Fluorescence correlation spectroscopy evidence for structural heterogeneity in ionic liquids

Guo, Jianchang; Baker, Gary A.; Hillesheim, Patrick C.; Dai, Sheng; Shaw, Robert W.; Mahurin, Shannon M.

doi:10.1039/C1CP20929A

Title: Fluorescence correlation spectroscopy evidence for structural heterogeneity in ionic liquids

Journal Article · Sat Jan 01 00:00:00 EST 2011 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/C1CP20929A· OSTI ID:1380615

Guo, Jianchang; Baker, Gary A.; Hillesheim, Patrick C.; Dai, Sheng; Shaw, Robert W.; Mahurin, Shannon M.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: ERKCC61

OSTI ID:: 1380615

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 13, Issue 27; Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia; ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (35)

Dispersed Kinetics without Rate Heterogeneity in an Ionic Liquid Measured with Multiple Population-Period Transient Spectroscopy Khurmi, Champak; Berg, Mark A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 1 https://doi.org/10.1021/jz900141a	journal	November 2009
Fluorescence Probing of Temperature-Dependent Dynamics and Friction in Ionic Liquid Local Environments ^† Funston, Alison M.; Fadeeva, Tatiana A.; Wishart, James F. The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp068298o	journal	May 2007
Understanding Ionic Liquids at the Molecular Level: Facts, Problems, and Controversies Weingärtner, Hermann Angewandte Chemie International Edition, Vol. 47, Issue 4 https://doi.org/10.1002/anie.200604951	journal	January 2008
Small angle neutron scattering from 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids ([Cnmim][PF6], n=4, 6, and 8) Hardacre, Christopher; Holbrey, John D.; Mullan, Claire L. The Journal of Chemical Physics, Vol. 133, Issue 7 https://doi.org/10.1063/1.3473825	journal	August 2010
Ionic liquids and reactions at the electrochemical interface MacFarlane, Douglas R.; Pringle, Jennifer M.; Howlett, Patrick C. Physical Chemistry Chemical Physics, Vol. 12, Issue 8 https://doi.org/10.1039/b923053j	journal	January 2010
Structure and Solvation in Ionic Liquids Hardacre, Christopher; Holbrey, John D.; Nieuwenhuyzen, Mark Accounts of Chemical Research, Vol. 40, Issue 11 https://doi.org/10.1021/ar700068x	journal	November 2007
Fluorescence correlation spectroscopy: the technique and its applications Krichevsky, Oleg; Bonnet, Grégoire Reports on Progress in Physics, Vol. 65, Issue 2 https://doi.org/10.1088/0034-4885/65/2/203	journal	January 2002
Energy applications of ionic liquids Wishart, James F. Energy & Environmental Science, Vol. 2, Issue 9 https://doi.org/10.1039/b906273d	journal	January 2009
Multiple Diffusion Mechanisms Due to Nanostructuring in Crowded Environments Sanabria, Hugo; Kubota, Yoshihisa; Waxham, M. Neal Biophysical Journal, Vol. 92, Issue 1 https://doi.org/10.1529/biophysj.106.090498	journal	January 2007
Unique Spatial Heterogeneity in Ionic Liquids Wang, Yanting; Voth, Gregory A. Journal of the American Chemical Society, Vol. 127, Issue 35 https://doi.org/10.1021/ja053796g	journal	September 2005
Nanoscale Segregation in Room Temperature Ionic Liquids ^† Triolo, Alessandro; Russina, Olga; Bleif, Hans-Jurgen The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp067705t	journal	May 2007
Probe Diffusion in Aqueous Poly(vinyl alcohol) Solutions Studied by Fluorescence Correlation Spectroscopy Michelman-Ribeiro, Ariel; Horkay, Ferenc; Nossal, Ralph Biomacromolecules, Vol. 8, Issue 5 https://doi.org/10.1021/bm061195r	journal	May 2007
Morphology and intermolecular dynamics of 1-alkyl-3-methylimidazolium bis{(trifluoromethane)sulfonyl}amide ionic liquids: structural and dynamic evidence of nanoscale segregation Russina, Olga; Triolo, Alessandro; Gontrani, Lorenzo Journal of Physics: Condensed Matter, Vol. 21, Issue 42 https://doi.org/10.1088/0953-8984/21/42/424121	journal	September 2009
Selected chemical–physical properties and structural heterogeneities in 1-ethyl-3-methylimidazolium alkyl-sulfate room temperature ionic liquids Russina, Olga; Gontrani, Lorenzo; Fazio, Barbara Chemical Physics Letters, Vol. 493, Issue 4-6 https://doi.org/10.1016/j.cplett.2010.05.042	journal	June 2010
Stable Mesoscopic Dye-Sensitized Solar Cells Based on Tetracyanoborate Ionic Liquid Electrolyte Kuang, Daibin; Wang, Peng; Ito, Seigo Journal of the American Chemical Society, Vol. 128, Issue 24 https://doi.org/10.1021/ja061714y	journal	June 2006
Charge Separation and Efficient Light Energy Conversion in Sensitized Mesoscopic Solar Cells Based on Binary Ionic Liquids Wang, Peng; Wenger, Bernard; Humphry-Baker, Robin Journal of the American Chemical Society, Vol. 127, Issue 18 https://doi.org/10.1021/ja042232u	journal	May 2005
