Multicomponent Nanomaterials with Complex Networked Architectures from Orthogonal Degradation and Binary Metal Backfilling in ABC Triblock Terpolymers

Cowman, Christina D.; Padgett, Elliot; Tan, Kwan Wee; Hovden, Robert; Gu, Yibei; Andrejevic, Nina; Muller, David; Coates, Geoffrey W.; Wiesner, Ulrich

doi:10.1021/jacs.5b01915

Title: Multicomponent Nanomaterials with Complex Networked Architectures from Orthogonal Degradation and Binary Metal Backfilling in ABC Triblock Terpolymers

Journal Article · Wed May 13 00:00:00 EDT 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b01915· OSTI ID:1370437

Cowman, Christina D.; Padgett, Elliot; Tan, Kwan Wee; Hovden, Robert; Gu, Yibei; Andrejevic, Nina; Muller, David; Coates, Geoffrey W.; Wiesner, Ulrich

Selective degradation of block copolymer templates and backfilling the open mesopores is an effective strategy for the synthesis of nanostructured hybrid and inorganic materials. Incorporation of more than one type of inorganic material in orthogonal ways enables the synthesis of multicomponent nanomaterials with complex yet well-controlled architectures; however, developments in this field have been limited by the availability of appropriate orthogonally degradable block copolymers for use as templates. We report the synthesis and self-assembly into cocontinuous network structures of polyisoprene-block-polystyrene-block-poly(propylene carbonate) where the polyisoprene and poly(propylene carbonate) blocks can be orthogonally removed from the polymer film. Through sequential block etching and backfilling the resulting mesopores with different metals, we demonstrate first steps toward the preparation of three-component polymer–inorganic hybrid materials with two distinct metal networks. Multiblock copolymers in which two blocks can be degraded and backfilled independently of each other, without interference from the other, may be used in a wide range of applications requiring periodically ordered complex multicomponent nanoarchitectures.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Materials Center at Cornell (EMC2)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001086

OSTI ID:: 1370437

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 18; Related Information: Emc2 partners with Cornell University (lead); Lawrence Berkeley National Laboratory; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (47)

