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Title: Interfacial Dynamics and Solar Fuel Formation in Dye-Sensitized Photoelectrosynthesis Cells

Authors:
; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Catalytic Hydrocarbon Functionalization (CCHF)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1381549
DOE Contract Number:  
SC0001298
Resource Type:
Journal Article
Journal Name:
ChemPhysChem
Additional Journal Information:
Journal Volume: 13; Journal Issue: 12; Related Information: CCHF partners with University of Virginia (lead); Brigham Young University; California Institute of Technology; Colorado School of Mines; University of Maryland; University of North Carolina, Chapel Hill; University of North Texas; Princeton University; The Scripps Research Institute; Yale University; Journal ID: ISSN 1439-4235
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Song, Wenjing, Chen, Zuofeng, Glasson, Christopher R. K., Hanson, Kenneth, Luo, Hanlin, Norris, Michael R., Ashford, Dennis L., Concepcion, Javier J., Brennaman, M. Kyle, and Meyer, Thomas J. Interfacial Dynamics and Solar Fuel Formation in Dye-Sensitized Photoelectrosynthesis Cells. United States: N. p., 2012. Web. doi:10.1002/cphc.201200100.
Song, Wenjing, Chen, Zuofeng, Glasson, Christopher R. K., Hanson, Kenneth, Luo, Hanlin, Norris, Michael R., Ashford, Dennis L., Concepcion, Javier J., Brennaman, M. Kyle, & Meyer, Thomas J. Interfacial Dynamics and Solar Fuel Formation in Dye-Sensitized Photoelectrosynthesis Cells. United States. doi:10.1002/cphc.201200100.
Song, Wenjing, Chen, Zuofeng, Glasson, Christopher R. K., Hanson, Kenneth, Luo, Hanlin, Norris, Michael R., Ashford, Dennis L., Concepcion, Javier J., Brennaman, M. Kyle, and Meyer, Thomas J. Tue . "Interfacial Dynamics and Solar Fuel Formation in Dye-Sensitized Photoelectrosynthesis Cells". United States. doi:10.1002/cphc.201200100.
@article{osti_1381549,
title = {Interfacial Dynamics and Solar Fuel Formation in Dye-Sensitized Photoelectrosynthesis Cells},
author = {Song, Wenjing and Chen, Zuofeng and Glasson, Christopher R. K. and Hanson, Kenneth and Luo, Hanlin and Norris, Michael R. and Ashford, Dennis L. and Concepcion, Javier J. and Brennaman, M. Kyle and Meyer, Thomas J.},
abstractNote = {},
doi = {10.1002/cphc.201200100},
journal = {ChemPhysChem},
issn = {1439-4235},
number = 12,
volume = 13,
place = {United States},
year = {2012},
month = {6}
}

Works referenced in this record:

Single-Site, Catalytic Water Oxidation on Oxide Surfaces
journal, November 2009

  • Chen, Zuofeng; Concepcion, Javier J.; Jurss, Jonah W.
  • Journal of the American Chemical Society, Vol. 131, Issue 43, p. 15580-15581
  • DOI: 10.1021/ja906391w

Catalytic Water Oxidation by Single-Site Ruthenium Catalysts
journal, February 2010

  • Concepcion, Javier J.; Jurss, Jonah W.; Norris, Michael R.
  • Inorganic Chemistry, Vol. 49, Issue 4, p. 1277-1279
  • DOI: 10.1021/ic901437e

Interfacial Electron Transfer Dynamics for [Ru(bpy) 2 ((4,4′-PO 3 H 2 ) 2 bpy)] 2+ Sensitized TiO 2 in a Dye-Sensitized Photoelectrosynthesis Cell: Factors Influencing Efficiency and Dynamics
journal, March 2011

  • Song, Wenjing; Brennaman, M. Kyle; Concepcion, Javier J.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 14
  • DOI: 10.1021/jp200124k

Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972

  • Fujishima, Akira; Honda, Kenichi
  • Nature, Vol. 238, Issue 5358, p. 37-38
  • DOI: 10.1038/238037a0

Solar Driven Water Oxidation by a Bioinspired Manganese Molecular Catalyst
journal, March 2010

