Low-current field-assisted assembly of copper nanoparticles for current collectors

Liu, Lehao; Choi, Bong Gill; Tung, Siu On; Hu, Tao; Liu, Yajie; Li, Tiehu; Zhao, Tingkai; Kotov, Nicholas A.

doi:10.1039/c4fd00263f

Title: Low-current field-assisted assembly of copper nanoparticles for current collectors

Journal Article · Thu May 21 00:00:00 EDT 2015 · Faraday Discussions

DOI:https://doi.org/10.1039/c4fd00263f· OSTI ID:1370094

Liu, Lehao ^[1]; Choi, Bong Gill ^[2]; Tung, Siu On ^[3]; Hu, Tao ^[3]; Liu, Yajie ^[3]; Li, Tiehu ^[4]; Zhao, Tingkai ^[4]; Kotov, Nicholas A. ^[5]

Northwestern Polytechnical Univ., Shaanxi (China); Univ. of Michigan, Ann Arbor, MI (United States)
Univ. of Michigan, Ann Arbor, MI (United States); Kangwon National Univ., Samcheok (Korea)
Univ. of Michigan, Ann Arbor, MI (United States)
Northwestern Polytechnical Univ., Shaanxi (China)
Department of Chemical Engineering; University of Michigan; Ann Arbor, USA; Biointerfaces Institute; University of Michigan

Current collectors are essential features of batteries and many other electronic devices being responsible for efficient charge transport to active electrode materials. Three-dimensional (3D), high surface area current collectors considerably improve the performance of cathodes and anodes in batteries, but their technological implementation is impeded by the complexity of their preparation, which needs to be simple, fast, and energy efficient. In this paper we demonstrate that field-stimulated assembly of ~3 nm copper nanoparticles (NPs) enables the preparation of porous Cu NP films. The use of NP dispersions enables 30× reduction of the deposition current for making functional 3D coatings. In addition to high surface area, lattice-to-lattice connectivity in the self-assembly of NPs in 3D structures enables fast charge transport. The mesoscale dimensions of out-of-plane features and the spacing between them in Cu films made by field-stimulated self-assembly of NPs provides promising morphology for current collection in lithium ion batteries (LIBs). Half-cell electrochemical models based on self-assembled films show improved specific capacity, total capacity, and cycling performance compared to traditional flat and other 3D current collectors. While integration of active electrode material into the 3D topography of the current collector needs to be improved, this study indicates that self-assembled NP films represent a viable manufacturing approach for 3D electrodes.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Solar and Thermal Energy Conversion (CSTEC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); China Scholarship Council (CSC); Samsung

Grant/Contract Number:: SC0000957

OSTI ID:: 1370094

Journal Information:: Faraday Discussions, Vol. 181; Related Information: CSTEC partners with University of Michigan (lead); Kent State University; ISSN 1359-6640

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 17 works

Citation information provided by
Web of Science

References (81)

