Microphysical explanation of the RH-dependent water affinity of biogenic organic aerosol and its importance for climate

Rastak, N.; Pajunoja, A.; Acosta Navarro, J. C.; Ma, J.; Song, M.; Partridge, D. G.; Kirkevåg, A.; Leong, Y.; Hu, W. W.; Taylor, N. F.; Lambe, A.; Cerully, K.; Bougiatioti, A.; Liu, P.; Krejci, R.; Petäjä, T.; Percival, C.; Davidovits, P.; Worsnop, D. R.; Ekman, A. M. L.; Nenes, A.; Martin, S.; Jimenez, J. L.; Collins, D. R.; Topping, D. O.; Bertram, A. K.; Zuend, A.; Virtanen, A.; Riipinen, I.

doi:10.1002/2017GL073056

Title: Microphysical explanation of the RH-dependent water affinity of biogenic organic aerosol and its importance for climate

Journal Article · Sun May 21 00:00:00 EDT 2017 · Geophysical Research Letters

DOI:https://doi.org/10.1002/2017GL073056· OSTI ID:1358118

Rastak, N. ^[1];

^[2];

^[1];

^[3]; Song, M. ^[4]; Partridge, D. G. ^[1]; Kirkevåg, A. ^[5];

^[6];

^[7]; Taylor, N. F. ^[8]; Lambe, A. ^[9]; Cerully, K. ^[10];

^[11]; Liu, P. ^[12];

^[1]; Petäjä, T. ^[13];

^[14]; Davidovits, P. ^[15]; Worsnop, D. R. ^[16];

^[17] more »

Department of Environmental Science and Analytical Chemistry (ACES) and Bolin Centre for Climate research, Stockholm University, Stockholm Sweden
Department of Applied Physics, University of Eastern Finland, Kuopio Finland
Department of Atmospheric and Oceanic Sciences, McGill University, Montreal Quebec Canada
Department of Earth and Environmental Sciences, Chonbuk National University, Jeonju Republic of Korea, Department of Chemistry, University of British Columbia, Vancouver British Columbia Canada
Norwegian Meteorological Institute, Oslo Norway
Department of Applied Physics, University of Eastern Finland, Kuopio Finland, Department of Civil and Environmental Engineering, Rice University, Houston Texas USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder Colorado USA, Department of Chemistry and Biochemistry, University of Colorado, Boudler Colorado USA
Department of Atmospheric Sciences, Texas A&M University, College Station Texas USA
Aerodyne Research Inc., Billerica Massachusetts USA, Department of Chemistry, Boston College, Chestnut Hill Massachusetts USA
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta Georgia USA
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta Georgia USA, Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Palea Penteli Greece
School of Engineering and Applied Sciences, Harvard University, Cambridge Massachusetts USA
Department of Physics, University of Helsinki, Helsinki Finland
School of Earth and Environmental Sciences, University of Manchester, Manchester UK
Department of Chemistry, Boston College, Chestnut Hill Massachusetts USA
Aerodyne Research Inc., Billerica Massachusetts USA
Department of Meteorology, Stockholm University, Stockholm Sweden
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta Georgia USA, School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta Georgia USA, Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Palea Penteli Greece, Institute of Chemical Engineering Sciences, Foundation for Research and Technology-Hellas, Patras Greece
School of Earth and Environmental Sciences, University of Manchester, Manchester UK, National Centre for Atmospheric Science (NCAS), University of Manchester, Manchester UK
Department of Chemistry, University of British Columbia, Vancouver British Columbia Canada

A large fraction of atmospheric organic aerosol (OA) originates from natural emissions that are oxidized in the atmosphere to form secondary organic aerosol (SOA). Isoprene (IP) and monoterpenes (MT) are the most important precursors of SOA originating from forests. The climate impacts from OA are currently estimated through parameterizations of water uptake that drastically simplify the complexity of OA. We combine laboratory experiments, thermodynamic modeling, field observations, and climate modeling to (1) explain the molecular mechanisms behind RH-dependent SOA water-uptake with solubility and phase separation; (2) show that laboratory data on IP- and MT-SOA hygroscopicity are representative of ambient data with corresponding OA source profiles; and (3) demonstrate the sensitivity of the modeled aerosol climate effect to assumed OA water affinity. We conclude that the commonly used single-parameter hygroscopicity framework can introduce significant error when quantifying the climate effects of organic aerosol. The results highlight the need for better constraints on the overall global OA mass loadings and its molecular composition, including currently underexplored anthropogenic and marine OA sources.

