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Title: Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires

Abstract

Metal-organic frameworks (MOFs), with their well-ordered pore networks and tunable surface chemistries, offer a versatile platform for preparing well-defined nanostructures wherein functionality such as catalysis can be incorporated. We resolved the atomic structure of Ni-oxo species deposited in the MOF NU-1000 through atomic layer deposition using local and long-range structure probes, including X-ray absorption spectroscopy, pair distribution function analysis and difference envelope density analysis, with electron microscopy imaging and computational modeling.

Authors:
ORCiD logo [1];  [2];  [2];  [2]; ORCiD logo [1]; ; ; ORCiD logo; ORCiD logo; ; ; ;  [1]; ORCiD logo [3]; ORCiD logo;  [4]; ; ; ORCiD logo [5]; ORCiD logo [2] more »; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1] « less
  1. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States
  2. Department of Chemistry, Minnesota Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota 55455, United States
  3. Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
  4. Materials Science and Engineering, University of Washington, Seattle, Washington 98195, United States
  5. Department of Chemistry and Catalysis Research Institute, Technische Universität München, 85748 Garching, Germany
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1374646
Report Number(s):
PNNL-SA-127715
Journal ID: ISSN 0002-7863; 48810; KC0307010
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 139; Journal Issue: 30; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
Environmental Molecular Sciences Laboratory

Citation Formats

Platero-Prats, Ana E., League, Aaron B., Bernales, Varinia, Ye, Jingyun, Gallington, Leighanne C., Vjunov, Aleksei, Schweitzer, Neil M., Li, Zhanyong, Zheng, Jian, Mehdi, B. Layla, Stevens, Andrew J., Dohnalkova, Alice, Balasubramanian, Mahalingam, Farha, Omar K., Hupp, Joseph T., Browning, Nigel D., Fulton, John L., Camaioni, Donald M., Lercher, Johannes A., Truhlar, Donald G., Gagliardi, Laura, Cramer, Christopher J., and Chapman, Karena W. Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires. United States: N. p., 2017. Web. doi:10.1021/jacs.7b04997.
Platero-Prats, Ana E., League, Aaron B., Bernales, Varinia, Ye, Jingyun, Gallington, Leighanne C., Vjunov, Aleksei, Schweitzer, Neil M., Li, Zhanyong, Zheng, Jian, Mehdi, B. Layla, Stevens, Andrew J., Dohnalkova, Alice, Balasubramanian, Mahalingam, Farha, Omar K., Hupp, Joseph T., Browning, Nigel D., Fulton, John L., Camaioni, Donald M., Lercher, Johannes A., Truhlar, Donald G., Gagliardi, Laura, Cramer, Christopher J., & Chapman, Karena W. Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires. United States. doi:10.1021/jacs.7b04997.
Platero-Prats, Ana E., League, Aaron B., Bernales, Varinia, Ye, Jingyun, Gallington, Leighanne C., Vjunov, Aleksei, Schweitzer, Neil M., Li, Zhanyong, Zheng, Jian, Mehdi, B. Layla, Stevens, Andrew J., Dohnalkova, Alice, Balasubramanian, Mahalingam, Farha, Omar K., Hupp, Joseph T., Browning, Nigel D., Fulton, John L., Camaioni, Donald M., Lercher, Johannes A., Truhlar, Donald G., Gagliardi, Laura, Cramer, Christopher J., and Chapman, Karena W. Mon . "Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires". United States. doi:10.1021/jacs.7b04997.
@article{osti_1374646,
title = {Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires},
author = {Platero-Prats, Ana E. and League, Aaron B. and Bernales, Varinia and Ye, Jingyun and Gallington, Leighanne C. and Vjunov, Aleksei and Schweitzer, Neil M. and Li, Zhanyong and Zheng, Jian and Mehdi, B. Layla and Stevens, Andrew J. and Dohnalkova, Alice and Balasubramanian, Mahalingam and Farha, Omar K. and Hupp, Joseph T. and Browning, Nigel D. and Fulton, John L. and Camaioni, Donald M. and Lercher, Johannes A. and Truhlar, Donald G. and Gagliardi, Laura and Cramer, Christopher J. and Chapman, Karena W.},
abstractNote = {Metal-organic frameworks (MOFs), with their well-ordered pore networks and tunable surface chemistries, offer a versatile platform for preparing well-defined nanostructures wherein functionality such as catalysis can be incorporated. We resolved the atomic structure of Ni-oxo species deposited in the MOF NU-1000 through atomic layer deposition using local and long-range structure probes, including X-ray absorption spectroscopy, pair distribution function analysis and difference envelope density analysis, with electron microscopy imaging and computational modeling.},
doi = {10.1021/jacs.7b04997},
journal = {Journal of the American Chemical Society},
issn = {0002-7863},
number = 30,
volume = 139,
place = {United States},
year = {2017},
month = {7}
}