Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al 2 O 3 catalyst pellets during lignin-first fractionation

Van den Bosch, S.; Renders, T.; Kennis, S.; Koelewijn, S. -F.; Van den Bossche, G.; Vangeel, T.; Deneyer, A.; Depuydt, D.; Courtin, C. M.; Thevelein, J. M.; Schutyser, W.; Sels, B. F.

doi:10.1039/C7GC01324H

Title: Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al ₂ O ₃ catalyst pellets during lignin-first fractionation

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Green Chemistry

DOI:https://doi.org/10.1039/C7GC01324H· OSTI ID:1375115

Van den Bosch, S. ^[1]; Renders, T. ^[1]; Kennis, S. ^[1]; Koelewijn, S. -F. ^[1]; Van den Bossche, G. ^[1]; Vangeel, T. ^[1]; Deneyer, A. ^[1]; Depuydt, D. ^[2]; Courtin, C. M. ^[3];

^[4]; Schutyser, W. ^[5];

^[1]

Center for Surface Chemistry and Catalysis; KU Leuven; 3001 Heverlee; Belgium
Bio Base Europe Pilot Plant; 9042 Ghent; Belgium
Center for Food and Microbial Technology; KU Leuven; 3001 Heverlee; Belgium
Lab of Molecular Cell Biology; KU Leuven and Center for Microbiology; VIB; 3001 Heverlee; Belgium
Center for Surface Chemistry and Catalysis; KU Leuven; 3001 Heverlee; Belgium; National Renewable Energy Laboratory

Elucidation of the catalyst role during reductive catalytic fractionation, enabling the integration of lignin valorization and bio-ethanol production.

Cite

Export

Save

Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1375115

Report Number(s):: NREL/JA-5100-69048; GRCHFJ

Journal Information:: Green Chemistry, Vol. 19, Issue 14; ISSN 1463-9262

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (78)

