Ionic Liquid as an Effective Additive for Rechargeable Magnesium Batteries

Pan, Baofei; Lau, Ka -Cheong; Vaughey, John T.; Zhang, Lu; Zhang, Zhengcheng; Liao, Chen

doi:10.1149/2.1551704jes

Title: Ionic Liquid as an Effective Additive for Rechargeable Magnesium Batteries

Journal Article · Thu Mar 02 00:00:00 EST 2017 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.1551704jes· OSTI ID:1373600

Pan, Baofei ^[1]; Lau, Ka -Cheong ^[1]; Vaughey, John T. ^[1]; Zhang, Lu ^[1]; Zhang, Zhengcheng ^[1]; Liao, Chen ^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)

Here, the effect of the addition of an ionic liquid DEME•TFSI to an electrolyte solution of Mg(HMDS)₂-MgCl₂ in THF was studied electrochemically and spectroscopically. Reversible magnesium deposition/dissolution was achieved with the DEME•TFSI-modified electrolyte. This electrolyte shows higher ionic conductivity, and a linear relationship was observed between the ionic conductivity and the concentration of DEME•TFSI in THF solution of Mg(HMDS)₂-MgCl₂. Mg-Mo₆S₈ coin cells have also been successfully cycled using Mg(HMDS)₂-MgCl₂ electrolyte with the addition of DEME•TFSI. Raman and NMR spectroscopy suggest that DEME•TFSI facilitates magnesium deposition/dissolution by improving ionic conductivity of the electrolyte.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1373600

Journal Information:: Journal of the Electrochemical Society, Vol. 164, Issue 4; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 16 works

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Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review Ma, Zheng; MacFarlane, Douglas R.; Kar, Mega Batteries & Supercaps, Vol. 2, Issue 2 https://doi.org/10.1002/batt.201800102	journal	January 2019
Rechargeable Magnesium Batteries using Conversion-Type Cathodes: A Perspective and Minireview Zhang, Zhonghua; Dong, Shamu; Cui, Zili Small Methods, Vol. 2, Issue 10 https://doi.org/10.1002/smtd.201800020	journal	July 2018
Strategic combination of Grignard reagents and allyl-functionalized ionic liquids as an advanced electrolyte for rechargeable magnesium batteries Lee, Boeun; Cho, Jae-Hyun; Seo, Hyo Ree Journal of Materials Chemistry A, Vol. 6, Issue 7 https://doi.org/10.1039/c7ta09330f	journal	January 2018

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