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of Colorado, Boulder, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: SC0016559; SC0012792

OSTI ID:: 1358118

Alternate ID(s):: OSTI ID: 1377937; OSTI ID: 1429324

Journal Information:: Geophysical Research Letters, Journal Name: Geophysical Research Letters; ISSN 0094-8276

Publisher:: American Geophysical UnionCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 64 works

Citation information provided by
Web of Science

References (81)

Prediction of cloud condensation nuclei activity for organic compounds using functional group contribution methods Petters, M. D.; Kreidenweis, S. M.; Ziemann, P. J. Geoscientific Model Development, Vol. 9, Issue 1 https://doi.org/10.5194/gmd‐9‐111‐2016	journal	January 2016
M7: An efficient size-resolved aerosol microphysics module for large-scale aerosol transport models: AEROSOL MICROPHYSICS MODULE Vignati, Elisabetta; Wilson, Julian; Stier, Philip Journal of Geophysical Research: Atmospheres, Vol. 109, Issue D22 https://doi.org/10.1029/2003JD004485	journal	November 2004
Physical Adsorption on Non‐Uniform Surfaces Halsey, George The Journal of Chemical Physics, Vol. 16, Issue 10 https://doi.org/10.1063/1.1746689	journal	October 1948
Liquid-liquid phase separation in aerosol particles: Dependence on O:C, organic functionalities, and compositional complexity: PHASE SEPARATION Song, M.; Marcolli, C.; Krieger, U. K. Geophysical Research Letters, Vol. 39, Issue 19 https://doi.org/10.1029/2012GL052807	journal	October 2012
Large contribution of natural aerosols to uncertainty in indirect forcing Carslaw, K. S.; Lee, L. A.; Reddington, C. L. Nature, Vol. 503, Issue 7474 https://doi.org/10.1038/nature12674	journal	November 2013
Known and Unexplored Organic Constituents in the Earth's Atmosphere Goldstein, Allen H.; Galbally, Ian E. Environmental Science & Technology, Vol. 41, Issue 5 https://doi.org/10.1021/es072476p	journal	March 2007
Hygroscopicity, CCN and volatility properties of submicron atmospheric aerosol in a boreal forest environment during the summer of 2010 Hong, J.; Häkkinen, S. A. K.; Paramonov, M. Atmospheric Chemistry and Physics, Vol. 14, Issue 9 https://doi.org/10.5194/acp‐14‐4733‐2014	journal	January 2014
Formation and evolution of molecular products in α-pinene secondary organic aerosol Zhang, Xuan; McVay, Renee C.; Huang, Dan D. Proceedings of the National Academy of Sciences, Vol. 112, Issue 46 https://doi.org/10.1073/pnas.1517742112	journal	November 2015
Ultraviolet and visible complex refractive indices of secondary organic material produced by photooxidation of the aromatic compounds toluene and m -xylene Liu, P. F.; Abdelmalki, N.; Hung, H. -M. Atmospheric Chemistry and Physics, Vol. 15, Issue 3 https://doi.org/10.5194/acp‐15‐1435‐2015	journal	January 2015
Connecting the solubility and CCN activation of complex organic aerosols: a theoretical study using solubility distributions Riipinen, I.; Rastak, N.; Pandis, S. N. Atmospheric Chemistry and Physics, Vol. 15, Issue 11 https://doi.org/10.5194/acp-15-6305-2015	journal	January 2015
ISORROPIA: A New Thermodynamic Equilibrium Model for Multiphase Multicomponent Inorganic Aerosols Nenes, Athanasios; Pandis, Spyros N.; Pilinis, Christodoulos Aquatic Geochemistry, Vol. 4, Issue 1, p. 123-152 https://doi.org/10.1023/A:1009604003981	journal	March 1998
Parameterization of cloud droplet formation for global and regional models: including adsorption activation from insoluble CCN Kumar, P.; Sokolik, I. N.; Nenes, A. Atmospheric Chemistry and Physics, Vol. 9, Issue 7 https://doi.org/10.5194/acp-9-2517-2009	journal	January 2009
Discontinuities in hygroscopic growth below and above water saturation for laboratory surrogates of oligomers in organic atmospheric aerosols Hodas, Natasha; Zuend, Andreas; Schilling, Katherine Atmospheric Chemistry and Physics, Vol. 16, Issue 19 https://doi.org/10.5194/acp‐16‐12767‐2016	journal	January 2016
An interfacial mechanism for cloud droplet formation on organic aerosols Ruehl, C. R.; Davies, J. F.; Wilson, K. R. Science, Vol. 351, Issue 6280 https://doi.org/10.1126/science.aad4889	journal	March 2016
