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Title: Electrochemical and Raman spectroscopy identification of morphological and phase transformations in nanostructured TiO 2 (B)

Abstract

A systematic transformation of 2-D TiO 2(B) nanosheets into 3-D nanoparticles is studied using Raman and cyclic voltammetry to characterize changes in lithiation mechanism.

Authors:
 [1];  [1]
  1. Department of Chemistry; University of Texas at Austin; Austin, USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Understanding Charge Separation and Transfer at Interfaces in Energy Materials (CST)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1370047
DOE Contract Number:  
SC0001091
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 2; Journal Issue: 47; Related Information: CST partners with University of Texas at Austin (lead); Sandia National Laboratories; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Dylla, Anthony G., and Stevenson, Keith J. Electrochemical and Raman spectroscopy identification of morphological and phase transformations in nanostructured TiO 2 (B). United States: N. p., 2014. Web. doi:10.1039/c4ta04394d.
Dylla, Anthony G., & Stevenson, Keith J. Electrochemical and Raman spectroscopy identification of morphological and phase transformations in nanostructured TiO 2 (B). United States. doi:10.1039/c4ta04394d.
Dylla, Anthony G., and Stevenson, Keith J. Wed . "Electrochemical and Raman spectroscopy identification of morphological and phase transformations in nanostructured TiO 2 (B)". United States. doi:10.1039/c4ta04394d.
@article{osti_1370047,
title = {Electrochemical and Raman spectroscopy identification of morphological and phase transformations in nanostructured TiO 2 (B)},
author = {Dylla, Anthony G. and Stevenson, Keith J.},
abstractNote = {A systematic transformation of 2-D TiO2(B) nanosheets into 3-D nanoparticles is studied using Raman and cyclic voltammetry to characterize changes in lithiation mechanism.},
doi = {10.1039/c4ta04394d},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 47,
volume = 2,
place = {United States},
year = {2014},
month = {1}
}

Works referenced in this record:

Nanotubes with the TiO2-B structure
journal, January 2005

  • Armstrong, Graham; Armstrong, A. Robert; Canales, Jesús
  • Chemical Communications, Issue 19
  • DOI: 10.1039/b501883h

Ultrasmall Titania Nanocrystals and Their Direct Assembly into Mesoporous Structures Showing Fast Lithium Insertion
journal, September 2010

  • Szeifert, Johann M.; Feckl, Johann M.; Fattakhova-Rohlfing, Dina
  • Journal of the American Chemical Society, Vol. 132, Issue 36
  • DOI: 10.1021/ja101810e

Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000


Pushing Nanoionics to the Limits: Charge Carrier Chemistry in Extremely Small Systems
journal, September 2013


Large Impact of Particle Size on Insertion Reactions. A Case for Anatase Li x TiO 2
journal, April 2007

  • Wagemaker, Marnix; Borghols, Wouter J. H.; Mulder, Fokko M.
  • Journal of the American Chemical Society, Vol. 129, Issue 14
  • DOI: 10.1021/ja067733p

One-Step Synthesis of TiO 2 (B) Nanoparticles from a Water-Soluble Titanium Complex
journal, October 2007

  • Kobayashi, Makoto; Petrykin, Valery V.; Kakihana, Masato
  • Chemistry of Materials, Vol. 19, Issue 22
  • DOI: 10.1021/cm071370q

Electrochemical and gas-phase photocatalytic performance of nanostructured TiO2(B) prepared by novel synthetic route
journal, January 2005


Surfactant-Templated TiO 2 (Anatase):  Characteristic Features of Lithium Insertion Electrochemistry in Organized Nanostructures
journal, December 2000

  • Kavan, Ladislav; Rathouský, Jiří; Grätzel, Michael
  • The Journal of Physical Chemistry B, Vol. 104, Issue 50
  • DOI: 10.1021/jp003609v

Electrochemical charge storage of flowerlike rutile TiO2 nanorods
journal, April 2010


TiO2-B Nanowires
journal, April 2004

  • Armstrong, A. Robert; Armstrong, Graham; Canales, Jesús
  • Angewandte Chemie International Edition, Vol. 43, Issue 17, p. 2286-2288
  • DOI: 10.1002/anie.200353571

Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
journal, October 2007

  • Wang, John; Polleux, Julien; Lim, James
  • The Journal of Physical Chemistry C, Vol. 111, Issue 40, p. 14925-14931
  • DOI: 10.1021/jp074464w

Nanoparticulate TiO2(B): An Anode for Lithium-Ion Batteries
journal, January 2012

  • Ren, Yu; Liu, Zheng; Pourpoint, Frédérique
  • Angewandte Chemie International Edition, Vol. 51, Issue 9
  • DOI: 10.1002/anie.201108300

Two-Dimensional Nanoarchitectures for Lithium Storage
journal, April 2012


Large-scale synthesis of metastable TiO2(B) nanosheets with atomic thickness and their photocatalytic properties
journal, January 2010

  • Xiang, Guolei; Li, Tianyang; Zhuang, Jing
  • Chemical Communications, Vol. 46, Issue 36
  • DOI: 10.1039/c0cc02327b

Lithium Insertion into Anatase Nanotubes
journal, November 2012

  • Gentili, V.; Brutti, S.; Hardwick, L. J.
  • Chemistry of Materials, Vol. 24, Issue 22
  • DOI: 10.1021/cm302912f

Lithium-Ion Intercalation into TiO 2 -B Nanowires
journal, March 2005

  • Armstrong, A. R.; Armstrong, G.; Canales, J.
  • Advanced Materials, Vol. 17, Issue 7
  • DOI: 10.1002/adma.200400795

Lithium insertion in different TiO2 modifications
journal, September 1988


Pseudocapacitive Lithium Storage in TiO2(B)
journal, March 2005

  • Zukalová, Markéta; