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Title: Elucidating the origins of phase transformation hysteresis during electrochemical cycling of Li–Sb electrodes

Abstract

In this combined computational and experimental study, we identify the origins of phase transformation hysteresis during cycling of Sb electrodes, which undergoes alloying reactions upon lithiation.

Authors:
 [1];  [2];  [3];  [4];  [5];  [3];  [1]
  1. Materials Department; University of California; Santa Barbara; Santa Barbara, USA
  2. Department of Chemistry; University of Cambridge; Cambridge, UK; Harbin Institute of Technology; School of Chemical Engineering & Technology
  3. Department of Chemistry; University of Cambridge; Cambridge, UK
  4. CNRS; Universite de Bordeaux; Pessac F33600, France; ALISTORE-ERI; FR CNRS#3104
  5. Institut Charles Gerhardt Montpellier-UMR 5253 CNRS; ALISTORE European Research Institute (3104 CNRS); Université Montpellier 2; Montpellier, France; ALISTORE-ERI
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1370904
DOE Contract Number:  
SC0001294
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Materials Chemistry. A; Journal Volume: 3; Journal Issue: 37; Related Information: NECCES partners with Stony Brook University (lead); Argonne National Laboratory; Binghamton University; Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology; University of Michigan; Rutgers University
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), defects, charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Chang, Donghee, Huo, Hua, Johnston, Karen E., Ménétrier, Michel, Monconduit, Laure, Grey, Clare P., and Van der Ven, Anton. Elucidating the origins of phase transformation hysteresis during electrochemical cycling of Li–Sb electrodes. United States: N. p., 2015. Web. doi:10.1039/c5ta06183k.
Chang, Donghee, Huo, Hua, Johnston, Karen E., Ménétrier, Michel, Monconduit, Laure, Grey, Clare P., & Van der Ven, Anton. Elucidating the origins of phase transformation hysteresis during electrochemical cycling of Li–Sb electrodes. United States. doi:10.1039/c5ta06183k.
Chang, Donghee, Huo, Hua, Johnston, Karen E., Ménétrier, Michel, Monconduit, Laure, Grey, Clare P., and Van der Ven, Anton. Thu . "Elucidating the origins of phase transformation hysteresis during electrochemical cycling of Li–Sb electrodes". United States. doi:10.1039/c5ta06183k.
@article{osti_1370904,
title = {Elucidating the origins of phase transformation hysteresis during electrochemical cycling of Li–Sb electrodes},
author = {Chang, Donghee and Huo, Hua and Johnston, Karen E. and Ménétrier, Michel and Monconduit, Laure and Grey, Clare P. and Van der Ven, Anton},
abstractNote = {In this combined computational and experimental study, we identify the origins of phase transformation hysteresis during cycling of Sb electrodes, which undergoes alloying reactions upon lithiation.},
doi = {10.1039/c5ta06183k},
journal = {Journal of Materials Chemistry. A},
number = 37,
volume = 3,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}