Ordered Network Mesostructures in Block Polymer Materials Meuler, Adam J.; Hillmyer, Marc A.; Bates, Frank S. Macromolecules, Vol. 42, Issue 19 https://doi.org/10.1021/ma9009593	journal	October 2009
Block Copolymers—Designer Soft Materials Bates, Frank S.; Fredrickson, Glenn H. Physics Today, Vol. 52, Issue 2 https://doi.org/10.1063/1.882522	journal	February 1999
Organically Modified Aluminosilicate Mesostructures from Block Copolymer Phases Templin, Markus; Franck, Achim; Du Chesne, Alexander Science, Vol. 278, Issue 5344 https://doi.org/10.1126/science.278.5344.1795	journal	December 1997
Hierarchically Ordered Oxides Yang, P.; Deng, T.; Zhao, D. Science, Vol. 282, Issue 5397 https://doi.org/10.1126/science.282.5397.2244	journal	December 1998
Synthesis and organization of zeolite-like materials with three-dimensional helical pores Gier, Thurman E.; Bu, Xianhui; Feng, Pingyun Nature, Vol. 395, Issue 6698 https://doi.org/10.1038/25960	journal	September 1998
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles Joo, Sang Hoon; Choi, Seong Jae; Oh, Ilwhan Nature, Vol. 412, Issue 6843 https://doi.org/10.1038/35084046	journal	July 2001
Ordered Mesoporous Materials from Metal Nanoparticle-Block Copolymer Self-Assembly Warren, S. C.; Messina, L. C.; Slaughter, L. S. Science, Vol. 320, Issue 5884, p. 1748-1752 https://doi.org/10.1126/science.1159950	journal	June 2008
Block Copolymer Self-Assembly–Directed Single-Crystal Homo- and Heteroepitaxial Nanostructures Arora, Hitesh; Du, Phong; Tan, Kwan W. Science, Vol. 330, Issue 6001, p. 214-219 https://doi.org/10.1126/science.1193369	journal	October 2010
Block copolymer template-directed synthesis of well-ordered metallic nanostructures Vukovic, Ivana; Brinke, Gerrit ten; Loos, Katja Polymer, Vol. 54, Issue 11 https://doi.org/10.1016/j.polymer.2013.03.013	journal	May 2013
Nanoprocessing Based on Bicontinuous Microdomains of Block Copolymers: Nanochannels Coated with Metals Hashimoto, Takeji; Tsutsumi, Kiyoharu; Funaki, Yoshinori Langmuir, Vol. 13, Issue 26 https://doi.org/10.1021/la970967p	journal	December 1997
Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates Thurn-Albrecht, T.; Schotter, J.; Kastle, G. A. Science, Vol. 290, Issue 5499, p. 2126-2129 https://doi.org/10.1126/science.290.5499.2126	journal	December 2000
A 3D Optical Metamaterial Made by Self-Assembly Vignolini, Silvia; Yufa, Nataliya A.; Cunha, Pedro S. Advanced Materials, Vol. 24, Issue 10 https://doi.org/10.1002/adma.201103610	journal	October 2011
A Bicontinuous Double Gyroid Hybrid Solar Cell Crossland, Edward J. W.; Kamperman, Marleen; Nedelcu, Mihaela Nano Letters, Vol. 9, Issue 8 https://doi.org/10.1021/nl803174p	journal	August 2009
Labyrinth-Induced Faceted Electrochemical Growth Scherer, Maik R. J.; Cunha, Pedro M. S.; Steiner, Ullrich Advanced Materials, Vol. 26, Issue 15 https://doi.org/10.1002/adma.201305074	journal	February 2014
Size-Selective Organization of Enthalpic Compatibilized Nanocrystals in Ternary Block Copolymer/Particle Mixtures Bockstaller, Michael R.; Lapetnikov, Yonit; Margel, Shlomo Journal of the American Chemical Society, Vol. 125, Issue 18 https://doi.org/10.1021/ja034523t	journal	May 2003
Linking experiment and theory for three-dimensional networked binary metal nanoparticle–triblock terpolymer superstructures Li, Zihui; Hur, Kahyun; Sai, Hiroaki Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4247	journal	February 2014
A Step-Wise Approach for Dual Nanoparticle Patterning via Block Copolymer Self-Assembly Horechyy, Andriy; Nandan, Bhanu; Zafeiropoulos, Nikolaos E. Advanced Functional Materials, Vol. 23, Issue 4 https://doi.org/10.1002/adfm.201201452	journal	September 2012
SCFT Study of Nonfrustrated ABC Triblock Copolymer Melts Tyler, Christopher A.; Qin, Jian; Bates, Frank S. Macromolecules, Vol. 40, Issue 13 https://doi.org/10.1021/ma062778w	journal	June 2007
Networked and chiral nanocomposites from ABC triblock terpolymer coassembly with transition metal oxide nanoparticles Stefik, Morgan; Wang, Suntao; Hovden, Robert J. Mater. Chem., Vol. 22, Issue 3 https://doi.org/10.1039/C1JM14113A	journal	January 2012
Cobalt Catalysts for the Alternating Copolymerization of Propylene Oxide and Carbon Dioxide: Combining High Activity and Selectivity Cohen, Claire T.; Chu, Tony; Coates, Geoffrey W. Journal of the American Chemical Society, Vol. 127, Issue 31 https://doi.org/10.1021/ja051744l	journal	August 2005
Immortal polymerization: The outset, development, and application Inoue, Shohei Journal of Polymer Science Part A: Polymer Chemistry, Vol. 38, Issue 16 https://doi.org/10.1002/1099-0518(20000815)38:16<2861::AID-POLA20>3.0.CO;2-1	journal	January 2000
‘Immortal’ polymerization. Polymerization of epoxide catalysed by an aluminium porphyrin–alcohol system Asano, Shoichi; Aida, Takuzo; Inoue, Shohei J. Chem. Soc., Chem. Commun., Issue 17 https://doi.org/10.1039/C39850001148	journal	January 1985
Morphological Behavior Bridging the Symmetric AB and ABC States in the Poly(styrene- b -isoprene- b -ethylene oxide) Triblock Copolymer System Bailey, Travis S.; Pham, Hoai D.; Bates, Frank S. Macromolecules, Vol. 34, Issue 20 https://doi.org/10.1021/ma0103371	journal	September 2001
Functionalization of carbon nanotubes by surface-initiated immortal alternating polymerization of CO ₂ and epoxides Wang, Yi-Ming; Song, Xiao-Yu; Shao, Song-Hai Polym. Chem., Vol. 4, Issue 3 https://doi.org/10.1039/C2PY20753B	journal	January 2013