Binder effect on cycling performance of silicon/carbon composite anodes for lithium ion batteries Chen, Libao; Xie, Xiaohua; Xie, Jingying Journal of Applied Electrochemistry, Vol. 36, Issue 10 https://doi.org/10.1007/s10800-006-9191-2	journal	August 2006
High rate capabilities Fe₃O₄-based Cu nano-architectured electrodes for lithium-ion battery applications Taberna, P. L.; Mitra, S.; Poizot, P. Nature Materials, Vol. 5, Issue 7, p. 567-573 https://doi.org/10.1038/nmat1672	journal	June 2006
Synthesis and Rate Performance of Monolithic Macroporous Carbon Electrodes for Lithium-Ion Secondary Batteries Lee, K. T.; Lytle, J. C.; Ergang, N. S. Advanced Functional Materials, Vol. 15, Issue 4 https://doi.org/10.1002/adfm.200400186	journal	April 2005
Assembly of Highly Ordered Three-Dimensional Porous Structure with Nanocrystalline TiO ₂ Semiconductors Meng, Q. -B.; Fu, C. -H.; Einaga, Y. Chemistry of Materials, Vol. 14, Issue 1 https://doi.org/10.1021/cm0101576	journal	January 2002
Carbon materials for lithium-ion (shuttlecock) cells Sawai, K.; Iwakoshi, Y.; Ohzuku, T. Solid State Ionics, Vol. 69, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90416-2	journal	August 1994
Three-dimensional nanoarchitecture of Sn–Sb–Co alloy as an anode of lithium-ion batteries with excellent lithium storage performance Ke, Fu-Sheng; Huang, Ling; Solomon, Bryan C. Journal of Materials Chemistry, Vol. 22, Issue 34 https://doi.org/10.1039/c2jm32162a	journal	January 2012
One-step green route to narrowly dispersed copper nanocrystals Wu, Chunwei; Mosher, Brian P.; Zeng, Taofang Journal of Nanoparticle Research, Vol. 8, Issue 6 https://doi.org/10.1007/s11051-005-9065-2	journal	March 2006
Charge–discharge stability of graphite anodes for lithium-ion batteries Wang, Chunsheng; Appleby, A. John; Little, Frank E. Journal of Electroanalytical Chemistry, Vol. 497, Issue 1-2 https://doi.org/10.1016/S0022-0728(00)00447-2	journal	February 2001
On the compressive behaviour of sintered porous coppers with low to medium porosities—Part I: Experimental study Zhang, Erlin; Wang, Bin International Journal of Mechanical Sciences, Vol. 47, Issue 4-5 https://doi.org/10.1016/j.ijmecsci.2004.12.011	journal	April 2005
Spontaneous Self-Organization Enables Dielectrophoresis of Small Nanoparticles and Formation of Photoconductive Microbridges Jung, Seung-Ho; Chen, Chen; Cha, Sang-Ho Journal of the American Chemical Society, Vol. 133, Issue 28 https://doi.org/10.1021/ja200422s	journal	July 2011
Li Segregation Induces Structure and Strength Changes at the Amorphous Si/Cu Interface Stournara, Maria E.; Xiao, Xingcheng; Qi, Yue Nano Letters, Vol. 13, Issue 10 https://doi.org/10.1021/nl402353k	journal	September 2013
Silica-coating of metallic copper nanoparticles in aqueous solution Kobayashi, Y.; Sakuraba, T. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 317, Issue 1-3 https://doi.org/10.1016/j.colsurfa.2007.11.009	journal	March 2008
Preparation of 3D nanoporous copper-supported cuprous oxide for high-performance lithium ion battery anodes Liu, Dequan; Yang, Zhibo; Wang, Peng Nanoscale, Vol. 5, Issue 5 https://doi.org/10.1039/c2nr33383j	journal	January 2013
Carbon paper as three-dimensional conducting substrate for tin anodes in lithium-ion batteries Arbizzani, C.; Beninati, S.; Lazzari, M. Journal of Power Sources, Vol. 141, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.09.013	journal	February 2005
Three-dimensional porous Sn–Cu alloy anode for lithium-ion batteries Xue, Leigang; Fu, Zhenghao; Yao, Yu Electrochimica Acta, Vol. 55, Issue 24 https://doi.org/10.1016/j.electacta.2010.07.015	journal	October 2010
Anisotropic mechanical properties of porous copper fabricated by unidirectional solidification Hyun, S. K.; Murakami, K.; Nakajima, H. Materials Science and Engineering: A, Vol. 299, Issue 1-2 https://doi.org/10.1016/S0921-5093(00)01402-7	journal	February 2001