Predicting Particle Critical Supersaturation from Hygroscopic Growth Measurements in the Humidified TDMA. Part I: Theory and Sensitivity Studies Brechtel, Fred J.; Kreidenweis, Sonia M. Journal of the Atmospheric Sciences, Vol. 57, Issue 12 https://doi.org/10.1175/1520-0469(2000)057<1854:PPCSFH>2.0.CO;2	journal	June 2000
The Norwegian Earth System Model, NorESM1-M – Part 1: Description and basic evaluation of the physical climate Bentsen, M.; Bethke, I.; Debernard, J. B. Geoscientific Model Development, Vol. 6, Issue 3 https://doi.org/10.5194/gmd‐6‐687‐2013	journal	January 2013
A Rigorous Test for SPARC's Chemical Reactivity Models: Estimation of More Than 4300 Ionization pK _a s Hilal, S. H.; Karickhoff, S. W.; Carreira, L. A. Quantitative Structure-Activity Relationships, Vol. 14, Issue 4 https://doi.org/10.1002/qsar.19950140405	journal	January 1995
Physical Adsorption and the Free Volume Model for Liquids Hill, Terrell L. The Journal of Chemical Physics, Vol. 17, Issue 6 https://doi.org/10.1063/1.1747341	journal	June 1949
Aerosol–climate interactions in the Norwegian Earth System Model – NorESM1-M Kirkevåg, A.; Iversen, T.; Seland, Ø. Geoscientific Model Development, Vol. 6, Issue 1 https://doi.org/10.5194/gmd‐6‐207‐2013	journal	January 2013
Measurements of cloud condensation nuclei activity and droplet activation kinetics of fresh unprocessed regional dust samples and minerals Kumar, P.; Sokolik, I. N.; Nenes, A. Atmospheric Chemistry and Physics, Vol. 11, Issue 7 https://doi.org/10.5194/acp‐11‐3527‐2011	journal	January 2011
Cloud Nucleation on Insoluble Particles McDonald, J. E. Journal of the Atmospheric Sciences, Vol. 21, Issue 1 https://doi.org/10.1175/1520-0469(1964)021<0109:CNOIP>2.0.CO;2	journal	January 1964
The effect of H<sub>2</sub>O adsorption on cloud drop activation of insoluble particles: a theoretical framework Sorjamaa, R.; Laaksonen, A. Atmospheric Chemistry and Physics, Vol. 7, Issue 24 https://doi.org/10.5194/acp-7-6175-2007	journal	January 2007
Laboratory studies of the chemical composition and cloud condensation nuclei (CCN) activity of secondary organic aerosol (SOA) and oxidized primary organic aerosol (OPOA) Lambe, A. T.; Onasch, T. B.; Massoli, P. Atmospheric Chemistry and Physics, Vol. 11, Issue 17 https://doi.org/10.5194/acp-11-8913-2011	journal	January 2011
Surface Partitioning in Organic–Inorganic Mixtures Contributes to the Size-Dependence of the Phase-State of Atmospheric Nanoparticles Werner, Josephina; Dalirian, Maryam; Walz, Marie-Madeleine Environmental Science & Technology, Vol. 50, Issue 14 https://doi.org/10.1021/acs.est.6b00789	journal	July 2016
Formation and occurrence of dimer esters of pinene oxidation products in atmospheric aerosols Kristensen, K.; Enggrob, K. L.; King, S. M. Atmospheric Chemistry and Physics, Vol. 13, Issue 7 https://doi.org/10.5194/acp-13-3763-2013	journal	January 2013
Observations and implications of liquid–liquid phase separation at high relative humidities in secondary organic material produced by α -pinene ozonolysis without inorganic salts Renbaum-Wolff, Lindsay; Song, Mijung; Marcolli, Claudia Atmospheric Chemistry and Physics, Vol. 16, Issue 12 https://doi.org/10.5194/acp-16-7969-2016	journal	January 2016
Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements Hu, W. W.; Campuzano-Jost, P.; Palm, B. B. Atmospheric Chemistry and Physics, Vol. 15, Issue 20 https://doi.org/10.5194/acp‐15‐11807‐2015	journal	January 2015
EVAPORATION: a new vapour pressure estimation methodfor organic molecules including non-additivity and intramolecular interactions Compernolle, S.; Ceulemans, K.; Müller, J. -F. Atmospheric Chemistry and Physics, Vol. 11, Issue 18 https://doi.org/10.5194/acp‐11‐9431‐2011	journal	January 2011
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd‐5‐1471‐2012	journal	January 2012
Seasonal variation of VOC concentrations above a boreal coniferous forest Hakola, H.; Tarvainen, V.; Laurila, T. Atmospheric Environment, Vol. 37, Issue 12 https://doi.org/10.1016/S1352-2310(03)00014-1	journal	April 2003
A Continuous-Flow Streamwise Thermal-Gradient CCN Chamber for Atmospheric Measurements Roberts, G. C.; Nenes, A. Aerosol Science and Technology, Vol. 39, Issue 3 https://doi.org/10.1080/027868290913988	journal	March 2005