  • Brimblecombe, Robin; Koo, Annette; Dismukes, G. Charles
  • Journal of the American Chemical Society, Vol. 132, Issue 9
  • DOI: 10.1021/ja910055a

Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO 2 semiconductor surfaces
journal, January 2009

  • Ardo, Shane; Meyer, Gerald J.
  • Chem. Soc. Rev., Vol. 38, Issue 1
  • DOI: 10.1039/B804321N

Nonaqueous Catalytic Water Oxidation
journal, December 2010

  • Chen, Zuofeng; Concepcion, Javier J.; Luo, Hanlin
  • Journal of the American Chemical Society, Vol. 132, Issue 50
  • DOI: 10.1021/ja107347n

Visible Region Photooxidation on TiO 2 with a Chromophore−Catalyst Molecular Assembly
journal, October 1999

  • Treadway, Joseph A.; Moss, John A.; Meyer, Thomas J.
  • Inorganic Chemistry, Vol. 38, Issue 20
  • DOI: 10.1021/ic990466m

Parameters Influencing Charge Recombination Kinetics in Dye-Sensitized Nanocrystalline Titanium Dioxide Films
journal, January 2000

  • Haque, Saif A.; Tachibana, Yasuhiro; Willis, Richard L.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 3
  • DOI: 10.1021/jp991085x

Dye-sensitized nanostructured tandem cell-first demonstrated cell with a dye-sensitized photocathode
journal, May 2000


Water-Splitting Chemistry of Photosystem II
journal, November 2006

  • McEvoy, James P.; Brudvig, Gary W.
  • Chemical Reviews, Vol. 106, Issue 11
  • DOI: 10.1021/cr0204294

Dye-Sensitized Solar Cells
journal, November 2010

  • Hagfeldt, Anders; Boschloo, Gerrit; Sun, Licheng
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr900356p

Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes
journal, January 2011

  • Chen, Zuofeng; Chen, Chuncheng; Weinberg, David R.
  • Chemical Communications, Vol. 47, Issue 47
  • DOI: 10.1039/c1cc15071e

Concerted O atom-proton transfer in the O--O bond forming step in water oxidation
journal, April 2010

  • Chen, Z.; Concepcion, J. J.; Hu, X.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 16, p. 7225-7229
  • DOI: 10.1073/pnas.1001132107

Modulation of the Rate of Electron Injection in Dye-Sensitized Nanocrystalline TiO 2 Films by Externally Applied Bias
journal, August 2001

  • Tachibana, Yasuhiro; Haque, Saif A.; Mercer, Ian P.
  • The Journal of Physical Chemistry B, Vol. 105, Issue 31
  • DOI: 10.1021/jp010173q

Charge Recombination Kinetics in Dye-Sensitized Nanocrystalline Titanium Dioxide Films under Externally Applied Bias
journal, March 1998

  • Haque, Saif A.; Tachibana, Yasuhiro; Klug, David R.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 10
  • DOI: 10.1021/jp973335k

Vectorial electron injection into transparent semiconductor membranes and electric field effects on the dynamics of light-induced charge separation
journal, November 1990

  • O'Regan, Brian.; Moser, Jacques.; Anderson, Marc.
  • The Journal of Physical Chemistry, Vol. 94, Issue 24
  • DOI: 10.1021/j100387a017

Structure and redox properties of the water-oxidation catalyst [(bpy)2(OH2)RuORu(OH2)(bpy)2]4+
journal, June 1985

  • Gilbert, John A.; Eggleston, Drake S.; Murphy, Wyatt R.
  • Journal of the American Chemical Society, Vol. 107, Issue 13
  • DOI: 10.1021/ja00299a017

Synthesis and Mechanistic Studies of Organic Chromophores with Different Energy Levels for p-Type Dye-Sensitized Solar Cells
journal, March 2010

  • Qin, Peng; Wiberg, Joanna; Gibson, Elizabeth A.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 10
  • DOI: 10.1021/jp911091n

Improving Photosynthetic Efficiency for Greater Yield
journal, June 2010


Oxobis(2,2'-bipyridine)pyridineruthenium(IV) ion, [(bpy)2(py)Ru:O]2+
journal, May 1978