Optimization of electrolytic process of formation of open and porous copper electrodes by the pulsating current (PC) regime Nikolić, Nebojša D.; Branković, Goran; Popov, Konstantin I. Materials Chemistry and Physics, Vol. 125, Issue 3 https://doi.org/10.1016/j.matchemphys.2010.10.013	journal	February 2011
Effect of poly(acrylic acid) on adhesion strength and electrochemical performance of natural graphite negative electrode for lithium-ion batteries Lee, Jin-Hyon; Paik, Ungyu; Hackley, Vincent A. Journal of Power Sources, Vol. 161, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.03.087	journal	October 2006
Synthesis and Characterization of Monodispersed Copper Colloids in Polar Solvents Yu, Wei; Xie, Huaqing; Chen, Lifei Nanoscale Research Letters, Vol. 4, Issue 5 https://doi.org/10.1007/s11671-009-9264-3	journal	February 2009
In situ observation of oxidation and reduction of small supported copper particles using optical absorption and X-ray diffraction Yanase, Akihisa; Komiyama, Hiroshi Surface Science, Vol. 248, Issue 1-2 https://doi.org/10.1016/0039-6028(91)90056-X	journal	May 1991
Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor ACS Applied Materials & Interfaces, Vol. 2, Issue 11 https://doi.org/10.1021/am100871y	journal	October 2010
Nickel-Foam-Supported Reticular CoO-Li2O Composite Anode Materials for Lithium Ion Batteries Yu, Yan; Chen, Chun-Hua; Shui, Jiang-Lan Angewandte Chemie International Edition, Vol. 44, Issue 43 https://doi.org/10.1002/anie.200501905	journal	November 2005
Facile synthesis and self-assembly of hierarchical porous NiO nano/micro spherical superstructures for high performance supercapacitors Yuan, Changzhou; Zhang, Xiaogang; Su, Linhao Journal of Materials Chemistry, Vol. 19, Issue 32 https://doi.org/10.1039/b902221j	journal	January 2009
Three-dimensionally porous Fe3O4 as high-performance anode materials for lithium–ion batteries Wu, Hao; Du, Ning; Wang, Jiazheng Journal of Power Sources, Vol. 246 https://doi.org/10.1016/j.jpowsour.2013.07.063	journal	January 2014
Lost carbonate sintering process for manufacturing metal foams Zhao, Y. Y.; Fung, T.; Zhang, L. P. Scripta Materialia, Vol. 52, Issue 4 https://doi.org/10.1016/j.scriptamat.2004.10.012	journal	February 2005
A modified graphite anode with high initial efficiency and excellent cycle life expectation Guoping, W.; Bolan, Z.; Min, Y. Solid State Ionics, Vol. 176, Issue 9-10 https://doi.org/10.1016/j.ssi.2004.11.009	journal	March 2005
Effects of Surface Chemistry on the Generation of Reactive Oxygen Species by Copper Nanoparticles Shi, Miao; Kwon, Hyun Soo; Peng, Zhenmeng ACS Nano, Vol. 6, Issue 3 https://doi.org/10.1021/nn300445d	journal	February 2012
A dendrite-suppressing composite ion conductor from aramid nanofibres Tung, Siu-On; Ho, Szushen; Yang, Ming Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7152	journal	January 2015
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices Guo, Yu-Guo; Hu, Jin-Song; Wan, Li-Jun Advanced Materials, Vol. 20, Issue 15 https://doi.org/10.1002/adma.200800627	journal	August 2008
Templateassisted selfassembly of macro–micro bifunctional porous materials Zhu, Guangshan; Qiu, Shilun; Gao, Feifei Journal of Materials Chemistry, Vol. 11, Issue 6 https://doi.org/10.1039/b008801n	journal	January 2001
Study of poly(acrylonitrile-methyl methacrylate) as binder for graphite anode and LiMn2O4 cathode of Li-ion batteries Zhang, S. S.; Jow, T. R. Journal of Power Sources, Vol. 109, Issue 2 https://doi.org/10.1016/S0378-7753(02)00107-6	journal	July 2002
Lithiation/Delithiation Performance of Cu[sub 6]Sn[sub 5] with Carbon Paper as Current Collector Arbizzani, Catia; Lazzari, Mariachiara; Mastragostino, Marina Journal of The Electrochemical Society, Vol. 152, Issue 2 https://doi.org/10.1149/1.1839466	journal	January 2005