Determination of the biogenic secondary organic aerosol fraction in the boreal forest by NMR spectroscopy Finessi, E.; Decesari, S.; Paglione, M. Atmospheric Chemistry and Physics, Vol. 12, Issue 2 https://doi.org/10.5194/acp‐12‐941‐2012	journal	January 2012
A simplified description of the evolution of organic aerosol composition in the atmosphere: VAN KREVELEN DIAGRAM OF ORGANIC AEROSOL Heald, C. L.; Kroll, J. H.; Jimenez, J. L. Geophysical Research Letters, Vol. 37, Issue 8 https://doi.org/10.1029/2010GL042737	journal	April 2010
Phase state of ambient aerosol linked with water uptake and chemical aging in the southeastern US Pajunoja, Aki; Hu, Weiwei; Leong, Yu J. Atmospheric Chemistry and Physics, Vol. 16, Issue 17 https://doi.org/10.5194/acp-16-11163-2016	journal	January 2016
The AeroCom evaluation and intercomparison of organic aerosol in global models Tsigaridis, K.; Daskalakis, N.; Kanakidou, M. Atmospheric Chemistry and Physics, Vol. 14, Issue 19 https://doi.org/10.5194/acp‐14‐10845‐2014	journal	January 2014
Role of nucleation mechanism on the size dependent morphology of organic aerosol Altaf, Muhammad Bilal; Zuend, Andreas; Freedman, Miriam Arak Chemical Communications, Vol. 52, Issue 59 https://doi.org/10.1039/C6CC03826C	journal	January 2016
The ERA-Interim reanalysis: configuration and performance of the data assimilation system Dee, D. P.; Uppala, S. M.; Simmons, A. J. Quarterly Journal of the Royal Meteorological Society, Vol. 137, Issue 656 https://doi.org/10.1002/qj.828	journal	April 2011
Saturation Vapor Pressures and Transition Enthalpies of Low-Volatility Organic Molecules of Atmospheric Relevance: From Dicarboxylic Acids to Complex Mixtures Bilde, Merete; Barsanti, Kelley; Booth, Murray Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr5005502	journal	February 2015
On the link between hygroscopicity, volatility, and oxidation state of ambient and water-soluble aerosols in the southeastern United States Cerully, K. M.; Bougiatioti, A.; Hite, J. R. Atmospheric Chemistry and Physics, Vol. 15, Issue 15 https://doi.org/10.5194/acp‐15‐8679‐2015	journal	January 2015
Atmospheric component of the MPI-M Earth System Model: ECHAM6: ECHAM6 Stevens, Bjorn; Giorgetta, Marco; Esch, Monika Journal of Advances in Modeling Earth Systems, Vol. 5, Issue 2 https://doi.org/10.1002/jame.20015	journal	April 2013
O/C and OM/OC Ratios of Primary, Secondary, and Ambient Organic Aerosols with High-Resolution Time-of-Flight Aerosol Mass Spectrometry Aiken, Allison C.; DeCarlo, Peter F.; Kroll, Jesse H. Environmental Science & Technology, Vol. 42, Issue 12 https://doi.org/10.1021/es703009q	journal	June 2008
Introducing the concept of Potential Aerosol Mass (PAM) Kang, E.; Root, M. J.; Toohey, D. W. Atmospheric Chemistry and Physics, Vol. 7, Issue 22 https://doi.org/10.5194/acp-7-5727-2007	journal	January 2007
Analysis of CCN activity of Arctic aerosol and Canadian biomass burning during summer 2008 Lathem, T. L.; Beyersdorf, A. J.; Thornhill, K. L. Atmospheric Chemistry and Physics, Vol. 13, Issue 5 https://doi.org/10.5194/acp-13-2735-2013	journal	January 2013
Physicochemical properties and origin of organic groups detected in boreal forest using an aerosol mass spectrometer Raatikainen, T.; Vaattovaara, P.; Tiitta, P. Atmospheric Chemistry and Physics, Vol. 10, Issue 4 https://doi.org/10.5194/acp‐10‐2063‐2010	journal	January 2010
Reactive intermediates revealed in secondary organic aerosol formation from isoprene Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C. Proceedings of the National Academy of Sciences, Vol. 107, Issue 15 https://doi.org/10.1073/pnas.0911114107	journal	December 2009
Liquid–liquid phase separation in atmospherically relevant particles consisting of organic species and inorganic salts You, Yuan; Smith, Mackenzie L.; Song, Mijung International Reviews in Physical Chemistry, Vol. 33, Issue 1 https://doi.org/10.1080/0144235X.2014.890786	journal	January 2014
The Norwegian Earth System Model, NorESM1-M – Part 2: Climate response and scenario projections Iversen, T.; Bentsen, M.; Bethke, I. Geoscientific Model Development, Vol. 6, Issue 2 https://doi.org/10.5194/gmd‐6‐389‐2013	journal	January 2013