Ordered Network Phases in Linear Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers Epps, Thomas H.; Cochran, Eric W.; Bailey, Travis S. Macromolecules, Vol. 37, Issue 22 https://doi.org/10.1021/ma048762s	journal	November 2004
Network Phases in ABC Triblock Copolymers Epps, Thomas H.; Cochran, Eric W.; Hardy, Cordell M. Macromolecules, Vol. 37, Issue 19 https://doi.org/10.1021/ma0493426	journal	September 2004
A Noncubic Triply Periodic Network Morphology in Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers Bailey, Travis S.; Hardy, Cordell M.; Epps, Thomas H. Macromolecules, Vol. 35, Issue 18 https://doi.org/10.1021/ma011716x	journal	August 2002
Comprehensive Phase Behavior of Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers Chatterjee, Joon; Jain, Sumeet; Bates, Frank S. Macromolecules, Vol. 40, Issue 8 https://doi.org/10.1021/ma062249s	journal	April 2007
Tunable 3D Extended Self-Assembled Gold Metamaterials with Enhanced Light Transmission Salvatore, Stefano; Demetriadou, Angela; Vignolini, Silvia Advanced Materials, Vol. 25, Issue 19 https://doi.org/10.1002/adma.201300193	journal	April 2013
Block Copolymer Lithography: Periodic Arrays of 10¹¹ Holes in 1 Square Centimeter Park, Miri; Harrison, Christopher; Chaikin, Paul M. Science, Vol. 276, Issue 5317, p. 1401-1404 https://doi.org/10.1126/science.276.5317.1401	journal	May 1997
Ordered Nanoporous Polymers from Polystyrene−Polylactide Block Copolymers Zalusky, Andrew S.; Olayo-Valles, Roberto; Wolf, Johanna H. Journal of the American Chemical Society, Vol. 124, Issue 43 https://doi.org/10.1021/ja0278584	journal	October 2002
Nanoscopic Templates from Oriented Block Copolymer Films Thurn-Albrecht, T.; Steiner, R.; DeRouchey, J. Advanced Materials, Vol. 12, Issue 11, p. 787-791 https://doi.org/10.1002/(SICI)1521-4095(200006)12:11<787::AID-ADMA787>3.0.CO;2-1	journal	June 2000
Nanoporous Polystyrene by Chemical Etching of Poly(ethylene oxide) from Ordered Block Copolymers Mao, Huiming; Hillmyer, Marc A. Macromolecules, Vol. 38, Issue 9 https://doi.org/10.1021/ma050008z	journal	May 2005
The metathetic degradation of polyisoprene and polybutadiene in block copolymers using Grubbs second generation catalyst Sedransk, Kyra L.; Kaminski, Clemens F.; Hutchings, Lian R. Polymer Degradation and Stability, Vol. 96, Issue 6 https://doi.org/10.1016/j.polymdegradstab.2011.03.007	journal	June 2011
Nanoporous Poly(lactide) by Olefin Metathesis Degradation Bertrand, Arthur; Hillmyer, Marc A. Journal of the American Chemical Society, Vol. 135, Issue 30 https://doi.org/10.1021/ja4050532	journal	July 2013
Functional Polyolefins Containing Disulfide and Phosphoester Groups: Synthesis and Orthogonal Degradation Chang, Chia-Chih; Emrick, Todd Macromolecules, Vol. 47, Issue 4 https://doi.org/10.1021/ma500121a	journal	February 2014
Nanopore and Nanobushing Arrays from ABC Triblock Thin Films Containing Two Etchable Blocks Guo, Shouwu; Rzayev, Javid; Bailey, Travis S. Chemistry of Materials, Vol. 18, Issue 7 https://doi.org/10.1021/cm052694m	journal	March 2006
Multiple Nanoscale Templates by Orthogonal Degradation of a Supramolecular Block Copolymer Lithographic System Tang, Chuanbing; Sivanandan, Kulandaivelu; Stahl, Brian C. ACS Nano, Vol. 4, Issue 1 https://doi.org/10.1021/nn901330q	journal	December 2009
Nanoporous Gyroid Nickel from Block Copolymer Templates via Electroless Plating Hsueh, Han-Yu; Huang, Yen-Chun; Ho, Rong-Ming Advanced Materials, Vol. 23, Issue 27 https://doi.org/10.1002/adma.201100883	journal	May 2011
Nanoporous Network Channels from Self-Assembled Triblock Copolymer Supramolecules: Nanoporous Network Channels from Self-Assembled … du Sart, Gerrit Gobius; Vukovic, Ivana; Vukovic, Zorica Macromolecular Rapid Communications, Vol. 32, Issue 4 https://doi.org/10.1002/marc.201000674	journal	December 2010
Nanoporous Metal Foams Tappan, Bryce C.; Steiner, Stephen A.; Luther, Erik P. Angewandte Chemie International Edition, Vol. 49, Issue 27 https://doi.org/10.1002/anie.200902994	journal	May 2010
Photo-degradation of synthetic and natural polyisoprenes at specific UV radiations dos Santos, K. A. M.; Suarez, P. A. Z.; Rubim, J. C. Polymer Degradation and Stability, Vol. 90, Issue 1 https://doi.org/10.1016/j.polymdegradstab.2005.01.038	journal	October 2005
Photo-oxidative degradation in polyisoprene: surface characterization and analysis by atomic force microscopy Blach, Jolanta A.; Watson, Gregory S.; Busfield, W. Ken Polymer International, Vol. 51, Issue 1 https://doi.org/10.1002/pi.780	journal	January 2001
Well-Defined Multibranched Gold with Surface Plasmon Resonance in Near-Infrared Region from Seeding Growth Approach Using Gyroid Block Copolymer Template Hsueh, Han-Yu; Chen, Hung-Ying; Hung, Yu-Chueh Advanced Materials, Vol. 25, Issue 12 https://doi.org/10.1002/adma.201204631	journal	January 2013
Electroless Deposition of Nanoscale Copper Patterns via Microphase-Separated Diblock Copolymer Templated Self-Assembly Zehner, Robert W.; Sita, Lawrence R. Langmuir, Vol. 15, Issue 19 https://doi.org/10.1021/la9907782	journal	September 1999
Effect of Surface Chemistry on the Stability of Gold Nanostructures Biener, Juergen; Wittstock, Arne; Biener, Monika M. Langmuir, Vol. 26, Issue 17 https://doi.org/10.1021/la1019422	journal	September 2010
Cobalt catalysts for the coupling of CO ₂ and epoxides to provide polycarbonates and cyclic carbonates Lu, Xiao-Bing; Darensbourg, Donald J. Chem. Soc. Rev., Vol. 41, Issue 4 https://doi.org/10.1039/c1cs15142h	journal	January 2012