Mechanical and physical characterization of copper foam El-Hadek, Medhat Awad; Kaytbay, Saleh International Journal of Mechanics and Materials in Design, Vol. 4, Issue 1 https://doi.org/10.1007/s10999-008-9058-2	journal	January 2008
A new method for preparing hydrophobic nano-copper powders Jian-guang, Yang; Yuang-lin, Zhou; Okamoto, Takeshi Journal of Materials Science, Vol. 42, Issue 18 https://doi.org/10.1007/s10853-007-1899-9	journal	September 2007
Nanomaterials for Rechargeable Lithium Batteries Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946 https://doi.org/10.1002/anie.200702505	journal	April 2008
Stretchable nanoparticle conductors with self-organized conductive pathways Kim, Yoonseob; Zhu, Jian; Yeom, Bongjun Nature, Vol. 500, Issue 7460, p. 59-63 https://doi.org/10.1038/nature12401	journal	July 2013
Sn–Co alloy anode using porous Cu as current collector for lithium ion battery Fan, Xiao-Yong; Ke, Fu-Sheng; Wei, Guo-Zhen Journal of Alloys and Compounds, Vol. 476, Issue 1-2, p. 70-73 https://doi.org/10.1016/j.jallcom.2008.09.030	journal	May 2009
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
Surface-Modified Graphite as an Improved Intercalating Anode for Lithium-Ion Batteries Cao, Yuliang; Xiao, Lifen; Ai, Xinping Electrochemical and Solid-State Letters, Vol. 6, Issue 2 https://doi.org/10.1149/1.1534730	journal	January 2003
Evaluation on dispersion behavior of the aqueous copper nano-suspensions Li, Xinfang; Zhu, Dongsheng; Wang, Xianju Journal of Colloid and Interface Science, Vol. 310, Issue 2 https://doi.org/10.1016/j.jcis.2007.02.067	journal	June 2007
Electrodeposition and lithium storage performance of novel three-dimensional porous Fe–Sb–P amorphous alloy electrode Huang, Ling; Zheng, Xiao-Mei; Wu, Yun-Shi Electrochemistry Communications, Vol. 11, Issue 3 https://doi.org/10.1016/j.elecom.2008.12.054	journal	March 2009
Effect of transference velocity and hydrogen pressure on porosity and pore morphology of lotus-type porous copper fabricated by a continuous casting technique Park, J. S.; Hyun, S. K.; Suzuki, S. Acta Materialia, Vol. 55, Issue 16 https://doi.org/10.1016/j.actamat.2007.06.022	journal	September 2007
Lithium storage performance and interfacial processes of three dimensional porous Sn–Co alloy electrodes for lithium-ion batteries Xue, Lian-Jie; Xu, Yue-Feng; Huang, Ling Electrochimica Acta, Vol. 56, Issue 17 https://doi.org/10.1016/j.electacta.2011.04.103	journal	July 2011
Nickel Foam-Supported Porous NiO∕Ag Film Electrode for Lithium-Ion Batteries Huang, X. H.; Tu, J. P.; Zeng, Z. Y. Journal of The Electrochemical Society, Vol. 155, Issue 6 https://doi.org/10.1149/1.2904878	journal	January 2008
Mathematical modeling of the capacity fade of Li-ion cells Ramadass, P.; Haran, Bala; White, Ralph Journal of Power Sources, Vol. 123, Issue 2 https://doi.org/10.1016/S0378-7753(03)00531-7	journal	September 2003
Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji Nano Letters, Vol. 8, Issue 8, p. 2277-2282 https://doi.org/10.1021/nl800957b	journal	August 2008
Spontaneous Organization of Single CdTe Nanoparticles into Luminescent Nanowires Tang, Z. Science, Vol. 297, Issue 5579 https://doi.org/10.1126/science.1072086	journal	July 2002
Kinetic Characterization of the Electrochemical Intercalation of Lithium Ions into Graphite Electrodes Chang, Yu-Chi; Jong, Jyh-Hwa; Fey, George Ting-Kuo Journal of The Electrochemical Society, Vol. 147, Issue 6 https://doi.org/10.1149/1.1393481	journal	January 2000
Synthesis of metallic copper nanoparticles coated with polypyrrole Kobayashi, Yoshio; Ishida, Satoshi; Ihara, Kazuaki Colloid and Polymer Science, Vol. 287, Issue 7 https://doi.org/10.1007/s00396-009-2047-7	journal	May 2009