Evolution of Organic Aerosols in the Atmosphere Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M. Science, Vol. 326, Issue 5959 https://doi.org/10.1126/science.1180353	journal	December 2009
Sensitivity studies of different aerosol indirect effects in mixed-phase clouds Lohmann, U.; Hoose, C. Atmospheric Chemistry and Physics, Vol. 9, Issue 22 https://doi.org/10.5194/acp‐9‐8917‐2009	journal	January 2009
Size Dependence of the Structure of Organic Aerosol Veghte, Daniel P.; Altaf, Muhammad Bilal; Freedman, Miriam Arak Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja408903g	journal	October 2013
Computation of liquid-liquid equilibria and phase stabilities: implications for RH-dependent gas/particle partitioning of organic-inorganic aerosols Zuend, A.; Marcolli, C.; Peter, T. Atmospheric Chemistry and Physics, Vol. 10, Issue 16 https://doi.org/10.5194/acp‐10‐7795‐2010	journal	January 2010
The analysis of size-segregated cloud condensation nuclei counter (CCNC) data and its implications for cloud droplet activation Paramonov, M.; Aalto, P. P.; Asmi, A. Atmospheric Chemistry and Physics, Vol. 13, Issue 20 https://doi.org/10.5194/acp-13-10285-2013	journal	January 2013
A single parameter representation of hygroscopic growth and cloud condensation nucleus activity Petters, M. D.; Kreidenweis, S. M. Atmospheric Chemistry and Physics, Vol. 7, Issue 8 https://doi.org/10.5194/acp-7-1961-2007	journal	January 2007
The sensitivity of Secondary Organic Aerosol component partitioning to the predictions of component properties – Part 2: Determination of particle hygroscopicity and its dependence on "apparent" volatility Topping, D. O.; Barley, M. H.; McFiggans, G. Atmospheric Chemistry and Physics, Vol. 11, Issue 15 https://doi.org/10.5194/acp-11-7767-2011	journal	January 2011
Cryo-Transmission Electron Microscopy Imaging of the Morphology of Submicrometer Aerosol Containing Organic Acids and Ammonium Sulfate Veghte, Daniel P.; Bittner, Danielle Rae; Freedman, Miriam Arak Analytical Chemistry, Vol. 86, Issue 5 https://doi.org/10.1021/ac403279f	journal	February 2014
Particle-Phase Chemistry of Secondary Organic Material: Modeled Compared to Measured O:C and H:C Elemental Ratios Provide Constraints Chen, Qi; Liu, Yingjun; Donahue, Neil M. Environmental Science & Technology, Vol. 45, Issue 11 https://doi.org/10.1021/es104398s	journal	June 2011
Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer DeCarlo, Peter F.; Kimmel, Joel R.; Trimborn, Achim Analytical Chemistry, Vol. 78, Issue 24 https://doi.org/10.1021/ac061249n	journal	December 2006
Size dependence of phase transitions in aerosol nanoparticles Cheng, Yafang; Su, Hang; Koop, Thomas Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6923	journal	January 2015
Predicting the relative humidities of liquid-liquid phase separation, efflorescence, and deliquescence of mixed particles of ammonium sulfate, organic material, and water using the organic-to-sulfate mass ratio of the particle and the oxygen-to-carbon elemental ratio of the organic component Bertram, A. K.; Martin, S. T.; Hanna, S. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp‐11‐10995‐2011	journal	January 2011
Modeling the gas-particle partitioning of secondary organic aerosol: the importance of liquid-liquid phase separation Zuend, A.; Seinfeld, J. H. Atmospheric Chemistry and Physics, Vol. 12, Issue 9 https://doi.org/10.5194/acp-12-3857-2012	journal	January 2012
An amorphous solid state of biogenic secondary organic aerosol particles Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas Nature, Vol. 467, Issue 7317 https://doi.org/10.1038/nature09455	journal	October 2010
Fine-particle water and pH in the southeastern United States Guo, H.; Xu, L.; Bougiatioti, A. Atmospheric Chemistry and Physics, Vol. 15, Issue 9 https://doi.org/10.5194/acp‐15‐5211‐2015	journal	January 2015
Novel methods for predicting gas–particle partitioning during the formation of secondary organic aerosol Wania, F.; Lei, Y. D.; Wang, C. Atmospheric Chemistry and Physics, Vol. 14, Issue 23 https://doi.org/10.5194/acp-14-13189-2014	journal	January 2014
Towards closing the gap between hygroscopic growth and activation for secondary organic aerosol: Part 1 – Evidence from measurements Wex, H.; Petters, M. D.; Carrico, C. M. Atmospheric Chemistry and Physics, Vol. 9, Issue 12 https://doi.org/10.5194/acp-9-3987-2009	journal	January 2009
