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Title: Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution

Abstract

A “bare” V 5+ complex with glutaroimide-dioxime (H 3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L) 2]2H 2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [3];  [3];  [3];  [1];  [2];  [1]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1377416
Alternate Identifier(s):
OSTI ID: 1337242
Report Number(s):
PNNL-SA-112588
Journal ID: ISSN 2041-6520; CSHCBM; AF5855000
Grant/Contract Number:  
AC05-76RL01830; AC02-05CH11231
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 4; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; vanadium; uranium; seawater; amidoxime; XRD

Citation Formats

Leggett, Christina J., Parker, Bernard F., Teat, Simon J., Zhang, Z., Dau, Phuong D., Lukens, Wayne W., Peterson, Sonja M., Cardenas, Allan J. P., Warner, Marvin G., Gibson, John K., Arnold, John, and Rao, Linfeng. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States: N. p., 2016. Web. doi:10.1039/c5sc03958d.
Leggett, Christina J., Parker, Bernard F., Teat, Simon J., Zhang, Z., Dau, Phuong D., Lukens, Wayne W., Peterson, Sonja M., Cardenas, Allan J. P., Warner, Marvin G., Gibson, John K., Arnold, John, & Rao, Linfeng. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States. doi:10.1039/c5sc03958d.
Leggett, Christina J., Parker, Bernard F., Teat, Simon J., Zhang, Z., Dau, Phuong D., Lukens, Wayne W., Peterson, Sonja M., Cardenas, Allan J. P., Warner, Marvin G., Gibson, John K., Arnold, John, and Rao, Linfeng. Thu . "Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution". United States. doi:10.1039/c5sc03958d. https://www.osti.gov/servlets/purl/1377416.
@article{osti_1377416,
title = {Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution},
author = {Leggett, Christina J. and Parker, Bernard F. and Teat, Simon J. and Zhang, Z. and Dau, Phuong D. and Lukens, Wayne W. and Peterson, Sonja M. and Cardenas, Allan J. P. and Warner, Marvin G. and Gibson, John K. and Arnold, John and Rao, Linfeng},
abstractNote = {A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.},
doi = {10.1039/c5sc03958d},
journal = {Chemical Science},
number = 4,
volume = 7,
place = {United States},
year = {Thu Jan 14 00:00:00 EST 2016},
month = {Thu Jan 14 00:00:00 EST 2016}
}

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Cited by: 19 works
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Works referenced in this record:

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976