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Title: Magnetic phase transitions and magnetoelastic coupling in S = 1 2 Heisenberg antiferromagnets

Abstract

We combined magneto-infrared spectroscopy and first-principles calculations to unravel the role of spin-phonon coupling in the vicinity of the magnetic field-driven phase transitions in two chemically similar S = 1/2 Heisenberg antiferromagnets, CuF2(H2O)(2)(3-Clpy) and [Cu(pyz)(2)(HF2)]PF6. This comparison resolves questions about the conditions under which the lattice participates in magnetic-field-driven transitions and, at the same time, provides a way to predict how the lattice is likely to support microscopic spin rearrangements.

Authors:
; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science - Office of Basic Energy Sciences - Materials Sciences and Engineering Division; National Science Foundation (NSF)
OSTI Identifier:
1374881
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 95; Journal Issue: 10; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

al-Wahish, Amal, O'Neal, K. R., Lee, C., Fan, S., Hughey, K., Yokosuk, M. O., Clune, A. J., Li, Z., Schlueter, J. A., Manson, J. L., Whangbo, M. -H., and Musfeldt, J. L. Magnetic phase transitions and magnetoelastic coupling in S=12 Heisenberg antiferromagnets. United States: N. p., 2017. Web. doi:10.1103/PhysRevB.95.104437.
al-Wahish, Amal, O'Neal, K. R., Lee, C., Fan, S., Hughey, K., Yokosuk, M. O., Clune, A. J., Li, Z., Schlueter, J. A., Manson, J. L., Whangbo, M. -H., & Musfeldt, J. L. Magnetic phase transitions and magnetoelastic coupling in S=12 Heisenberg antiferromagnets. United States. doi:10.1103/PhysRevB.95.104437.
al-Wahish, Amal, O'Neal, K. R., Lee, C., Fan, S., Hughey, K., Yokosuk, M. O., Clune, A. J., Li, Z., Schlueter, J. A., Manson, J. L., Whangbo, M. -H., and Musfeldt, J. L. Wed . "Magnetic phase transitions and magnetoelastic coupling in S=12 Heisenberg antiferromagnets". United States. doi:10.1103/PhysRevB.95.104437.
@article{osti_1374881,
title = {Magnetic phase transitions and magnetoelastic coupling in S=12 Heisenberg antiferromagnets},
author = {al-Wahish, Amal and O'Neal, K. R. and Lee, C. and Fan, S. and Hughey, K. and Yokosuk, M. O. and Clune, A. J. and Li, Z. and Schlueter, J. A. and Manson, J. L. and Whangbo, M. -H. and Musfeldt, J. L.},
abstractNote = {We combined magneto-infrared spectroscopy and first-principles calculations to unravel the role of spin-phonon coupling in the vicinity of the magnetic field-driven phase transitions in two chemically similar S = 1/2 Heisenberg antiferromagnets, CuF2(H2O)(2)(3-Clpy) and [Cu(pyz)(2)(HF2)]PF6. This comparison resolves questions about the conditions under which the lattice participates in magnetic-field-driven transitions and, at the same time, provides a way to predict how the lattice is likely to support microscopic spin rearrangements.},
doi = {10.1103/PhysRevB.95.104437},
journal = {Physical Review B},
issn = {2469-9950},
number = 10,
volume = 95,
place = {United States},
year = {2017},
month = {3}
}

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