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Title: Mesoporous Ni 60 Fe 30 Mn 10 -alloy based metal/metal oxide composite thick films as highly active and robust oxygen evolution catalysts

Abstract

Mesoporous NiFeMn-based electrocatalysts made by selective alloy corrosion stably produce O 2from water for more than eleven days in 1 M KOH at a current density of 500 mA cm -2and an overpotential of just 360 mV.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [2]
  1. Department of Chemistry & Biochemistry; University of California–Los Angeles (UCLA); Los Angeles, USA
  2. Department of Chemistry & Biochemistry; University of California–Los Angeles (UCLA); Los Angeles, USA; Department of Materials Science & Engineering and the California NanoSystems Institute; University of California–Los Angeles (UCLA)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Molecularly Engineered Energy Materials (MEEM)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1370231
DOE Contract Number:  
SC0001342
Resource Type:
Journal Article
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 2; Related Information: MEEM partners with University of California, Los Angeles (lead); University of California, Berkeley; Eastern Washington University; University of Kansas; National Renewable Energy Laboratory; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Detsi, Eric, Cook, John B., Lesel, Benjamin K., Turner, Christopher L., Liang, Yu-Lun, Robbennolt, Shauna, and Tolbert, Sarah H. Mesoporous Ni 60 Fe 30 Mn 10 -alloy based metal/metal oxide composite thick films as highly active and robust oxygen evolution catalysts. United States: N. p., 2016. Web. doi:10.1039/c5ee02509e.
Detsi, Eric, Cook, John B., Lesel, Benjamin K., Turner, Christopher L., Liang, Yu-Lun, Robbennolt, Shauna, & Tolbert, Sarah H. Mesoporous Ni 60 Fe 30 Mn 10 -alloy based metal/metal oxide composite thick films as highly active and robust oxygen evolution catalysts. United States. doi:10.1039/c5ee02509e.
Detsi, Eric, Cook, John B., Lesel, Benjamin K., Turner, Christopher L., Liang, Yu-Lun, Robbennolt, Shauna, and Tolbert, Sarah H. Fri . "Mesoporous Ni 60 Fe 30 Mn 10 -alloy based metal/metal oxide composite thick films as highly active and robust oxygen evolution catalysts". United States. doi:10.1039/c5ee02509e.
@article{osti_1370231,
title = {Mesoporous Ni 60 Fe 30 Mn 10 -alloy based metal/metal oxide composite thick films as highly active and robust oxygen evolution catalysts},
author = {Detsi, Eric and Cook, John B. and Lesel, Benjamin K. and Turner, Christopher L. and Liang, Yu-Lun and Robbennolt, Shauna and Tolbert, Sarah H.},
abstractNote = {Mesoporous NiFeMn-based electrocatalysts made by selective alloy corrosion stably produce O2from water for more than eleven days in 1 M KOH at a current density of 500 mA cm-2and an overpotential of just 360 mV.},
doi = {10.1039/c5ee02509e},
journal = {Energy & Environmental Science},
issn = {1754-5692},
number = 2,
volume = 9,
place = {United States},
year = {2016},
month = {1}
}

Works referenced in this record:

Evolution of nanoporosity in dealloying
journal, March 2001

  • Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain
  • Nature, Vol. 410, Issue 6827, p. 450-453
  • DOI: 10.1038/35068529

Solar Water Splitting Cells
journal, November 2010

  • Walter, Michael G.; Warren, Emily L.; McKone, James R.
  • Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
  • DOI: 10.1021/cr1002326

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal, August 2008