Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires

Platero-Prats, Ana E.; League, Aaron B.; Bernales, Varinia; Ye, Jingyun; Gallington, Leighanne C.; Vjunov, Aleksei; Schweitzer, Neil M.; Li, Zhanyong; Zheng, Jian; Mehdi, B. Layla; Stevens, Andrew J.; Dohnalkova, Alice; Balasubramanian, Mahalingam; Farha, Omar K.; Hupp, Joseph T.; Browning, Nigel D.; Fulton, John L.; Camaioni, Donald M.; Lercher, Johannes A.; Truhlar, Donald G.; Gagliardi, Laura; Cramer, Christopher J.; Chapman, Karena W.

doi:10.1021/jacs.7b04997

Title: Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires

Journal Article · Mon Jul 24 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b04997· OSTI ID:1374646

^[1]; League, Aaron B. ^[2]; Bernales, Varinia ^[2]; Ye, Jingyun ^[2];

^[1]; Vjunov, Aleksei; Schweitzer, Neil M.;

;

; Mehdi, B. Layla; Stevens, Andrew J.; Dohnalkova, Alice; Balasubramanian, Mahalingam ^[1];

^[3];

; Browning, Nigel D. ^[4]; Fulton, John L.; Camaioni, Donald M.;

^[5];

^[2] more »

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States
Department of Chemistry, Minnesota Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota 55455, United States
Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
Materials Science and Engineering, University of Washington, Seattle, Washington 98195, United States
Department of Chemistry and Catalysis Research Institute, Technische Universität München, 85748 Garching, Germany

Metal-organic frameworks (MOFs), with their well-ordered pore networks and tunable surface chemistries, offer a versatile platform for preparing well-defined nanostructures wherein functionality such as catalysis can be incorporated. We resolved the atomic structure of Ni-oxo species deposited in the MOF NU-1000 through atomic layer deposition using local and long-range structure probes, including X-ray absorption spectroscopy, pair distribution function analysis and difference envelope density analysis, with electron microscopy imaging and computational modeling.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1374646

Report Number(s):: PNNL-SA-127715; 48810; KC0307010

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 30; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

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NanoMOFs: little crystallites for substantial applications Majewski, M. B.; Noh, H.; Islamoglu, T. Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/c8ta02132e	journal	January 2018
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