Nonenzymatic Sugar Production from Biomass Using Biomass-Derived -Valerolactone Luterbacher, J. S.; Rand, J. M.; Alonso, D. M. Science, Vol. 343, Issue 6168 https://doi.org/10.1126/science.1246748	journal	January 2014
Effective Release of Lignin Fragments from Lignocellulose by Lewis Acid Metal Triflates in the Lignin-First Approach Huang, Xiaoming; Zhu, Jiadong; Korányi, Tamás I. ChemSusChem, Vol. 9, Issue 23 https://doi.org/10.1002/cssc.201601252	journal	October 2016
Bioconversion of lignocellulose: inhibitors and detoxification Jönsson, Leif J.; Alriksson, Björn; Nilvebrant, Nils-Olof Biotechnology for Biofuels, Vol. 6, Issue 1 https://doi.org/10.1186/1754-6834-6-16	journal	January 2013
Characterization of Lignin Structures and Lignin–Carbohydrate Complex (LCC) Linkages by Quantitative ¹³ C and 2D HSQC NMR Spectroscopy Yuan, Tong-Qi; Sun, Shao-Ni; Xu, Feng Journal of Agricultural and Food Chemistry, Vol. 59, Issue 19 https://doi.org/10.1021/jf2031549	journal	October 2011
Depolymerization of lignin by microwave-assisted methylation of benzylic alcohols Zhu, Guodian; Qiu, Xueqing; Zhao, Ying Bioresource Technology, Vol. 218 https://doi.org/10.1016/j.biortech.2016.07.021	journal	October 2016
Selective Degradation of Wood Lignin over Noble‐Metal Catalysts in a Two‐Step Process Yan, Ning; Zhao, Chen; Dyson, Paul J. ChemSusChem, Vol. 1, Issue 7 https://doi.org/10.1002/cssc.200800080	journal	July 2008
Potential and challenges of zeolite chemistry in the catalytic conversion of biomass Ennaert, Thijs; Van Aelst, Joost; Dijkmans, Jan Chemical Society Reviews, Vol. 45, Issue 3 https://doi.org/10.1039/C5CS00859J	journal	January 2016
Mild and Robust Redox-Neutral Pd/C-Catalyzed Lignol β-O-4′ Bond Cleavage Through a Low-Energy-Barrier Pathway Galkin, Maxim V.; Dahlstrand, Christian; Samec, Joseph S. M. ChemSusChem, Vol. 8, Issue 13 https://doi.org/10.1002/cssc.201500117	journal	April 2015
Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited Bozell, Joseph J.; Petersen, Gene R. Green Chemistry, Vol. 12, Issue 4, p. 539-554 https://doi.org/10.1039/b922014c	journal	January 2010
Alkane production from biomass: chemo-, bio- and integrated catalytic approaches Deneyer, Aron; Renders, Tom; Van Aelst, Joost Current Opinion in Chemical Biology, Vol. 29 https://doi.org/10.1016/j.cbpa.2015.08.010	journal	December 2015
Hydrogen-free catalytic fractionation of woody biomass Galkin, Maxim V.; Smit, Arjan T.; Subbotina, Elena ChemSusChem, Vol. 9, Issue 23 https://doi.org/10.1002/cssc.201600648	journal	November 2016
Reductive lignocellulose fractionation into soluble lignin-derived phenolic monomers and dimers and processable carbohydrate pulps Van den Bosch, S.; Schutyser, W.; Vanholme, R. Energy & Environmental Science, Vol. 8, Issue 6 https://doi.org/10.1039/C5EE00204D	journal	January 2015
Synergetic Effects of Alcohol/Water Mixing on the Catalytic Reductive Fractionation of Poplar Wood Renders, Tom; Van den Bosch, Sander; Vangeel, Thijs ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 12 https://doi.org/10.1021/acssuschemeng.6b01844	journal	October 2016
Redefining biorefinery: the search for unconventional building blocks for materials Esposito, Davide; Antonietti, Markus Chemical Society Reviews, Vol. 44, Issue 16 https://doi.org/10.1039/C4CS00368C	journal	January 2015
Selective Route to 2-Propenyl Aryls Directly from Wood by a Tandem Organosolv and Palladium-Catalysed Transfer Hydrogenolysis Galkin, Maxim V.; Samec, Joseph S. M. ChemSusChem, Vol. 7, Issue 8 https://doi.org/10.1002/cssc.201402017	journal	June 2014
Quantification of lignin–carbohydrate linkages with high-resolution NMR spectroscopy Balakshin, Mikhail; Capanema, Ewellyn; Gracz, Hanna Planta, Vol. 233, Issue 6 https://doi.org/10.1007/s00425-011-1359-2	journal	February 2011
Lignin monomer production integrated into the γ-valerolactone sugar platform Luterbacher, Jeremy S.; Azarpira, Ali; Motagamwala, Ali H. Energy & Environmental Science, Vol. 8, Issue 9 https://doi.org/10.1039/C5EE01322D	journal	January 2015
A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass Parsell, Trenton; Yohe, Sara; Degenstein, John Green Chemistry, Vol. 17, Issue 3 https://doi.org/10.1039/C4GC01911C	journal	January 2015
Tandem Catalytic Depolymerization of Lignin by Water-Tolerant Lewis Acids and Rhodium Complexes Jastrzebski, Robin; Constant, Sandra; Lancefield, Christopher S. ChemSusChem, Vol. 9, Issue 16 https://doi.org/10.1002/cssc.201600683	journal	July 2016
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels Li, Changzhi; Zhao, Xiaochen; Wang, Aiqin Chemical Reviews, Vol. 115, Issue 21, p. 11559-11624 https://doi.org/10.1021/acs.chemrev.5b00155	journal	October 2015