Cited By (18)

Di-Zinc-Aryl Complexes: CO ₂ Insertions and Applications in Polymerisation Catalysis Romain, Charles; Garden, Jennifer A.; Trott, Gemma Chemistry - A European Journal, Vol. 23, Issue 30 https://doi.org/10.1002/chem.201701013	journal	May 2017
Fit-for-purpose block polymer membranes molecularly engineered for water treatment Zhang, Yizhou; Almodovar-Arbelo, Noelia E.; Weidman, Jacob L. npj Clean Water, Vol. 1, Issue 1 https://doi.org/10.1038/s41545-018-0002-1	journal	April 2018
Fate and risk of metal sulfide nanoparticles in the environment Ubaid, Khan Ashfeen; Zhang, Xiaoxia; Sharma, Virender K. Environmental Chemistry Letters, Vol. 18, Issue 1 https://doi.org/10.1007/s10311-019-00920-x	journal	August 2019
Nanomaterial datasets to advance tomography in scanning transmission electron microscopy Levin, Barnaby D. A.; Padgett, Elliot; Chen, Chien-Chun Scientific Data, Vol. 3, Issue 1 https://doi.org/10.1038/sdata.2016.41	journal	June 2016
Construction of Versatile and Functional Nanostructures Derived from CO ₂ -based Polycarbonates Wang, Yanyan; Fan, Jingwei; Darensbourg, Donald J. Angewandte Chemie International Edition, Vol. 54, Issue 35 https://doi.org/10.1002/anie.201505076	journal	July 2015
Effect of electronic modification on nanostructures stability to degradation Kozlovskiy, А; Kenzhina, I.; Kaikanov, М Materials Research Express, Vol. 5, Issue 7 https://doi.org/10.1088/2053-1591/aacfa4	journal	July 2018
Soft self-assembly of Weyl materials for light and sound Fruchart, Michel; Jeon, Seung-Yeol; Hur, Kahyun Proceedings of the National Academy of Sciences, Vol. 115, Issue 16 https://doi.org/10.1073/pnas.1720828115	journal	April 2018
A vesicle-aggregation-assembly approach to highly ordered mesoporous γ-alumina microspheres with shifted double-diamond networks Liu, Yang; Teng, Wei; Chen, Gang Chemical Science, Vol. 9, Issue 39 https://doi.org/10.1039/c8sc02967a	journal	January 2018
Functional Polycarbonates from Carbon Dioxide and Tailored Epoxide Monomers: Degradable Materials and Their Application Potential Scharfenberg, Markus; Hilf, Jeannette; Frey, Holger Advanced Functional Materials, Vol. 28, Issue 10 https://doi.org/10.1002/adfm.201704302	journal	January 2018
Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO ₂ ‐Based Block Copolymers from Monomer Mixtures Zhao, Yajun; Wang, Yong; Zhou, Xingping Angewandte Chemie, Vol. 131, Issue 40 https://doi.org/10.1002/ange.201906140	journal	August 2019
Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO ₂ ‐Based Block Copolymers from Monomer Mixtures Zhao, Yajun; Wang, Yong; Zhou, Xingping Angewandte Chemie International Edition, Vol. 58, Issue 40 https://doi.org/10.1002/anie.201906140	journal	August 2019
Polymer-guided assembly of inorganic nanoparticles Yi, Chenglin; Yang, Yiqun; Liu, Ben Chemical Society Reviews, Vol. 49, Issue 2 https://doi.org/10.1039/c9cs00725c	journal	January 2020
Multiscale Phase Separations for Hierarchically Ordered Macro/Mesostructured Metal Oxides Jo, Changshin; Hwang, Jongkook; Lim, Won-Gwang Advanced Materials, Vol. 30, Issue 6 https://doi.org/10.1002/adma.201703829	journal	December 2017
Chain transfer agents utilized in epoxide and CO ₂ copolymerization processes Darensbourg, Donald J. Green Chemistry, Vol. 21, Issue 9 https://doi.org/10.1039/c9gc00620f	journal	January 2019
Construction of Versatile and Functional Nanostructures Derived from CO ₂ -based Polycarbonates Wang, Yanyan; Fan, Jingwei; Darensbourg, Donald J. Angewandte Chemie, Vol. 127, Issue 35 https://doi.org/10.1002/ange.201505076	journal	July 2015
Soft self-assembly of Weyl materials for light and sound Fruchart, Michel; Jeon, Seung-Yeol; Hur, Kahyun arXiv https://doi.org/10.48550/arxiv.1711.11019	text	January 2017
Controlled Synthesis of Uniform Cobalt Phosphide Hyperbranched Nanocrystals Using Tri- n -octylphosphine Oxide as a Phosphorus Source Zhang, Haitao; Ha, Don-Hyung; Hovden, Robert Nano Letters, Vol. 11, Issue 1 https://doi.org/10.1021/nl103400a	journal	January 2011
Nanomaterial datasets to advance tomography in scanning transmission electron microscopy Levin, Barnaby D. A.; Padgett, Elliot; Chen, Chien-Chun arXiv https://doi.org/10.48550/arxiv.1606.02938	text	January 2016

