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Title: A stepwise transition from microporosity to mesoporosity in metal–organic frameworks by thermal treatment

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/c0sc00320d· OSTI ID:1380550
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Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001015
OSTI ID:
1380550
Journal Information:
Chemical Science, Vol. 2, Issue 1; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (37)

Tailored Porous Materials journal October 1999
Gas storage in porous metal–organic frameworks for clean energy applications journal January 2010
High Uptakes of CO 2 and CH 4 in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101 journal July 2008
A Mesoporous Metal–Organic Framework journal December 2009
Exceptionally high H2 storage by a metal–organic polyhedral framework journal January 2009
Mesoporous Metal–Organic Framework with Rare etb Topology for Hydrogen Storage and Dye Assembly journal September 2007
Silica-Based Mesoporous Organic–Inorganic Hybrid Materials journal May 2006
Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks journal February 2008
Recent Advances in Processing and Characterization of Periodic Mesoporous MCM-41 Silicate Molecular Sieves journal June 2001
High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites journal February 2009
A Mesoporous Metal−Organic Framework with Permanent Porosity journal December 2006
A short history of SHELX journal December 2007
The current status of hydrogen storage in metal–organic frameworks journal January 2008
Crystallized Frameworks with Giant Pores:  Are There Limits to the Possible? journal April 2005
Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows journal July 2009
A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst journal August 2002
Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn 2+ Coordination Sites journal December 2006
Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal−Organic Frameworks journal March 2009
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area journal September 2005
Ordered porous materials for emerging applications journal June 2002
Crystal Structure and Guest Uptake of a Mesoporous Metal–Organic Framework Containing Cages of 3.9 and 4.7 nm in Diameter journal November 2007
Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs journal May 2008
On the Controllable Soft-Templating Approach to Mesoporous Silicates journal July 2007
Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis journal November 2009
Mesopore-Modified Zeolites:  Preparation, Characterization, and Applications journal March 2006
Single-crystal structure validation with the program PLATON journal January 2003
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature journal December 2005
From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis journal October 1997
Hierarchically Micro- and Mesoporous Metal-Organic Frameworks with Tunable Porosity journal November 2008
Hydrogen Storage in Microporous Metal-Organic Frameworks journal May 2003
Selective gas adsorption and separation in metal–organic frameworks journal January 2009
Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology journal May 2009
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) journal January 1985
A Porous Coordination Copolymer with over 5000 m 2 /g BET Surface Area journal April 2009
Porous Chromium Terephthalate MIL-101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis journal May 2009
Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake journal January 2008
A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal January 2008

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