Ammonia Pretreatment of Corn Stover Enables Facile Lignin Extraction Mittal, Ashutosh; Katahira, Rui; Donohoe, Bryon S. ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 3 https://doi.org/10.1021/acssuschemeng.6b02892	journal	February 2017
Towards industrial pentose-fermenting yeast strains Hahn-Hägerdal, Bärbel; Karhumaa, Kaisa; Fonseca, César Applied Microbiology and Biotechnology, Vol. 74, Issue 5 https://doi.org/10.1007/s00253-006-0827-2	journal	February 2007
Renewable Feedstocks: The Problem of Catalyst Deactivation and its Mitigation Lange, Jean-Paul Angewandte Chemie International Edition, Vol. 54, Issue 45 https://doi.org/10.1002/anie.201503595	journal	October 2015
Characterization of Miscanthus giganteus Lignin Isolated by Ethanol Organosolv Process under Reflux Condition Bauer, Stefan; Sorek, Hagit; Mitchell, Valerie D. Journal of Agricultural and Food Chemistry, Vol. 60, Issue 33 https://doi.org/10.1021/jf302409d	journal	August 2012
Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers Sergeev, A. G.; Hartwig, J. F. Science, Vol. 332, Issue 6028, p. 439-443 https://doi.org/10.1126/science.1200437	journal	April 2011
Heterogeneous Catalyst Deactivation and Regeneration: A Review Argyle, Morris; Bartholomew, Calvin Catalysts, Vol. 5, Issue 1 https://doi.org/10.3390/catal5010145	journal	February 2015
Conversion of biomass to selected chemical products Gallezot, Pierre Chem. Soc. Rev., Vol. 41, Issue 4 https://doi.org/10.1039/C1CS15147A	journal	January 2012
Mild hydrogenolysis of in-situ and isolated Pinus radiata lignins Torr, Kirk M.; van de Pas, Daniel J.; Cazeils, Emmanuel Bioresource Technology, Vol. 102, Issue 16 https://doi.org/10.1016/j.biortech.2011.05.040	journal	August 2011
Sustainable bisphenols from renewable softwood lignin feedstock for polycarbonates and cyanate ester resins Koelewijn, S. -F.; Van den Bosch, S.; Renders, T. Green Chemistry, Vol. 19, Issue 11 https://doi.org/10.1039/C7GC00776K	journal	January 2017
Distribution of lignin interunit bonds in the differentiating xylem of compression and normal woods of Pinus thunbergii Saito, Kaori; Fukushima, Kazuhiko Journal of Wood Science, Vol. 51, Issue 3 https://doi.org/10.1007/s10086-004-0644-0	journal	June 2005
Robust Heterogeneous Nickel Catalysts with Tailored Porosity for the Selective Hydrogenolysis of Aryl Ethers Zaheer, Muhammad; Hermannsdörfer, Justus; Kretschmer, Winfried P. ChemCatChem, Vol. 6, Issue 1, p. 91-95 https://doi.org/10.1002/cctc.201300763	journal	October 2013
Catalytic Biorefining of Plant Biomass to Non-Pyrolytic Lignin Bio-Oil and Carbohydrates through Hydrogen Transfer Reactions Ferrini, Paola; Rinaldi, Roberto Angewandte Chemie International Edition, Vol. 53, Issue 33 https://doi.org/10.1002/anie.201403747	journal	June 2014
Lignin valorization through integrated biological funneling and chemical catalysis Linger, J. G.; Vardon, D. R.; Guarnieri, M. T. Proceedings of the National Academy of Sciences, Vol. 111, Issue 33, p. 12013-12018 https://doi.org/10.1073/pnas.1410657111	journal	August 2014
Review of current and future softwood kraft lignin process chemistry Chakar, Fadi S.; Ragauskas, Arthur J. Industrial Crops and Products, Vol. 20, Issue 2 https://doi.org/10.1016/j.indcrop.2004.04.016	journal	September 2004
Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation–hydrogenolysis process Song, Qi; Wang, Feng; Cai, Jiaying Energy & Environmental Science, Vol. 6, Issue 3, p. 994-1007 https://doi.org/10.1039/c2ee23741e	journal	January 2013
Catalytic Upstream Biorefining through Hydrogen Transfer Reactions: Understanding the Process from the Pulp Perspective Ferrini, Paola; Rezende, Camila A.; Rinaldi, Roberto ChemSusChem, Vol. 9, Issue 22 https://doi.org/10.1002/cssc.201601121	journal	October 2016
Lignin Composition and Structure in Young versus Adult Eucalyptus globulus Plants Rencoret, Jorge; Gutiérrez, Ana; Nieto, Lidia Plant Physiology, Vol. 155, Issue 2 https://doi.org/10.1104/pp.110.167254	journal	November 2010
Lignin Valorization through Catalytic Lignocellulose Fractionation: A Fundamental Platform for the Future Biorefinery Galkin, Maxim V.; Samec, Joseph S. M. ChemSusChem, Vol. 9, Issue 13 https://doi.org/10.1002/cssc.201600237	journal	June 2016
Lignin Valorization: Improving Lignin Processing in the Biorefinery Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J. Science, Vol. 344, Issue 6185, p. 1246843-1246843 https://doi.org/10.1126/science.1246843	journal	May 2014
Catalytic transfer hydrogenolysis of ionic liquid processed biorefinery lignin to phenolic compounds Kim, Kwang Ho; Simmons, Blake A.; Singh, Seema Green Chemistry, Vol. 19, Issue 1 https://doi.org/10.1039/C6GC02473D	journal	January 2017
