Superconducting Phases of Phosphorus Hydride Under Pressure: Stabilization by Mobile Molecular Hydrogen

Bi, Tiange; Miller, Daniel P.; Shamp, Andrew; Zurek, Eva

doi:10.1002/ange.201701660

Title: Superconducting Phases of Phosphorus Hydride Under Pressure: Stabilization by Mobile Molecular Hydrogen

Journal Article · Fri May 05 00:00:00 EDT 2017 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201701660· OSTI ID:1374464

^[1];

^[1]; Shamp, Andrew ^[1];

^[1]

Department of Chemistry, State University of New York at Buffalo, Buffalo NY 14260-3000 USA

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Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0002006

OSTI ID:: 1374464

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 129 Journal Issue: 34; ISSN 0044-8249

Publisher:: German Chemical SocietyCopyright Statement

Country of Publication:: Germany

Language:: English

References (23)

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Superconductivity in metastable phases of phosphorus-hydride compounds under high pressure Flores-Livas, José A.; Amsler, Maximilian; Heil, Christoph Physical Review B, Vol. 93, Issue 2 https://doi.org/10.1103/PhysRevB.93.020508	journal	January 2016
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The Chemical Imagination at Work inVery Tight Places Grochala, Wojciech; Hoffmann, Roald; Feng, Ji Angewandte Chemie International Edition, Vol. 46, Issue 20 https://doi.org/10.1002/anie.200602485	journal	May 2007
Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system Drozdov, A. P.; Eremets, M. I.; Troyan, I. A. Nature, Vol. 525, Issue 7567 https://doi.org/10.1038/nature14964	journal	August 2015
Pressure-induced metallization of dense (H2S)2H2 with high-Tc superconductivity Duan, Defang; Liu, Yunxian; Tian, Fubo Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06968	journal	November 2014
Predicting crystal structures and properties of matter under extreme conditions via quantum mechanics: the pressure is on Zurek, Eva; Grochala, Wojciech Physical Chemistry Chemical Physics, Vol. 17, Issue 5 https://doi.org/10.1039/C4CP04445B	journal	January 2015
XtalOpt: An open-source evolutionary algorithm for crystal structure prediction Lonie, David C.; Zurek, Eva Computer Physics Communications, Vol. 182, Issue 2 https://doi.org/10.1016/j.cpc.2010.07.048	journal	February 2011
Proton or Deuteron Transfer in Phase IV of Solid Hydrogen and Deuterium Liu, Hanyu; Ma, Yanming Physical Review Letters, Vol. 110, Issue 2 https://doi.org/10.1103/PhysRevLett.110.025903	journal	January 2013
X-ray diffraction and equation of state of hydrogen at megabar pressures Loubeyre, P.; LeToullec, R.; Hausermann, D. Nature, Vol. 383, Issue 6602 https://doi.org/10.1038/383702a0	journal	October 1996
Decomposition Products of Phosphine Under Pressure: PH ₂ Stable and Superconducting? Shamp, Andrew; Terpstra, Tyson; Bi, Tiange Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b10180	journal	February 2016
Chemie unter höchsten Drücken: eine Herausforderung für die chemische Intuition Grochala, Wojciech; Hoffmann, Roald; Feng, Ji Angewandte Chemie, Vol. 119, Issue 20 https://doi.org/10.1002/ange.200602485	journal	May 2007
Quasimolecules in Compressed Lithium Miao, Mao-sheng; Hoffmann, Roald; Botana, Jorge Angewandte Chemie International Edition, Vol. 56, Issue 4 https://doi.org/10.1002/anie.201608490	journal	December 2016
The metallization and superconductivity of dense hydrogen sulfide Li, Yinwei; Hao, Jian; Liu, Hanyu The Journal of Chemical Physics, Vol. 140, Issue 17 https://doi.org/10.1063/1.4874158	journal	May 2014
Quasimolecules in Compressed Lithium Miao, Mao-sheng; Hoffmann, Roald; Botana, Jorge Angewandte Chemie, Vol. 129, Issue 4 https://doi.org/10.1002/ange.201608490	journal	December 2016
Crystal Structure and Superconductivity of PH ₃ at High Pressures Liu, Hanyu; Li, Yinwei; Gao, Guoying The Journal of Physical Chemistry C, Vol. 120, Issue 6 https://doi.org/10.1021/acs.jpcc.5b12009	journal	February 2016
Simple-cubic–simple-hexagonal transition in phosphorus under pressure Akahama, Yuichi; Kobayashi, Mototada; Kawamura, Haruki Physical Review B, Vol. 59, Issue 13 https://doi.org/10.1103/PhysRevB.59.8520	journal	April 1999
Mercury under Pressure acts as a Transition Metal: Calculated from First Principles Botana, Jorge; Wang, Xiaoli; Hou, Chunju Angewandte Chemie, Vol. 127, Issue 32 https://doi.org/10.1002/ange.201503870	journal	July 2015
Supraleitung und Chemie Simon, Arndt Angewandte Chemie, Vol. 109, Issue 17 https://doi.org/10.1002/ange.19971091705	journal	September 1997
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Dissociation products and structures of solid $H_{2} S$ at strong compression Li, Yinwei; Wang, Lin; Liu, Hanyu Physical Review B, Vol. 93, Issue 2 https://doi.org/10.1103/PhysRevB.93.020103	journal	January 2016
High-Pressure Phase Stability and Superconductivity of Pnictogen Hydrides and Chemical Trends for Compressed Hydrides Fu, Yuhao; Du, Xiangpo; Zhang, Lijun Chemistry of Materials, Vol. 28, Issue 6 https://doi.org/10.1021/acs.chemmater.5b04638	journal	February 2016

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