Complications in complexation kinetics for lanthanides with DTPA using dye probe molecules in aqueous solution

Larsson, K.; Cullen, T. D.; Mezyk, S. P.; McDowell, R. G.; Martin, L. R.

doi:10.1039/C7RA04755J

Title: Complications in complexation kinetics for lanthanides with DTPA using dye probe molecules in aqueous solution

Journal Article · Wed May 17 00:00:00 EDT 2017 · RSC Advances

DOI:https://doi.org/10.1039/C7RA04755J· OSTI ID:1376481

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California State Univ. (CalState), Long Beach, CA (United States). Dept. of Chemistry and Biochemistry
Idaho National Lab. (INL), Idaho Falls, ID (United States). Aqueous Separations and Radiochemistry Dept.

The complexation kinetics for the polyaminopolycarboxylic ligand DTPA to lanthanides in acidic aqueous solution were investigated using the dye ligand displacement technique and stopped-flow spectroscopy. Significant rate differences were obtained for different dye probes used, indicating that the kinetics of the dissociation of the dye molecule significantly impacts the overall measured kinetics when using this common methodology. The conditions of the solution also influenced the dye-lanthanide-DTPA interactions, which reconciled previously disparate data in the literature.

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Research Organization:: California State Univ. (CalState), Long Beach, CA (United States); Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5); USDOE Office of Nuclear Energy (NE), Nuclear Reactor Technologies (NE-7). Nuclear Energy Universities Program (NEUP)

Grant/Contract Number:: AC07-05ID14517; NE0008410

OSTI ID:: 1376481

Journal Information:: RSC Advances, Vol. 7, Issue 42; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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Spectrophotometric determination of ligand–protein ratio in B2M3–DTPA monoclonal conjugates based on yttrium–methylthymol blue complex Nesměrák, Karel; Třmínková-Němcová, Pavlína; Drož, Ladislav Monatshefte für Chemie - Chemical Monthly, Vol. 149, Issue 9 https://doi.org/10.1007/s00706-018-2248-1	journal	August 2018
Dissociation rate kinetics of europium-DTPA complexes Larsson, Kristian; Mezyk, Stephen P. Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1 https://doi.org/10.1007/s10967-018-6103-y	journal	August 2018
Employing Luminescence to Determine Eu-DTPA Complex Formation Rate Constants in Lactate and Citrate Media: Experiment and Aggregate-Species Kinetic Modelling Larsson, Kristian; Mezyk, Stephen P. Solvent Extraction and Ion Exchange, Vol. 37, Issue 1 https://doi.org/10.1080/07366299.2019.1578476	journal	December 2018
Employing Luminescence to Determine Eu-DTPA Complex Formation Rate Constants in Lactate and Citrate Media: Experiment and Aggregate-Species Kinetic Modelling Larsson, Kristian; Mezyk, Stephen P. Taylor & Francis https://doi.org/10.6084/m9.figshare.8004629.v1	text	January 2019

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