Reductive fractionation of woody biomass into lignin monomers and cellulose by tandem metal triflate and Pd/C catalysis Huang, Xiaoming; Morales Gonzalez, Olivia M.; Zhu, Jiadong Green Chemistry, Vol. 19, Issue 1 https://doi.org/10.1039/C6GC02962K	journal	January 2017
A Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization in Acidic Environments Sturgeon, Matthew R.; Kim, Seonah; Lawrence, Kelsey ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 3, p. 472-485 https://doi.org/10.1021/sc400384w	journal	November 2013
Green chemistry and the biorefinery: a partnership for a sustainable future Clark, James H.; Budarin, Vitaly; Deswarte, Fabien E. I. Green Chemistry, Vol. 8, Issue 10 https://doi.org/10.1039/b604483m	journal	January 2006
Combining inhibitor tolerance and D-xylose fermentation in industrial Saccharomyces cerevisiae for efficient lignocellulose-based bioethanol production Demeke, Mekonnen M.; Dumortier, Françoise; Li, Yingying Biotechnology for Biofuels, Vol. 6, Issue 1 https://doi.org/10.1186/1754-6834-6-120	journal	January 2013
Lignin fate and characterization during ionic liquid biomass pretreatment for renewable chemicals and fuels production Sathitsuksanoh, Noppadon; Holtman, Kevin M.; Yelle, Daniel J. Green Chem., Vol. 16, Issue 3 https://doi.org/10.1039/C3GC42295J	journal	January 2014
Isolation and characterization of new lignin streams derived from extractive-ammonia (EA) pretreatment da Costa Sousa, Leonardo; Foston, Marcus; Bokade, Vijay Green Chemistry, Vol. 18, Issue 15 https://doi.org/10.1039/C6GC00298F	journal	January 2016
High Yield Production of Natural Phenolic Alcohols from Woody Biomass Using a Nickel-Based Catalyst Chen, Jiazhi; Lu, Fang; Si, Xiaoqin ChemSusChem, Vol. 9, Issue 23 https://doi.org/10.1002/cssc.201601273	journal	November 2016
New insights into the structure and composition of technical lignins: a comparative characterisation study Constant, Sandra; Wienk, Hans L. J.; Frissen, Augustinus E. Green Chemistry, Vol. 18, Issue 9 https://doi.org/10.1039/C5GC03043A	journal	January 2016
Reductive Catalytic Fractionation of Corn Stover Lignin Anderson, Eric M.; Katahira, Rui; Reed, Michelle ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 12 https://doi.org/10.1021/acssuschemeng.6b01858	journal	October 2016
Decomposition behavior of woody biomass in water-added supercritical methanol Minami, Eiji; Saka, Shiro Journal of Wood Science, Vol. 51, Issue 4 https://doi.org/10.1007/s10086-004-0670-y	journal	August 2005
Lignin and related compounds. I. A comparative study of catalysts for lignin hydrogenolysis Pepper, J. M.; Lee, Y. W. Canadian Journal of Chemistry, Vol. 47, Issue 5 https://doi.org/10.1139/v69-118	journal	March 1969
The Influence of Hemicellulose Sugars on Product Distribution of Early-Stage Conversion of Lignin Oligomers Catalysed by Raney Nickel Chesi, Claudio; de Castro, Ilton B. D.; Clough, Matthew T. ChemCatChem, Vol. 8, Issue 12 https://doi.org/10.1002/cctc.201600235	journal	May 2016
Hydrogenolysis Goes Bio: From Carbohydrates and Sugar Alcohols to Platform Chemicals Ruppert, Agnieszka M.; Weinberg, Kamil; Palkovits, Regina Angewandte Chemie International Edition, Vol. 51, Issue 11, p. 2564-2601 https://doi.org/10.1002/anie.201105125	journal	February 2012
Influence of bio-based solvents on the catalytic reductive fractionation of birch wood Schutyser, W.; Van den Bosch, S.; Renders, T. Green Chemistry, Vol. 17, Issue 11 https://doi.org/10.1039/C5GC01442E	journal	January 2015
Structural Characterization of Guaiacyl-rich Lignins in Flax (Linum usitatissimum) Fibers and Shives del Río, José C.; Rencoret, Jorge; Gutiérrez, Ana Journal of Agricultural and Food Chemistry, Vol. 59, Issue 20 https://doi.org/10.1021/jf201222r	journal	October 2011
Lignin depolymerisation by nickel supported layered-double hydroxide catalysts Sturgeon, Matthew R.; O'Brien, Marykate H.; Ciesielski, Peter N. Green Chem., Vol. 16, Issue 2 https://doi.org/10.1039/C3GC42138D	journal	January 2014
Biorefining of wheat straw using an acetic and formic acid based organosolv fractionation process Snelders, Jeroen; Dornez, Emmie; Benjelloun-Mlayah, Bouchra Bioresource Technology, Vol. 156 https://doi.org/10.1016/j.biortech.2014.01.069	journal	March 2014
Cellulose and hemicellulose valorisation: an integrated challenge of catalysis and reaction engineering Delidovich, I.; Leonhard, K.; Palkovits, R. Energy & Environmental Science, Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01067A	journal	January 2014
Ni-Catalyzed Cleavage of Aryl Ethers in the Aqueous Phase He, Jiayue; Zhao, Chen; Lercher, Johannes A. Journal of the American Chemical Society, Vol. 134, Issue 51, p. 20768-20775 https://doi.org/10.1021/ja309915e	journal	December 2012