Unknown Aspects of Self-Assembly of PbS Microscale Superstructures Querejeta-Fernández, Ana; Hernández-Garrido, Juan C.; Yang, Hengxi ACS Nano, Vol. 6, Issue 5 https://doi.org/10.1021/nn300890s	journal	April 2012
Charge Transport Dilemma of Solution-Processed Nanomaterials Kim, Ji-Young; Kotov, Nicholas A. Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm402675k	journal	September 2013
Preparation and characterization of silicon-based three-dimensional cellular anode for lithium ion battery Jiang, Tao; Zhang, Shichao; Qiu, Xinping Electrochemistry Communications, Vol. 9, Issue 5 https://doi.org/10.1016/j.elecom.2006.11.031	journal	May 2007
High-Capacity Lithium–Air Cathodes Beattie, S. D.; Manolescu, D. M.; Blair, S. L. Journal of The Electrochemical Society, Vol. 156, Issue 1 https://doi.org/10.1149/1.3005989	journal	January 2009
A free-standing-type design for cathodes of rechargeable Li–O2 batteries Cui, Yanming; Wen, Zhaoyin; Liu, Yu Energy & Environmental Science, Vol. 4, Issue 11 https://doi.org/10.1039/c1ee02365a	journal	January 2011
Colossal Reversible Volume Changes in Lithium Alloys Beaulieu, L. Y.; Eberman, K. W.; Turner, R. L. Electrochemical and Solid-State Letters, Vol. 4, Issue 9 https://doi.org/10.1149/1.1388178	journal	January 2001
Ultrathin Graphite Foam: A Three-Dimensional Conductive Network for Battery Electrodes Ji, Hengxing; Zhang, Lili; Pettes, Michael T. Nano Letters, Vol. 12, Issue 5 https://doi.org/10.1021/nl300528p	journal	April 2012
Spinel Li[Li1/3Ti5/3]O4 as an anode material for lithium ion batteries Wang, G. X.; Bradhurst, D. H.; Dou, S. X. Journal of Power Sources, Vol. 83, Issue 1-2 https://doi.org/10.1016/S0378-7753(99)00290-6	journal	October 1999
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries Kang, Kisuk; Shirley Meng, Ying; Breger, Julien Science, Vol. 311, Issue 5763, p. 977-980 https://doi.org/10.1126/science.1122152	journal	February 2006
Electrodeposition and lithium storage performance of three-dimensional porous reticular Sn–Ni alloy electrodes Huang, Ling; Wei, Hong-Bing; Ke, Fu-Sheng Electrochimica Acta, Vol. 54, Issue 10, p. 2693-2698 https://doi.org/10.1016/j.electacta.2008.11.044	journal	April 2009
Preparation and characterization of tin-based three-dimensional cellular anode for lithium ion battery Jiang, Tao; Zhang, Shichao; Qiu, Xinping Journal of Power Sources, Vol. 166, Issue 2, p. 503-508 https://doi.org/10.1016/j.jpowsour.2007.01.017	journal	April 2007
Electrochemical performance of expanded mesocarbon microbeads as anode material for lithium-ion batteries Yang, Shubin; Song, Huaihe; Chen, Xiaohong Electrochemistry Communications, Vol. 8, Issue 1, p. 137-142 https://doi.org/10.1016/j.elecom.2005.10.035	journal	January 2006
Influence of ligand structure on the stability and oxidation of copper nanoparticles Kanninen, Petri; Johans, Christoffer; Merta, Juha Journal of Colloid and Interface Science, Vol. 318, Issue 1 https://doi.org/10.1016/j.jcis.2007.09.069	journal	February 2008
Poly(allylamine)-Stabilized Colloidal Copper Nanoparticles: Synthesis, Morphology, and Their Surface-Enhanced Raman Scattering Properties Wang, Yanfei; Asefa, Tewodros Langmuir, Vol. 26, Issue 10 https://doi.org/10.1021/la904199f	journal	May 2010
High-Rate, Long-Life Ni–Sn Nanostructured Electrodes for Lithium-Ion Batteries Hassoun, J.; Panero, S.; Simon, P. Advanced Materials, Vol. 19, Issue 12, p. 1632-1635 https://doi.org/10.1002/adma.200602035	journal	June 2007
An Approach to Make Macroporous Metal Sheets as Current Collectors for Lithium-Ion Batteries Xu, Wu; Canfield, Nathan L.; Wang, Deyu Journal of The Electrochemical Society, Vol. 157, Issue 7 https://doi.org/10.1149/1.3417076	journal	January 2010
