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Title: From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework

Abstract

A stable framework has been constructed through multiple charge-assisted H-bonds between cationic coordination cages and chloride ions. The framework maintained its original structure upon desolvation, which has been established by single-crystal structure analysis. This is the first fully characterized stable porous framework based on coordination cages after desolvation, with a moderately high Brunauer–Emmett–Teller (BET) surface area of 1201 m2 g-1. This work will not only give a light to construct stable porous frameworks based on coordination cages and thus broaden their applications, but will also provide a new avenue to the assembly of other porous materials such as porous organic cages and hydrogen-bonded organic frameworks (HOFs) through non covalent bonds.

Authors:
 [1];  [1];  [2]; ORCiD logo [1]; ORCiD logo [3]
  1. State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou 350002 P. R. China
  2. ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, Argonne Illinois 60439 USA
  3. Department of Chemistry, University of Texas at San Antonio, San Antonio Texas 78249-0698 USA
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
FOREIGN
OSTI Identifier:
1377922
Resource Type:
Journal Article
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Volume: 23; Journal Issue: 20; Journal ID: ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Ju, Zhanfeng, Liu, Guoliang, Chen, Yu-Sheng, Yuan, Daqiang, and Chen, Banglin. From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework. United States: N. p., 2017. Web. doi:10.1002/chem.201700798.
Ju, Zhanfeng, Liu, Guoliang, Chen, Yu-Sheng, Yuan, Daqiang, & Chen, Banglin. From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework. United States. doi:10.1002/chem.201700798.
Ju, Zhanfeng, Liu, Guoliang, Chen, Yu-Sheng, Yuan, Daqiang, and Chen, Banglin. Mon . "From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework". United States. doi:10.1002/chem.201700798.
@article{osti_1377922,
title = {From Coordination Cages to a Stable Crystalline Porous Hydrogen-Bonded Framework},
author = {Ju, Zhanfeng and Liu, Guoliang and Chen, Yu-Sheng and Yuan, Daqiang and Chen, Banglin},
abstractNote = {A stable framework has been constructed through multiple charge-assisted H-bonds between cationic coordination cages and chloride ions. The framework maintained its original structure upon desolvation, which has been established by single-crystal structure analysis. This is the first fully characterized stable porous framework based on coordination cages after desolvation, with a moderately high Brunauer–Emmett–Teller (BET) surface area of 1201 m2 g-1. This work will not only give a light to construct stable porous frameworks based on coordination cages and thus broaden their applications, but will also provide a new avenue to the assembly of other porous materials such as porous organic cages and hydrogen-bonded organic frameworks (HOFs) through non covalent bonds.},
doi = {10.1002/chem.201700798},
journal = {Chemistry - A European Journal},
issn = {0947-6539},
number = 20,
volume = 23,
place = {United States},
year = {2017},
month = {3}
}

Works referenced in this record:

Nanoporous Organics Enter the Cage Age
journal, December 2010


A Robust Binary Supramolecular Organic Framework (SOF) with High CO 2 Adsorption and Selectivity
journal, September 2014

  • Lü, Jian; Perez-Krap, Cristina; Suyetin, Mikhail
  • Journal of the American Chemical Society, Vol. 136, Issue 37
  • DOI: 10.1021/ja506577g

Organic cage compounds – from shape-persistency to function
journal, January 2014

  • Zhang, Gang; Mastalerz, Michael
  • Chem. Soc. Rev., Vol. 43, Issue 6
  • DOI: 10.1039/C3CS60358J

Retikuläre Chemie metall‐organischer Polyeder
journal, June 2008

  • Tranchemontagne, David J.; Ni, Zheng; O'Keeffe, Michael
  • Angewandte Chemie, Vol. 120, Issue 28
  • DOI: 10.1002/ange.200705008

A C 3 -Symmetric Macrocycle-Based, Hydrogen-Bonded, Multiporous Hexagonal Network as a Motif of Porous Molecular Crystals
journal, January 2015

  • Hisaki, Ichiro; Nakagawa, Shoichi; Tohnai, Norimitsu
  • Angewandte Chemie International Edition, Vol. 54, Issue 10
  • DOI: 10.1002/anie.201411438

A Permanent Mesoporous Organic Cage with an Exceptionally High Surface Area
journal, January 2014


Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005

  • Ni, Zheng; Yassar, Abderrahim; Antoun, Tarek
  • Journal of the American Chemical Society, Vol. 127, Issue 37, p. 12752-12753
  • DOI: 10.1021/ja052055c

Porous Metal−Organic Polyhedra:  25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks
journal, May 2001

  • Eddaoudi, M.; Kim, Jaheon; Wachter, J. B.
  • Journal of the American Chemical Society, Vol. 123, Issue 18, p. 4368-4369
  • DOI: 10.1021/ja0104352