Comparison of the decomposition behaviors of hardwood and softwood in supercritical methanol Minami, E.; Saka, S. Journal of Wood Science, Vol. 49, Issue 1 https://doi.org/10.1007/s100860300012	journal	February 2003
Mechanistic investigation of the Zn/Pd/C catalyzed cleavage and hydrodeoxygenation of lignin Klein, Ian; Marcum, Christopher; Kenttämaa, Hilkka Green Chemistry, Vol. 18, Issue 8 https://doi.org/10.1039/C5GC01325A	journal	January 2016
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals Zakzeski, Joseph; Bruijnincx, Pieter C. A.; Jongerius, Anna L. Chemical Reviews, Vol. 110, Issue 6, p. 3552-3599 https://doi.org/10.1021/cr900354u	journal	June 2010
The occurrence and reactivity of phenoxyl linkages in lignin and low rank coal Dorrestijn, Edwin; Laarhoven, Lucas J. J.; Arends, Isabel W. C. E. Journal of Analytical and Applied Pyrolysis, Vol. 54, Issue 1-2, p. 153-192 https://doi.org/10.1016/S0165-2370(99)00082-0	journal	March 2000
Lignol Cleavage by Pd/C Under Mild Conditions and Without Hydrogen: A Role for Benzylic CH Activation? Zhou, Xiaoyuan; Mitra, Joyee; Rauchfuss, Thomas B. ChemSusChem, Vol. 7, Issue 6 https://doi.org/10.1002/cssc.201301253	journal	April 2014
Total Utilization of Miscanthus Biomass, Lignin and Carbohydrates, Using Earth Abundant Nickel Catalyst Luo, Hao; Klein, Ian M.; Jiang, Yuan ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 4 https://doi.org/10.1021/acssuschemeng.5b01776	journal	February 2016
Influence of Acidic (H ₃ PO ₄ ) and Alkaline (NaOH) Additives on the Catalytic Reductive Fractionation of Lignocellulose Renders, Tom; Schutyser, Wouter; Van den Bosch, Sander ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.5b02906	journal	February 2016
Aromatic Monomers by in Situ Conversion of Reactive Intermediates in the Acid-Catalyzed Depolymerization of Lignin Deuss, Peter J.; Scott, Martin; Tran, Fanny Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03693	journal	June 2015
Characteristics of wheat straw lignins from ethanol-based organosolv treatment Huijgen, W. J. J.; Telysheva, G.; Arshanitsa, A. Industrial Crops and Products, Vol. 59 https://doi.org/10.1016/j.indcrop.2014.05.003	journal	August 2014
Paving the Way for Lignin Valorisation: Recent Advances in Bioengineering, Biorefining and Catalysis Rinaldi, Roberto; Jastrzebski, Robin; Clough, Matthew T. Angewandte Chemie International Edition, Vol. 55, Issue 29 https://doi.org/10.1002/anie.201510351	journal	June 2016
Lignin depolymerisation strategies: towards valuable chemicals and fuels Xu, Chunping; Arancon, Rick Arneil D.; Labidi, Jalel Chemical Society Reviews, Vol. 43, Issue 22, p. 7485-7500 https://doi.org/10.1039/C4CS00235K	journal	January 2014
Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization Shuai, Li; Amiri, Masoud Talebi; Questell-Santiago, Ydna M. Science, Vol. 354, Issue 6310 https://doi.org/10.1126/science.aaf7810	journal	October 2016
Fragmentation of Lignin Samples with Commercial Pd/C under Ambient Pressure of Hydrogen Gao, Fang; Webb, Jonathan D.; Sorek, Hagit ACS Catalysis, Vol. 6, Issue 11 https://doi.org/10.1021/acscatal.6b02028	journal	October 2016
Polygenic analysis and targeted improvement of the complex trait of high acetic acid tolerance in the yeast Saccharomyces cerevisiae Meijnen, Jean-Paul; Randazzo, Paola; Foulquié-Moreno, María R. Biotechnology for Biofuels, Vol. 9, Issue 1 https://doi.org/10.1186/s13068-015-0421-x	journal	January 2016
Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood Van den Bosch, S.; Schutyser, W.; Koelewijn, S. -F. Chemical Communications, Vol. 51, Issue 67 https://doi.org/10.1039/C5CC04025F	journal	January 2015
Pretreatment: the key to unlocking low-cost cellulosic ethanol Yang, Bin; Wyman, Charles E. Biofuels, Bioproducts and Biorefining, Vol. 2, Issue 1 https://doi.org/10.1002/bbb.49	journal	January 2008
Recent trends in global production and utilization of bio-ethanol fuel Balat, Mustafa; Balat, Havva Applied Energy, Vol. 86, Issue 11 https://doi.org/10.1016/j.apenergy.2009.03.015	journal	November 2009
Studies on Lignin and Related Compounds. LXX. Hydrogenolysis and Hydrogenation of Maple Wood Bower, John R.; Cooke, Lloyd M.; Hibbert, Harold Journal of the American Chemical Society, Vol. 65, Issue 6 https://doi.org/10.1021/ja01246a049	journal	June 1943
Development of a D-xylose fermenting and inhibitor tolerant industrial Saccharomyces cerevisiae strain with high performance in lignocellulose hydrolysates using metabolic and evolutionary engineering Demeke, Mekonnen M.; Dietz, Heiko; Li, Yingying Biotechnology for Biofuels, Vol. 6, Issue 1 https://doi.org/10.1186/1754-6834-6-89	journal	January 2013

