  • Zhao, Li-Dong; He, Jiaqing; Wu, Chun-I
  • Journal of the American Chemical Society, Vol. 134, Issue 18
  • DOI: 10.1021/ja301772w

Projector augmented-wave method
journal, December 1994


Quantum Dot Superlattice Thermoelectric Materials and Devices
journal, September 2002


Valence-band structure of highly efficient p -type thermoelectric PbTe-PbS alloys
journal, January 2013


Stabilizing the Optimal Carrier Concentration for High Thermoelectric Efficiency
journal, November 2011

  • Pei, Yanzhong; LaLonde, Aaron D.; Heinz, Nicholas A.
  • Advanced Materials, Vol. 23, Issue 47
  • DOI: 10.1002/adma.201103153

Enhancement of Thermoelectric Figure of Merit by the Insertion of MgTe Nanostructures in p-type PbTe Doped with Na2Te
journal, May 2012

  • Ohta, Michihiro; Biswas, Kanishka; Lo, Shih-Han
  • Advanced Energy Materials, Vol. 2, Issue 9
  • DOI: 10.1002/aenm.201100756

Nanostructuring, Compositional Fluctuations, and Atomic Ordering in the Thermoelectric Materials AgPbmSbTe2+m. The Myth of Solid Solutions
journal, June 2005

  • Quarez, Eric; Hsu, Kuei-Fang; Pcionek, Robert
  • Journal of the American Chemical Society, Vol. 127, Issue 25, p. 9177-9190
  • DOI: 10.1021/ja051653o

Nanostructured AgPb m SbTe m +2 System Bulk Materials with Enhanced Thermoelectric Performance
journal, April 2008

  • Zhou, Min; Li, Jing-Feng; Kita, Takuji
  • Journal of the American Chemical Society, Vol. 130, Issue 13
  • DOI: 10.1021/ja7110652

Cubic AgPbmSbTe2+m: Bulk Thermoelectric Materials with High Figure of Merit
journal, February 2004


Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Reevaluation of PbTe1−xIx as high performance n-type thermoelectric material
journal, January 2011

  • LaLonde, Aaron D.; Pei, Yanzhong; Snyder, G. Jeffrey
  • Energy & Environmental Science, Vol. 4, Issue 6
  • DOI: 10.1039/c1ee01314a

Strained endotaxial nanostructures with high thermoelectric figure of merit
journal, January 2011

  • Biswas, Kanishka; He, Jiaqing; Zhang, Qichun
  • Nature Chemistry, Vol. 3, Issue 2
  • DOI: 10.1038/nchem.955

Resonant States in the Electronic Structure of the High Performance Thermoelectrics A g P b m S b T e 2 + m : The Role of Ag-Sb Microstructures
journal, September 2004


Convergence of electronic bands for high performance bulk thermoelectrics
journal, May 2011

  • Pei, Yanzhong; Shi, Xiaoya; LaLonde, Aaron
  • Nature, Vol. 473, Issue 7345, p. 66-69
  • DOI: 10.1038/nature09996

Enhancement of Thermoelectric Efficiency in PbTe by Distortion of the Electronic Density of States
journal, July 2008

  • Heremans, J. P.; Jovovic, V.; Toberer, E. S.
  • Science, Vol. 321, Issue 5888, p. 554-557
  • DOI: 10.1126/science.1159725

Nanostructured Thermoelectrics: The New Paradigm?
journal, February 2010

  • Kanatzidis, Mercouri G.
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm902195j

High Thermoelectric Performance in PbTe Due to Large Nanoscale Ag2Te Precipitates and La Doping
journal, November 2010

  • Pei, Yanzhong; Lensch-Falk, Jessica; Toberer, Eric S.
  • Advanced Functional Materials, Vol. 21, Issue 2
  • DOI: 10.1002/adfm.201000878

High-performance bulk thermoelectrics with all-scale hierarchical architectures
journal, September 2012

  • Biswas, Kanishka; He, Jiaqing; Blum, Ivan D.
  • Nature, Vol. 489, Issue 7416, p. 414-418
  • DOI: 10.1038/nature11439

Resonant levels in bulk thermoelectric semiconductors
journal, January 2012

  • Heremans, Joseph P.; Wiendlocha, Bartlomiej; Chamoire, Audrey M.
  • Energy Environ. Sci., Vol. 5, Issue 2
  • DOI: 10.1039/C1EE02612G

First-Principles Theory of Competing Order Types, Phase Separation, and Phonon Spectra in Thermoelectric AgPb m SbTe m + 2 Alloys
journal, October 2008


Enhanced thermoelectric properties in CoSb3-xTex alloys prepared by mechanical alloying and spark plasma sintering
journal, November 2007

  • Liu, Wei-Shu; Zhang, Bo-Ping; Li, Jing-Feng
  • Journal of Applied Physics, Vol. 102, Issue 10
  • DOI: 10.1063/1.2815671

Bismuth telluride nanotubes and the effects on the thermoelectric properties of nanotube-containing nanocomposites
journal, February 2005

  • Zhao, X. B.; Ji, X. H.; Zhang, Y. H.
  • Applied Physics Letters, Vol. 86, Issue 6
  • DOI: 10.1063/1.1863440

Bulk nanostructured thermoelectric materials: current research and future prospects
journal, January 2009

  • Minnich, A. J.; Dresselhaus, M. S.; Ren, Z. F.
  • Energy & Environmental Science, Vol. 2, Issue 5
  • DOI: 10.1039/b822664b

Temperature dependence of thermoelectric properties of Ni-doped CoSb3
journal, October 2005

  • Kitagawa, Hiroyuki; Wakatsuki, Machiko; Nagaoka, Hisanori
  • Journal of Physics and Chemistry of Solids, Vol. 66, Issue 10
  • DOI: 10.1016/j.jpcs.2005.05.077

High Performance Na-doped PbTe–PbS Thermoelectric Materials: Electronic Density of States Modification and Shape-Controlled Nanostructures
journal, October 2011

  • Girard, Steven N.; He, Jiaqing; Zhou, Xiaoyuan
  • Journal of the American Chemical Society, Vol. 133, Issue 41
  • DOI: 10.1021/ja206380h

Quantitative measurement of displacement and strain fields from HREM micrographs
journal, August 1998


High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys
journal, May 2008


High thermoelectric figure of merit in nanostructured p-type PbTe–MTe (M = Ca, Ba)
journal, January 2011

  • Biswas, Kanishka; He, Jiaqing; Wang, Guoyu
  • Energy & Environmental Science, Vol. 4, Issue 11
  • DOI: 10.1039/c1ee02297k

High-performance nanostructured thermoelectric materials
journal, October 2010