In Situ Construction of a Coordination Zirconocene Tetrahedron
journal, November 2013

  • Liu, Guoliang; Ju, Zhanfeng; Yuan, Daqiang
  • Inorganic Chemistry, Vol. 52, Issue 24
  • DOI: 10.1021/ic402428m

Coordinative alignment of molecules in chiral metal-organic frameworks
journal, August 2016


Self-assembly of ten molecules into nanometre-sized organic host frameworks
journal, November 1995

  • Fujita, Makoto; Oguro, Daichi; Miyazawa, Mayumi
  • Nature, Vol. 378, Issue 6556, p. 469-471
  • DOI: 10.1038/378469a0

Metal–organic molecular cages: applications of biochemical implications
journal, January 2015

  • Ahmad, Nazir; Younus, Hussein A.; Chughtai, Adeel H.
  • Chemical Society Reviews, Vol. 44, Issue 1
  • DOI: 10.1039/C4CS00222A

A Microporous Hydrogen-Bonded Organic Framework: Exceptional Stability and Highly Selective Adsorption of Gas and Liquid
journal, July 2013

  • Luo, Xu-Zhong; Jia, Xin-Jian; Deng, Ji-Hua
  • Journal of the American Chemical Society, Vol. 135, Issue 32
  • DOI: 10.1021/ja403002m

A Metal–Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks
journal, April 2006

  • Sudik, Andrea C.; Côté, Adrien P.; Wong-Foy, Antek G.
  • Angewandte Chemie, Vol. 118, Issue 16, p. 2590-2595
  • DOI: 10.1002/ange.200600175

Interconversion between Molecular Polyhedra and Metal−Organic Frameworks
journal, May 2009

  • Li, Jian-Rong; Timmons, Daren J.; Zhou, Hong-Cai
  • Journal of the American Chemical Society, Vol. 131, Issue 18
  • DOI: 10.1021/ja901731z

Thermally robust and porous noncovalent organic framework with high affinity for fluorocarbons and CFCs
journal, October 2014

  • Chen, Teng-Hao; Popov, Ilya; Kaveevivitchai, Watchareeya
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6131

Exceptional Stability and High Hydrogen Uptake in Hydrogen-Bonded Metal−Organic Cubes Possessing ACO and AST Zeolite- like Topologies
journal, August 2009

  • Sava, Dorina F.; Kravtsov, Victor Ch.; Eckert, Juergen
  • Journal of the American Chemical Society, Vol. 131, Issue 30
  • DOI: 10.1021/ja903287v

Porous organic cages
journal, October 2009

  • Tozawa, Tomokazu; Jones, James T. A.; Swamy, Shashikala I.
  • Nature Materials, Vol. 8, Issue 12, p. 973-978
  • DOI: 10.1038/nmat2545

A Metal–Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks
journal, April 2006

  • Sudik, Andrea C.; Côté, Adrien P.; Wong-Foy, Antek G.
  • Angewandte Chemie International Edition, Vol. 45, Issue 16, p. 2528-2533
  • DOI: 10.1002/anie.200600175

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks
journal, February 2008

  • Nouar, Farid; Eubank, Jarrod F.; Bousquet, Till
  • Journal of the American Chemical Society, Vol. 130, Issue 6
  • DOI: 10.1021/ja710123s

A Homochiral Microporous Hydrogen-Bonded Organic Framework for Highly Enantioselective Separation of Secondary Alcohols
journal, January 2014

  • Li, Peng; He, Yabing; Guang, Jie
  • Journal of the American Chemical Society, Vol. 136, Issue 2
  • DOI: 10.1021/ja4129795

Enhancing H 2 Uptake by “Close-Packing” Alignment of Open Copper Sites in Metal-Organic Frameworks
journal, September 2008

  • Wang, Xi-Sen; Ma, Shengqian; Forster, Paul M.
  • Angewandte Chemie International Edition, Vol. 47, Issue 38
  • DOI: 10.1002/anie.200802087

Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
  • DOI: 10.1021/ja042802q

Nanoporöse organische Festkörper im Zeichen des Käfigs
journal, December 2010


Assembly of metal–organic polyhedra into highly porous frameworks for ethene delivery
journal, January 2015

  • Stoeck, Ulrich; Senkovska, Irena; Bon, Volodymyr
  • Chemical Communications, Vol. 51, Issue 6
  • DOI: 10.1039/C4CC07920E

A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake
journal, January 2012

  • Stoeck, Ulrich; Krause, Simon; Bon, Volodymyr
  • Chemical Communications, Vol. 48, Issue 88
  • DOI: 10.1039/c2cc34840c

Rational Construction of an Extrinsic Porous Molecular Crystal with an Extraordinary High Specific Surface Area
journal, March 2012