  • Moyer, Bruce A.; Meyer, Thomas J.
  • Journal of the American Chemical Society, Vol. 100, Issue 11
  • DOI: 10.1021/ja00479a054

Multiple emissions from charge transfer excited states of ruthenium(II)—polypyridine complexes
journal, October 1978


Revealing the blueprint of photosynthesis
journal, July 1994


Dye-Sensitized Nanostructured p-Type Nickel Oxide Film as a Photocathode for a Solar Cell
journal, October 1999

  • He, Jianjun; Lindström, Henrik; Hagfeldt, Anders
  • The Journal of Physical Chemistry B, Vol. 103, Issue 42
  • DOI: 10.1021/jp991681r

Biofuels, facts, fantasy, and feasibility
journal, June 2009


Interfacial Electron Transfer Dynamics Following Laser Flash Photolysis of [Ru(bpy)2((4,4′-PO3H2)2bpy)]2+ in TiO2 Nanoparticle Films in Aqueous Environments
journal, February 2011

  • Brennaman, M. Kyle; Patrocinio, Antonio Otávio T.; Song, Wenjing
  • ChemSusChem, Vol. 4, Issue 2
  • DOI: 10.1002/cssc.201000356

Double-Layered NiO Photocathodes for p-Type DSSCs with Record IPCE
journal, April 2010


Photoelectrochemical Behavior of Sensitized TiO 2 Photoanodes in an Aqueous Environment: Application to Hydrogen Production
journal, April 2010

  • Caramori, Stefano; Cristino, Vito; Argazzi, Roberto
  • Inorganic Chemistry, Vol. 49, Issue 7
  • DOI: 10.1021/ic9023037

An Outlook on Microalgal Biofuels
journal, August 2010


Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement
journal, May 2011

  • Blankenship, R. E.; Tiede, D. M.; Barber, J.
  • Science, Vol. 332, Issue 6031, p. 805-809
  • DOI: 10.1126/science.1200165

Diffusion-Limited Interfacial Electron Transfer with Large Apparent Driving Forces
journal, September 1999

  • Hasselmann, Georg M.; Meyer, Gerald J.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 36
  • DOI: 10.1021/jp992086s

Electrocatalytic reduction of CO2 by a complex of rhenium in thin polymeric films
journal, February 1989

  • O'Toole, Terrence R.; Sullivan, B. Patrick; Bruce, Mitchell R. -M.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 259, Issue 1-2
  • DOI: 10.1016/0022-0728(89)80049-X

A vision for crystalline silicon photovoltaics
journal, January 2006

  • Swanson, Richard M.
  • Progress in Photovoltaics: Research and Applications, Vol. 14, Issue 5
  • DOI: 10.1002/pip.709

Random walk models of charge transfer and transport in dye sensitized systems
journal, July 2004


Highly efficient photocathodes for dye-sensitized tandem solar cells
journal, November 2009

  • Nattestad, A.; Mozer, A. J.; Fischer, M. K. R.
  • Nature Materials, Vol. 9, Issue 1
  • DOI: 10.1038/nmat2588

Photostability of Phosphonate-Derivatized, Ru II Polypyridyl Complexes on Metal Oxide Surfaces
journal, February 2012

  • Hanson, Kenneth; Brennaman, M. Kyle; Luo, Hanlin
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 3
  • DOI: 10.1021/am201717x

Ligand-Based Reduction of CO 2 to CO Mediated by an Anionic Niobium Nitride Complex
journal, February 2010

  • Silvia, Jared S.; Cummins, Christopher C.
  • Journal of the American Chemical Society, Vol. 132, Issue 7
  • DOI: 10.1021/ja910445r

Light-Induced Redox Reactions in Nanocrystalline Systems
journal, January 1995

  • Hagfeldt, Anders.; Graetzel, Michael.
  • Chemical Reviews, Vol. 95, Issue 1
  • DOI: 10.1021/cr00033a003

Electron transfer quenching of excited states of metal complexes
journal, January 1976

  • Young, Roger C.; Meyer, Thomas J.; Whitten, David G.
  • Journal of the American Chemical Society, Vol. 98, Issue 1
  • DOI: 10.1021/ja00417a073