Surface/bulk partitioning and acid/base speciation of aqueous decanoate: direct observations and atmospheric implications Prisle, N. L.; Ottosson, N.; Öhrwall, G. Atmospheric Chemistry and Physics, Vol. 12, Issue 24 https://doi.org/10.5194/acp‐12‐12227‐2012	journal	January 2012
Speciation of OH reactivity above the canopy of an isoprene-dominated forest Kaiser, J.; Skog, K. M.; Baumann, K. Atmospheric Chemistry and Physics, Vol. 16, Issue 14 https://doi.org/10.5194/acp‐16‐9349‐2016	journal	January 2016
Cloud activation of single-component organic aerosol particles Raymond, Timothy M. Journal of Geophysical Research, Vol. 107, Issue D24 https://doi.org/10.1029/2002JD002159	journal	January 2002
Exploring the complexity of aerosol particle properties and processes using single particle techniques Krieger, Ulrich K.; Marcolli, Claudia; Reid, Jonathan P. Chemical Society Reviews, Vol. 41, Issue 19 https://doi.org/10.1039/c2cs35082c	journal	January 2012
Understanding the contributions of aerosol properties and parameterization discrepancies to droplet number variability in a global climate model Morales Betancourt, R.; Nenes, A. Atmospheric Chemistry and Physics, Vol. 14, Issue 9 https://doi.org/10.5194/acp-14-4809-2014	journal	January 2014
A parameterization of aerosol activation: 2. Multiple aerosol types Abdul-Razzak, Hayder; Ghan, Steven J. Journal of Geophysical Research: Atmospheres, Vol. 105, Issue D5 https://doi.org/10.1029/1999JD901161	journal	March 2000
The nucleus in and the growth of hygroscopic droplets Köhler, Hilding Trans. Faraday Soc., Vol. 32, Issue 0 https://doi.org/10.1039/TF9363201152	journal	January 1936
Global indirect aerosol effects: a review Lohmann, U.; Feichter, J. Atmospheric Chemistry and Physics, Vol. 5, Issue 3 https://doi.org/10.5194/acp‐5‐715‐2005	journal	January 2005
Adsorptive uptake of water by semisolid secondary organic aerosols: Water uptake of SOA Pajunoja, Aki; Lambe, Andrew T.; Hakala, Jani Geophysical Research Letters, Vol. 42, Issue 8 https://doi.org/10.1002/2015GL063142	journal	April 2015
Comprehensively accounting for the effect of giant CCN in cloud activation parameterizations Barahona, D.; West, R. E. L.; Stier, P. Atmospheric Chemistry and Physics, Vol. 10, Issue 5 https://doi.org/10.5194/acp‐10‐2467‐2010	journal	January 2010
Improving our fundamental understanding of the role of aerosol−cloud interactions in the climate system Seinfeld, John H.; Bretherton, Christopher; Carslaw, Kenneth S. Proceedings of the National Academy of Sciences, Vol. 113, Issue 21 https://doi.org/10.1073/pnas.1514043113	journal	May 2016
Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H. Atmospheric Chemistry and Physics, Vol. 15, Issue 1 https://doi.org/10.5194/acp‐15‐253‐2015	journal	January 2015
Online coupled regional meteorology chemistry models in Europe: current status and prospects Baklanov, A.; Schlünzen, K.; Suppan, P. Atmospheric Chemistry and Physics, Vol. 14, Issue 1 https://doi.org/10.5194/acp‐14‐317‐2014	journal	January 2014
Cloud condensation nuclei activity and droplet activation kinetics of wet processed regional dust samples and minerals Kumar, P.; Sokolik, I. N.; Nenes, A. Atmospheric Chemistry and Physics, Vol. 11, Issue 16 https://doi.org/10.5194/acp-11-8661-2011	journal	January 2011
The global aerosol-climate model ECHAM-HAM, version 2: sensitivity to improvements in process representations Zhang, K.; O'Donnell, D.; Kazil, J. Atmospheric Chemistry and Physics, Vol. 12, Issue 19 https://doi.org/10.5194/acp‐12‐8911‐2012	journal	January 2012
Cloud droplet activation of secondary organic aerosol: CLOUD DROPLET ACTIVATION Prenni, Anthony J.; Petters, Markus D.; Kreidenweis, Sonia M. Journal of Geophysical Research: Atmospheres, Vol. 112, Issue D10 https://doi.org/10.1029/2006JD007963	journal	May 2007
A practical method for the calculation of liquid–liquid equilibria in multicomponent organic–water–electrolyte systems using physicochemical constraints Zuend, Andreas; Seinfeld, John H. Fluid Phase Equilibria, Vol. 337 https://doi.org/10.1016/j.fluid.2012.09.034	journal	January 2013