  • Mastalerz, Michael; Oppel, Iris M.
  • Angewandte Chemie International Edition, Vol. 51, Issue 21
  • DOI: 10.1002/anie.201201174

A Flexible Microporous Hydrogen-Bonded Organic Framework for Gas Sorption and Separation
journal, July 2015

  • Wang, Hailong; Li, Bin; Wu, Hui
  • Journal of the American Chemical Society, Vol. 137, Issue 31
  • DOI: 10.1021/jacs.5b05644

A Salicylbisimine Cage Compound with High Surface Area and Selective CO2/CH4 Adsorption
journal, November 2010

  • Mastalerz, Michael; Schneider, Markus W.; Oppel, Iris M.
  • Angewandte Chemie International Edition, Vol. 50, Issue 5, p. 1046-1051
  • DOI: 10.1002/anie.201005301

Supramolecular Engineering of Intrinsic and Extrinsic Porosity in Covalent Organic Cages
journal, October 2011

  • Bojdys, Michael J.; Briggs, Michael E.; Jones, James T. A.
  • Journal of the American Chemical Society, Vol. 133, Issue 41
  • DOI: 10.1021/ja2056374

Self-assembled metal–organic polyhedra: An overview of various applications
journal, January 2016

  • Vardhan, Harsh; Yusubov, Mekhman; Verpoort, Francis
  • Coordination Chemistry Reviews, Vol. 306
  • DOI: 10.1016/j.ccr.2015.05.016

A Rod-Packing Microporous Hydrogen-Bonded Organic Framework for Highly Selective Separation of C 2 H 2 /CO 2 at Room Temperature
journal, November 2014


Modular and predictable assembly of porous organic molecular crystals
journal, June 2011

  • Jones, James T. A.; Hasell, Tom; Wu, Xiaofeng
  • Nature, Vol. 474, Issue 7351
  • DOI: 10.1038/nature10125

A Microporous Hydrogen-Bonded Organic Framework for Highly Selective C 2 H 2 /C 2 H 4 Separation at Ambient Temperature
journal, September 2011

  • He, Yabing; Xiang, Shengchang; Chen, Banglin
  • Journal of the American Chemical Society, Vol. 133, Issue 37
  • DOI: 10.1021/ja2066016

Enhancing H 2 Uptake by “Close-Packing” Alignment of Open Copper Sites in Metal-Organic Frameworks
journal, September 2008

  • Wang, Xi-Sen; Ma, Shengqian; Forster, Paul M.
  • Angewandte Chemie, Vol. 120, Issue 38
  • DOI: 10.1002/ange.200802087

Beyond Molecules: Mesoporous Supramolecular Frameworks Self-Assembled from Coordination Cages and Inorganic Anions
journal, April 2015

  • Luo, Dong; Zhou, Xiao-Ping; Li, Dan
  • Angewandte Chemie International Edition, Vol. 54, Issue 21
  • DOI: 10.1002/anie.201501081

Reticular Chemistry of Metal–Organic Polyhedra
journal, June 2008

  • Tranchemontagne, David J.; Ni, Zheng; O'Keeffe, Michael
  • Angewandte Chemie International Edition, Vol. 47, Issue 28, p. 5136-5147
  • DOI: 10.1002/anie.200705008

Insight into the construction of metal–organic polyhedra: metal–organic cubes as a case study
journal, January 2011

  • Alkordi, Mohamed H.; Belof, Jonathan L.; Rivera, Edwin
  • Chemical Science, Vol. 2, Issue 9
  • DOI: 10.1039/c1sc00269d

Eine Salicylbisimin-Käfigverbindung mit großer spezifischer Oberfläche und selektiver CO2/CH4-Adsorption
journal, November 2010

  • Mastalerz, Michael; Schneider, Markus W.; Oppel, Iris M.
  • Angewandte Chemie, Vol. 123, Issue 5
  • DOI: 10.1002/ange.201005301

A Permanent Mesoporous Organic Cage with an Exceptionally High Surface Area
journal, January 2014

  • Zhang, Gang; Presly, Oliver; White, Fraser
  • Angewandte Chemie International Edition, Vol. 53, Issue 6
  • DOI: 10.1002/anie.201308924

Rationale Herstellung eines extrinsisch porösen Molekülkristalls mit einer außergewöhnlich großen spezifischen Oberfläche
journal, March 2012


A C 3 -Symmetric Macrocycle-Based, Hydrogen-Bonded, Multiporous Hexagonal Network as a Motif of Porous Molecular Crystals
journal, February 2015

  • Hisaki, Ichiro; Nakagawa, Shoichi; Tohnai, Norimitsu
  • Angewandte Chemie, Vol. 127, Issue 10
  • DOI: 10.1002/ange.201411438