Thermal and Electrical Conductivity of Porous Metals made by Powder Metallurgy Methods Grootenhuis, P.; Powell, R. W.; Tye, R. P. Proceedings of the Physical Society. Section B, Vol. 65, Issue 7 https://doi.org/10.1088/0370-1301/65/7/305	journal	July 1952
A comparative study of electrochemical properties of two kinds of carbon nanotubes as anode materials for lithium ion batteries Yang, Shubin; Huo, Junping; Song, Huaihe Electrochimica Acta, Vol. 53, Issue 5 https://doi.org/10.1016/j.electacta.2007.09.040	journal	January 2008
Copper Foam Structures with Highly Porous Nanostructured Walls Shin, Heon-Cheol; Liu, Meilin Chemistry of Materials, Vol. 16, Issue 25 https://doi.org/10.1021/cm048887b	journal	December 2004
Enhanced electrochemical performance of silicon-based anode material by using current collector with modified surface morphology Kim, Young-Lae; Sun, Yang-Kook; Lee, Sung-Man Electrochimica Acta, Vol. 53, Issue 13 https://doi.org/10.1016/j.electacta.2008.01.050	journal	May 2008
Electrodeposited 3D porous silicon/copper films with excellent stability and high rate performance for lithium-ion batteries Suk, Jungdon; Kim, Do Youb; Kim, Dong Wook Journal of Materials Chemistry A, Vol. 2, Issue 8 https://doi.org/10.1039/c3ta14645f	journal	January 2014
Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries Guo, Peng; Song, Huaihe; Chen, Xiaohong Electrochemistry Communications, Vol. 11, Issue 6, p. 1320-1324 https://doi.org/10.1016/j.elecom.2009.04.036	journal	June 2009
One-step electrodeposition synthesis and electrochemical properties of Cu6Sn5 alloy anodes for lithium-ion batteries Fan, Xiao-Yong; Zhuang, Quan-Chao; Wei, Guo-Zhen Journal of Applied Electrochemistry, Vol. 39, Issue 8 https://doi.org/10.1007/s10800-009-9802-9	journal	February 2009
Monolithic nanoporous copper by dealloying Mn–Cu Hayes, J. R.; Hodge, A. M.; Biener, J. Journal of Materials Research, Vol. 21, Issue 10 https://doi.org/10.1557/jmr.2006.0322	journal	October 2006
Formation and Characterization of Monolithic Nanoporous Copper by Chemical Dealloying of Al−Cu Alloys Qi, Zhen; Zhao, Changchun; Wang, Xiaoguang The Journal of Physical Chemistry C, Vol. 113, Issue 16 https://doi.org/10.1021/jp810742z	journal	March 2009
Self-Supported Formation of Needlelike Co3O4 Nanotubes and Their Application as Lithium-Ion Battery Electrodes Lou, X. W.; Deng, D.; Lee, J. Y. Advanced Materials, Vol. 20, Issue 2 https://doi.org/10.1002/adma.200702412	journal	January 2008
On the lithiation–delithiation of tin and tin-based intermetallic compounds on carbon paper current collector-substrate Arbizzani, C.; Beninati, S.; Lazzari, M. Journal of Power Sources, Vol. 158, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.06.042	journal	July 2006
Superhydrophobicity of 3D Porous Copper Films Prepared Using the Hydrogen Bubble Dynamic Template Li, Ying; Jia, Wen-Zhi; Song, Yan-Yan Chemistry of Materials, Vol. 19, Issue 23 https://doi.org/10.1021/cm071738j	journal	November 2007
High capacity and long cycle life silicon anode for Li-ion battery Takamura, Tsutomu; Uehara, Makiko; Suzuki, Junji Journal of Power Sources, Vol. 158, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.10.081	journal	August 2006
Non-aqueous Synthesis of Tin Oxide Nanocrystals and Their Assembly into Ordered Porous Mesostructures Ba, J.; Polleux, J.; Antonietti, M. Advanced Materials, Vol. 17, Issue 20, p. 2509-2512 https://doi.org/10.1002/adma.200501018	journal	October 2005
Three-Dimensional Porous Copper-Tin Alloy Electrodes for Rechargeable Lithium Batteries Shin, H.-C.; Liu, M. Advanced Functional Materials, Vol. 15, Issue 4, p. 582-586 https://doi.org/10.1002/adfm.200305165	journal	April 2005
Size-Monodisperse Metal Nanoparticles via Hydrogen-Free Spray Pyrolysis Kim, J. H.; Germer, T. A.; Mulholland, G. W. Advanced Materials, Vol. 14, Issue 7 https://doi.org/10.1002/1521-4095(20020404)14:7<518::AID-ADMA518>3.0.CO;2-P	journal	April 2002