Similar Records

Controlling Bacterial Contamination During Fuel Ethanol Fermentation Using Thermochemically Depolymerized Lignin Bio-Oils

Journal Article · Mon Aug 02 00:00:00 EDT 2021 · Green Chemistry · OSTI ID:1375115

Kalinoski, Ryan M.; Li, Wengi; Mobley, Justin K.; +4 more

Antimicrobial Properties of Corn Stover Lignin Fractions Derived from Catalytic Transfer Hydrogenolysis in Supercritical Ethanol with a Ru/C Catalyst

Journal Article · Fri Dec 04 00:00:00 EST 2020 · ACS Sustainable Chemistry & Engineering · OSTI ID:1375115

Kalinoski, Ryan M.; Li, Wenqi; Mobley, Justin K.; +5 more

Techno‐economic and greenhouse gas analyses of lignin valorization to eugenol and phenolic products in integrated ethanol biorefineries

Journal Article · Thu Mar 28 00:00:00 EDT 2019 · Biofuels, Bioproducts & Biorefining · OSTI ID:1375115

Martinez‐Hernandez, Elias; Cui, Xinguang; Scown, Corinne D.; +3 more

Related Subjects

09 BIOMASS FUELS
reductive catalytic fractionation
lignocellulosic biomass
biorefineries

Title: Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al 2 O 3 catalyst pellets during lignin-first fractionation

Citation Formats

References (78)

Similar Records

Related Subjects

Title: Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al ₂ O ₃ catalyst pellets during lignin-first fractionation