Similar Records

Multicomponent nanomaterials with complex networked architectures from orthogonal degradation and binary metal backfilling in ABC triblock terpolymers

Journal Article · Thu Apr 02 00:00:00 EDT 2015 · Journal of the American Chemical Society · OSTI ID:1370437

Cowman, Christina D.; Padgett, Elliot; Tan, Kwan Wee; +6 more

Surfactant-directed synthesis of mesoporous films made single-step by a tandem photosol-gel/photocalcination route

Journal Article · Sat Nov 01 00:00:00 EDT 2014 · APL Materials · OSTI ID:1370437

De Paz-Simon, Héloïse; Chemtob, Abraham; Croutxé-Barghorn, Céline; +4 more

Morphologies of ABC Triblock Terpolymer Melts Containing Poly(Cyclohexadiene): Effects of Conformational Asymmetry

Journal Article · Sun Dec 23 00:00:00 EST 2012 · Langmuir · OSTI ID:1370437

Kumar, Rajeev; Sides, Scott W.; Goswami, Monojoy; +12 more

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Multicomponent Nanomaterials with Complex Networked Architectures from Orthogonal Degradation and Binary Metal Backfilling in ABC Triblock Terpolymers

Citation Formats

References (47)

Cited By (18)

Similar Records

Related Subjects