Similar Records

Constraining nucleation, condensation, and chemistry in oxidation flow reactors using size-distribution measurements and aerosol microphysical modeling

Journal Article · Tue Aug 28 00:00:00 EDT 2018 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1358118

Hodshire, Anna L.; Palm, Brett B.; Alexander, M. Lizabeth; +18 more

Investigating Secondary Aerosol Processes in the Amazon through Molecular-level Characterization of Semi-Volatile Organics

Technical Report · Thu Oct 01 00:00:00 EDT 2020 · OSTI ID:1358118

Yee, Lindsay D.; Goldstein, Allen H.; Kreisberg, Nathan M.

Modeling Organic Aerosols during MILAGRO: Application of the CHIMERE Model and Importance of Biogenic Secondary Organic Aerosols

Journal Article · Tue Sep 22 00:00:00 EDT 2009 · Atmospheric Chemistry and Physics, 9(18):6949-6981 · OSTI ID:1358118

Hodzic, Alma; Jimenez, Jose L; Madronich, Sasha; +9 more

Related Subjects

54 ENVIRONMENTAL SCIENCES
atmospheric aerosol
secondary organic aerosol
hygroscopicity
aerosol-water interactions
aerosol-climate interactions

Title: Microphysical explanation of the RH-dependent water affinity of biogenic organic aerosol and its importance for climate

Citation Formats

References (81)

Similar Records

Related Subjects