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Title: Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii )

Abstract

Covalent tethering of a P 2N 2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a Cu I-catalyzed “click” reaction, followed by metallation with Ni II.

Authors:
 [1];  [2];  [1];  [1];  [1]
  1. Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland, USA
  2. Environmental Molecular Sciences Laboratory; Pacific Northwest National Laboratory; Richland, USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1370518
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Dalton Transactions; Journal Volume: 44; Journal Issue: 27; Related Information: CME partners with Pacific Northwest National Laboratory (lead); University of Illinois, Urbana-Champaign; Pennsylvania State University; University of Washington; University of Wyoming
Country of Publication:
United States
Language:
English
Subject:
catalysis (homogeneous), catalysis (heterogeneous), solar (fuels), bio-inspired, energy storage (including batteries and capacitors), hydrogen and fuel cells, charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Das, Atanu K., Engelhard, Mark H., Lense, Sheri, Roberts, John A. S., and Bullock, R. Morris. Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii ). United States: N. p., 2015. Web. doi:10.1039/C5DT00162E.
Das, Atanu K., Engelhard, Mark H., Lense, Sheri, Roberts, John A. S., & Bullock, R. Morris. Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii ). United States. doi:10.1039/C5DT00162E.
Das, Atanu K., Engelhard, Mark H., Lense, Sheri, Roberts, John A. S., and Bullock, R. Morris. Thu . "Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii )". United States. doi:10.1039/C5DT00162E.
@article{osti_1370518,
title = {Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii )},
author = {Das, Atanu K. and Engelhard, Mark H. and Lense, Sheri and Roberts, John A. S. and Bullock, R. Morris},
abstractNote = {Covalent tethering of a P2N2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction, followed by metallation with NiII.},
doi = {10.1039/C5DT00162E},
journal = {Dalton Transactions},
number = 27,
volume = 44,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}