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Title: l -Aspartate links for stable sodium metal–organic frameworks


Two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets using tetratopic aspartate-based linkers.

 [1];  [1];  [1];  [1]
  1. Department of Chemistry; University of California – Berkeley; Materials Sciences Division; Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute at Berkeley; Berkeley, USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Additional Journal Information:
Journal Volume: 51; Journal Issue: 98; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 1359-7345
Royal Society of Chemistry
Country of Publication:
United States
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Siman, Peter, Trickett, Christopher A., Furukawa, Hiroyasu, and Yaghi, Omar M. l -Aspartate links for stable sodium metal–organic frameworks. United States: N. p., 2015. Web. doi:10.1039/C5CC07578E.
Siman, Peter, Trickett, Christopher A., Furukawa, Hiroyasu, & Yaghi, Omar M. l -Aspartate links for stable sodium metal–organic frameworks. United States. doi:10.1039/C5CC07578E.
Siman, Peter, Trickett, Christopher A., Furukawa, Hiroyasu, and Yaghi, Omar M. Thu . "l -Aspartate links for stable sodium metal–organic frameworks". United States. doi:10.1039/C5CC07578E.
title = {l -Aspartate links for stable sodium metal–organic frameworks},
author = {Siman, Peter and Trickett, Christopher A. and Furukawa, Hiroyasu and Yaghi, Omar M.},
abstractNote = {Two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets using tetratopic aspartate-based linkers.},
doi = {10.1039/C5CC07578E},
journal = {ChemComm},
issn = {1359-7345},
number = 98,
volume = 51,
place = {United States},
year = {2015},
month = {1}

Works referenced in this record:

Recent advances in carbon dioxide capture with metal-organic frameworks
journal, August 2012

  • Liu, Yangyang; Wang, Zhiyong U.; Zhou, Hong-Cai
  • Greenhouse Gases: Science and Technology, Vol. 2, Issue 4
  • DOI: 10.1002/ghg.1296

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001

  • Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
  • Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
  • DOI: 10.1021/ar000034b

Molecular Tectonics:  From Simple Tectons to Complex Molecular Networks
journal, April 2005

  • Hosseini, Mir Wais
  • Accounts of Chemical Research, Vol. 38, Issue 4
  • DOI: 10.1021/ar0401799

Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009

  • Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283
  • DOI: 10.1039/b817735j

Recent Advances in s-Block Metal Carboxylate Networks
journal, October 2011

  • Banerjee, Debasis; Parise, John B.
  • Crystal Growth & Design, Vol. 11, Issue 10
  • DOI: 10.1021/cg2008304

Designed amyloid fibers as materials for selective carbon dioxide capture
journal, December 2013

  • Li, D.; Furukawa, H.; Deng, H.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 1
  • DOI: 10.1073/pnas.1321797111

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

4,4′-Biphenyldicarboxylate sodium coordination compounds as anodes for Na-ion batteries
journal, January 2014

  • Choi, Aram; Kim, Yun Kyeong; Kim, Tae Kyung
  • J. Mater. Chem. A, Vol. 2, Issue 36
  • DOI: 10.1039/C4TA02424A

Selective Capture of Carbon Dioxide under Humid Conditions by Hydrophobic Chabazite-Type Zeolitic Imidazolate Frameworks
journal, July 2014

  • Nguyen, Nhung T. T.; Furukawa, Hiroyasu; Gándara, Felipe
  • Angewandte Chemie International Edition, Vol. 53, Issue 40
  • DOI: 10.1002/anie.201403980

Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO 2 , N 2 , and H 2 O
journal, April 2015

  • Mason, Jarad A.; McDonald, Thomas M.; Bae, Tae-Hyun
  • Journal of the American Chemical Society, Vol. 137, Issue 14
  • DOI: 10.1021/jacs.5b00838

An Adaptable Peptide-Based Porous Material
journal, August 2010

Fluorous Metal-Organic Frameworks with Enhanced Stability and High H2/CO2 Storage Capacities
journal, November 2013

  • Zhang, Da-Shuai; Chang, Ze; Li, Yi-Fan
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep03312

Metal–Organic Frameworks (MOFs)
journal, January 2014

  • Zhou, Hong-Cai “Joe”; Kitagawa, Susumu
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS90059F

Novel alkali and alkaline earth metal coordination polymers based on 1,4-naphthalenedicarboxylic acid: synthesis, structural characterization and properties
journal, January 2014

  • Raja, Duraisamy Senthil; Luo, Jheng-Hong; Yeh, Chun-Ting
  • CrystEngComm, Vol. 16, Issue 10
  • DOI: 10.1039/c3ce42208a

Homochiral Helical Metal–Organic Frameworks of Group 1 Metals
journal, August 2013

  • Reger, Daniel L.; Leitner, Andrew; Smith, Mark D.
  • Inorganic Chemistry, Vol. 52, Issue 17
  • DOI: 10.1021/ic401327h

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
  • DOI: 10.1021/ja503296c

Solvothermal Synthesis, Structural Diversity, and Properties of Alkali Metal–Organic Frameworks Based on V-shaped Ligand
journal, July 2013

  • Senthil Raja, Duraisamy; Luo, Jheng-Hong; Wu, Cheng-You
  • Crystal Growth & Design, Vol. 13, Issue 8
  • DOI: 10.1021/cg400801s

High CO 2 /N 2 and CO 2 /CH 4 selectivity in a chiral metal–organic framework with contracted pores and multiple functionalities
journal, January 2014

  • Lv, Xiaoxia; Li, Liangjun; Tang, Sifu
  • Chem. Commun., Vol. 50, Issue 52
  • DOI: 10.1039/C4CC00334A

Tuning the structure and function of metal–organic frameworks via linker design
journal, January 2014

  • Lu, Weigang; Wei, Zhangwen; Gu, Zhi-Yuan
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00003J

Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
journal, February 2013

  • Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
  • Nature, Vol. 495, Issue 7439, p. 80-84
  • DOI: 10.1038/nature11893

Coordination polymers of alkali metal trithiocyanurates: structure determinations and ionic conductivity measurements using single crystals
journal, January 2013

  • Tominaka, Satoshi; Henke, Sebastian; Cheetham, Anthony K.
  • CrystEngComm, Vol. 15, Issue 45
  • DOI: 10.1039/c3ce41150h

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials
journal, August 2013

  • Wang, Cheng; Liu, Demin; Lin, Wenbin
  • Journal of the American Chemical Society, Vol. 135, Issue 36
  • DOI: 10.1021/ja308229p

Progress in adsorption-based CO 2 capture by metal–organic frameworks
journal, January 2012

  • Liu, Jian; Thallapally, Praveen K.; McGrail, B. Peter
  • Chem. Soc. Rev., Vol. 41, Issue 6
  • DOI: 10.1039/C1CS15221A

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011

  • O’Keeffe, Michael; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 675-702
  • DOI: 10.1021/cr200205j