Trap-limited recombination in dye-sensitized nanocrystalline metal oxide electrodes
journal, May 2001


A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
journal, October 1991

  • O'Regan, Brian; Grätzel, Michael
  • Nature, Vol. 353, Issue 6346, p. 737-740
  • DOI: 10.1038/353737a0

A p-Type NiO-Based Dye-Sensitized Solar Cell with an Open-Circuit Voltage of 0.35 V
journal, June 2009

  • Gibson, Elizabeth A.; Smeigh, Amanda L.; Le Pleux, Loïc
  • Angewandte Chemie, Vol. 121, Issue 24
  • DOI: 10.1002/ange.200900423

Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell
journal, January 2009

  • Youngblood, W. Justin; Lee, Seung-Hyun Anna; Kobayashi, Yoji
  • Journal of the American Chemical Society, Vol. 131, Issue 3, p. 926-927
  • DOI: 10.1021/ja809108y

Photoinduced Stepwise Oxidative Activation of a Chromophore–Catalyst Assembly on TiO 2
journal, June 2011

  • Song, Wenjing; Glasson, Christopher R. K.; Luo, Hanlin
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 14
  • DOI: 10.1021/jz200773r

Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies
journal, November 2009

  • Concepcion, Javier J.; Jurss, Jonah W.; Hoertz, Paul G.
  • Angewandte Chemie, Vol. 121, Issue 50
  • DOI: 10.1002/ange.200901279

Catalytic water oxidation on derivatized nanoITO
journal, January 2010

  • Chen, Zuofeng; Concepcion, Javier J.; Hull, Jonathan F.
  • Dalton Transactions, Vol. 39, Issue 30
  • DOI: 10.1039/c0dt00362j

A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst
journal, January 2011

  • Moore, Gary F.; Blakemore, James D.; Milot, Rebecca L.
  • Energy & Environmental Science, Vol. 4, Issue 7
  • DOI: 10.1039/c1ee01037a

Directed charge transfer. Reductive quenching in a chromophore-quencher complex
journal, August 1985

  • Westmoreland, T. David; Schanze, Kirk S.; Neveux, Paul E.
  • Inorganic Chemistry, Vol. 24, Issue 17
  • DOI: 10.1021/ic00211a004

Influence of Surface Protonation on the Sensitization Efficiency of Porphyrin-Derivatized TiO 2
journal, August 2004

  • Watson, David F.; Marton, Andras; Stux, Arnold M.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 31
  • DOI: 10.1021/jp048182x

Catalytic oxidation of water by an oxo-bridged ruthenium dimer
journal, July 1982

  • Gersten, Susan W.; Samuels, George J.; Meyer, Thomas J.
  • Journal of the American Chemical Society, Vol. 104, Issue 14
  • DOI: 10.1021/ja00378a053

Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
journal, February 2010

  • Concepcion, Javier J.; Tsai, Ming-Kang; Muckerman, James T.
  • Journal of the American Chemical Society, Vol. 132, Issue 5, p. 1545-1557
  • DOI: 10.1021/ja904906v

Application of High Surface Area Tin-Doped Indium Oxide Nanoparticle Films as Transparent Conducting Electrodes
journal, September 2010

  • Hoertz, Paul G.; Chen, Zuofeng; Kent, Caleb A.
  • Inorganic Chemistry, Vol. 49, Issue 18
  • DOI: 10.1021/ic100719r

Structural and pH Dependence of Excited State PCET Reactions Involving Reductive Quenching of the MLCT Excited State of [Ru II (bpy) 2 (bpz)] 2+ by Hydroquinones
journal, April 2011

  • Lebedeva, Natalia V.; Schmidt, Robert D.; Concepcion, Javier J.
  • The Journal of Physical Chemistry A, Vol. 115, Issue 15
  • DOI: 10.1021/jp200381n

Rapid Transfer of Hydride Ion from a Ruthenium Complex to C 1 Species in Water
journal, August 2007

  • Creutz, Carol; Chou, Mei H.
  • Journal of the American Chemical Society, Vol. 129, Issue 33
  • DOI: 10.1021/ja074158w

