Dramatically enhanced reversibility of Li2O in SnO2-based electrodes: the effect of nanostructure on high initial reversible capacity

Hu, Renzong; Chen, Dongchang; Waller, Gordon; Ouyang, Yunpeng; Chen, Yu; Zhao, Bote; Rainwater, Ben; Yang, Chenghao; Zhu, Min; Liu, Meilin

doi:10.1039/c5ee03367e

Title: Dramatically enhanced reversibility of Li₂O in SnO₂-based electrodes: the effect of nanostructure on high initial reversible capacity

Journal Article · Tue Dec 01 00:00:00 EST 2015 · Energy & Environmental Science

DOI:https://doi.org/10.1039/c5ee03367e· OSTI ID:1370140

Hu, Renzong ^[1]; Chen, Dongchang ^[2]; Waller, Gordon ^[2]; Ouyang, Yunpeng ^[3]; Chen, Yu ^[2]; Zhao, Bote ^[2]; Rainwater, Ben ^[2]; Yang, Chenghao ^[3]; Zhu, Min ^[3]; Liu, Meilin ^[4]

South China Univ. of Technology (SCUT), Guangzhou (China); Georgia Inst. of Technology, Atlanta, GA (United States)
Georgia Inst. of Technology, Atlanta, GA (United States)
South China Univ. of Technology (SCUT), Guangzhou (China)
Georgia Inst. of Technology, Atlanta, GA (United States); South China Univ. of Technology (SCUT), Guangzhou (China)

The formation of irreversible Li₂O during discharge is believed to be the main cause of large capacity loss and low Coulombic efficiency of oxide negative electrodes for Li batteries. This assumption may have misguided the development of high-capacity SnO₂-based anodes in recent years. In this work we demonstrated that contrary to this perception, Li₂O can indeed be highly reversible in a SnO₂ electrode with controlled nanostructure and achieved an initial Coulombic efficiency of ~95.5%, much higher than that previously believed to be possible (52.4%). In situ spectroscopic and diffraction analyses corroborate highly reversible electrochemical cycling, suggesting that the interfaces and grain boundaries of nano-sized SnO₂ may suppress the coarsening of Sn and enable the conversion between Li₂O and Sn to amorphous SnO₂ when de-lithiated. These results provide important insight into the rational design of high-performance oxide electrodes for Li-ion batteries.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC); Doctorate Foundation of Ministry of Education; Foundation for the Author of Excellent Doctoral Dissertation of Guangdong Province

Grant/Contract Number:: SC0001061

OSTI ID:: 1370140

Journal Information:: Energy & Environmental Science, Vol. 9, Issue 2; Related Information: HeteroFoaM partners with University of South Carolina (lead); University of California, Santa Barbara; University of Connecticut; Georgia Institute of Technology; Princeton University; Rochester Institute of Technology; Savannah River National Laboratory; University of South Carolina; University of Utah; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 267 works

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Title: Dramatically enhanced reversibility of Li₂O in SnO₂-based electrodes: the effect of nanostructure on high initial reversible capacity