Sn Nanoparticles Encapsulated in 3D Nanoporous Carbon Derived from a Metal–Organic Framework for Anode Material in Lithium-Ion Batteries

Guo, Yuanyuan; Zeng, Xiaoqiao; Zhang, Yu; Dai, Zhengfei; Fan, Haosen; Huang, Ying; Zhang, Weina; Zhang, Hua; Lu, Jun; Huo, Fengwei; Yan, Qingyu

doi:10.1021/acsami.7b04561

Title: Sn Nanoparticles Encapsulated in 3D Nanoporous Carbon Derived from a Metal–Organic Framework for Anode Material in Lithium-Ion Batteries

Journal Article · Thu May 04 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.7b04561· OSTI ID:1372071

Guo, Yuanyuan ^[1]; Zeng, Xiaoqiao ^[2]; Zhang, Yu ^[3]; Dai, Zhengfei ^[3]; Fan, Haosen ^[3]; Huang, Ying ^[3]; Zhang, Weina ^[4];

^[3];

^[2];

^[4]; Yan, Qingyu ^[3]

Nanyang Technological Univ. (Singapore); Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Nanyang Technological Univ. (Singapore)
Nanjing Tech Univ., Nanjing (People's Republic of China)

Three-dimensional nanoporous carbon frameworks encapsulated Sn nanoparticles (Sn@3D-NPC) are developed by a facile method as an improved lithium ion battery anode. The Sn@3D-NPC delivers a reversible capacity of 740 mAh g^–1 after 200 cycles at a current density of 200 mA g^–1, corresponding to a capacity retention of 85% (against the second capacity) and high rate capability (300 mAh g^–1 at 5 A g^–1). Compared to the Sn nanoparticles (SnNPs), such improvements are attributed to the 3D porous and conductive framework. The whole structure can provide not only the high electrical conductivity that facilities the electron transfer but also the elasticity that will suppress the volume expansion and aggregation of SnNPs during the charge and discharge process. Lastly, this work opens a new application of metal–organic frameworks in energy storage.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1372071

Journal Information:: ACS Applied Materials and Interfaces, Vol. 9, Issue 20; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 82 works

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