Additivity in the Optical Kerr Effect Spectra of Binary Ionic Liquid Mixtures: Implications for Nanostructural Organization Xiao, Dong; Rajian, Justin Rajesh; Li, Shengfu The Journal of Physical Chemistry B, Vol. 110, Issue 33 https://doi.org/10.1021/jp063740o	journal	August 2006
What is the Origin of the Prepeak in the X-ray Scattering of Imidazolium-Based Room-Temperature Ionic Liquids? Annapureddy, Harsha V. R.; Kashyap, Hemant K.; De Biase, Pablo M. The Journal of Physical Chemistry B, Vol. 114, Issue 50 https://doi.org/10.1021/jp108545z	journal	December 2010
Spotlight on ionic liquids Castner, Edward W.; Wishart, James F. The Journal of Chemical Physics, Vol. 132, Issue 12 https://doi.org/10.1063/1.3373178	journal	March 2010
Recent Developments in Fluorescence Correlation Spectroscopy for Diffusion Measurements in Planar Lipid Membranes Macháň, Radek; Hof, Martin International Journal of Molecular Sciences, Vol. 11, Issue 2 https://doi.org/10.3390/ijms11020427	journal	January 2010
Nanoscale organization in piperidinium-based room temperature ionic liquids Triolo, Alessandro; Russina, Olga; Fazio, Barbara The Journal of Chemical Physics, Vol. 130, Issue 16 https://doi.org/10.1063/1.3119977	journal	April 2009
Morphology of 1-alkyl-3-methylimidazolium hexafluorophosphate room temperature ionic liquids Triolo, Alessandro; Russina, Olga; Fazio, Barbara Chemical Physics Letters, Vol. 457, Issue 4-6 https://doi.org/10.1016/j.cplett.2008.04.027	journal	May 2008
Fluorescence correlation spectroscopic studies of diffusion within the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate Werner, James H.; Baker, Sheila N.; Baker, Gary A. The Analyst, Vol. 128, Issue 6 https://doi.org/10.1039/b300734k	journal	January 2003
Dynamics of Imidazolium Ionic Liquids from a Combined Dielectric Relaxation and Optical Kerr Effect Study: Evidence for Mesoscopic Aggregation Turton, David A.; Hunger, Johannes; Stoppa, Alexander Journal of the American Chemical Society, Vol. 131, Issue 31 https://doi.org/10.1021/ja903315v	journal	August 2009
Ionic Liquids in Separations Han, Xinxin; Armstrong, Daniel W. Accounts of Chemical Research, Vol. 40, Issue 11 https://doi.org/10.1021/ar700044y	journal	November 2007
Lithium-doped plastic crystal electrolytes exhibiting fast ion conduction for secondary batteries MacFarlane, Douglas R.; Huang, Junhua; Forsyth, Maria Nature, Vol. 402, Issue 6763 https://doi.org/10.1038/45514	journal	December 1999
Measurements of the Complete Solvation Response in Ionic Liquids ^† Arzhantsev, Sergei; Jin, Hui; Baker, Gary A. The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp067273m	journal	May 2007
Understanding Ionic Liquids through Atomistic and Coarse-Grained Molecular Dynamics Simulations Wang, Yanting; Jiang, Wei; Yan, Tianying Accounts of Chemical Research, Vol. 40, Issue 11 https://doi.org/10.1021/ar700160p	journal	November 2007
Resolution of Fluorescence Correlation Measurements Meseth, Ulrich; Wohland, Thorsten; Rigler, Rudolf Biophysical Journal, Vol. 76, Issue 3 https://doi.org/10.1016/S0006-3495(99)77321-2	journal	March 1999
Anomalous Diffusion of Proteins Due to Molecular Crowding Banks, Daniel S.; Fradin, Cécile Biophysical Journal, Vol. 89, Issue 5 https://doi.org/10.1529/biophysj.104.051078	journal	November 2005
The Smallest Amphiphiles: Nanostructure in Protic Room-Temperature Ionic Liquids with Short Alkyl Groups Atkin, Rob; Warr, Gregory G. The Journal of Physical Chemistry B, Vol. 112, Issue 14 https://doi.org/10.1021/jp801190u	journal	April 2008
Nanostructural Organization in Ionic Liquids Canongia Lopes, José N. A.; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 110, Issue 7 https://doi.org/10.1021/jp056006y	journal	February 2006
Photochemical processes in ionic liquids on ultrafast timescales Nese, Chandrasekhar; Unterreiner, Andreas-Neil Physical Chemistry Chemical Physics, Vol. 12, Issue 8 https://doi.org/10.1039/b916799b	journal	January 2010
Communication: X-ray scattering from ionic liquids with pyrrolidinium cations Santos, Cherry S.; Murthy, N. Sanjeeva; Baker, Gary A. The Journal of Chemical Physics, Vol. 134, Issue 12 https://doi.org/10.1063/1.3569131	journal	March 2011
Multiprobe Spectroscopic Evidence for “Hyperpolarity” within 1-Butyl-3-methylimidazolium Hexafluorophosphate Mixtures with Tetraethylene Glycol Sarkar, Abhra; Trivedi, Shruti; Baker, Gary A. The Journal of Physical Chemistry B, Vol. 112, Issue 47 https://doi.org/10.1021/jp804591q	journal	October 2008

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