Cited By (2)

Supramolecular ensemble of PBI derivative and copper nanoparticles: a light harvesting antenna for photocatalytic C(sp ² )–H functionalization Kaur, Sandeep; Kumar, Manoj; Bhalla, Vandana Green Chemistry, Vol. 18, Issue 21 https://doi.org/10.1039/c6gc01728b	journal	January 2016
Pressure compression of CdSe nanoparticles into luminescent nanowires Li, Binsong; Bian, Kaifu; Zhou, Xiaowang Science Advances, Vol. 3, Issue 5 https://doi.org/10.1126/sciadv.1602916	journal	May 2017

Similar Records

Research and analysis on electrochemical performances of α-Fe{sub 2}O{sub 3} electrode in Li-ion battery with different current collectors

Journal Article · Mon Jun 15 00:00:00 EDT 2015 · Materials Research Bulletin · OSTI ID:1370094

Huang, Lihong; Min, Zhonghua; Zhang, Qinyong

Nanostructures for Electrical Energy Storage (NEES) (2020 Final Technical Report)

Technical Report · Sun Nov 01 00:00:00 EDT 2020 · OSTI ID:1370094

Rubloff, Gary; Lee, Sangbok

Polymer-Stabilized Liquid Metal Nanoparticles as a Scalable Current Collector Engineering Approach Enabling Lithium Metal Anodes

Journal Article · Mon Mar 14 00:00:00 EDT 2022 · ACS Applied Energy Materials · OSTI ID:1370094

Liu, Tong; Wu, Xinsheng; Zhu, Shang; +9 more

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
copper nanoparticles
current collector
porous copper nanoparticle films
electro-deposition
three-dimensional electrodes
graphite
lithium ion batteries
metallic coatings

Title: Low-current field-assisted assembly of copper nanoparticles for current collectors

Citation Formats

References (81)

Cited By (2)

Similar Records

Related Subjects