Ultrafast electron injection from metal polypyridyl complexes to metal-oxide nanocrystalline thin films
journal, July 2004


Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies
journal, November 2009

  • Concepcion, Javier J.; Jurss, Jonah W.; Hoertz, Paul G.
  • Angewandte Chemie International Edition, Vol. 48, Issue 50
  • DOI: 10.1002/anie.200901279

Dye-sensitized solar cells: A safe bet for the future.
journal, January 2008

  • Gonçalves, Luís Moreira; de Zea Bermudez, Verónica; Ribeiro, Helena Aguilar
  • Energy & Environmental Science, Vol. 1, Issue 6
  • DOI: 10.1039/b807236a

Chemical approaches to artificial photosynthesis
journal, May 1989


A p-Type NiO-Based Dye-Sensitized Solar Cell with an Open-Circuit Voltage of 0.35 V
journal, June 2009

  • Gibson, Elizabeth A.; Smeigh, Amanda L.; Le Pleux, Loïc
  • Angewandte Chemie International Edition, Vol. 48, Issue 24
  • DOI: 10.1002/anie.200900423

Development of an Efficient Photocatalytic System for CO 2 Reduction Using Rhenium(I) Complexes Based on Mechanistic Studies
journal, February 2008

  • Takeda, Hiroyuki; Koike, Kazuhide; Inoue, Haruo
  • Journal of the American Chemical Society, Vol. 130, Issue 6
  • DOI: 10.1021/ja077752e

Parameters Influencing the Efficiency of Electron Injection in Dye-Sensitized Solar Cells
journal, April 2009

  • Koops, Sara E.; O’Regan, Brian C.; Barnes, Piers R. F.
  • Journal of the American Chemical Society, Vol. 131, Issue 13
  • DOI: 10.1021/ja8091278

Chemical Approaches to Artificial Photosynthesis. 2
journal, October 2005

  • Alstrum-Acevedo, James H.; Brennaman, M. Kyle; Meyer, Thomas J.
  • Inorganic Chemistry, Vol. 44, Issue 20
  • DOI: 10.1021/ic050904r

Photosystem II: Structure and mechanism of the water:plastoquinone oxidoreductase
journal, July 2007


Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells
journal, October 2005


Mimicking Photosynthetic Solar Energy Transduction
journal, January 2001

  • Gust, Devens; Moore, Thomas A.; Moore, Ana L.
  • Accounts of Chemical Research, Vol. 34, Issue 1
  • DOI: 10.1021/ar9801301

New Photovoltaic Devices Based on the Sensitization of p-type Semiconductors: Challenges and Opportunities
journal, August 2010

  • Odobel, Fabrice; Le Pleux, Loïc; Pellegrin, Yann
  • Accounts of Chemical Research, Vol. 43, Issue 8
  • DOI: 10.1021/ar900275b

Recent Advances in Sensitized Mesoscopic Solar Cells
journal, November 2009

  • Grätzel, Michael
  • Accounts of Chemical Research, Vol. 42, Issue 11, p. 1788-1798
  • DOI: 10.1021/ar900141y

Design of an Organic Chromophore for P-Type Dye-Sensitized Solar Cells
journal, July 2008

  • Qin, Peng; Zhu, Hongjun; Edvinsson, Tomas
  • Journal of the American Chemical Society, Vol. 130, Issue 27
  • DOI: 10.1021/ja8001474

Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
journal, December 2009

  • Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko
  • Accounts of Chemical Research, Vol. 42, Issue 12
  • DOI: 10.1021/ar9001679

Kinetic and Energetic Paradigms for Dye-Sensitized Solar Cells: Moving from the Ideal to the Real
journal, November 2009

  • O’Regan, Brian C.; Durrant, James R.
  • Accounts of Chemical Research, Vol. 42, Issue 11
  • DOI: 10.1021/ar900145z

Cation-Controlled Interfacial Charge Injection in Sensitized Nanocrystalline TiO 2
journal, September 1999

  • Kelly, Craig A.; Farzad, Fereshteh; Thompson, David W.
  • Langmuir, Vol. 15, Issue 20
  • DOI: 10.1021/la990617y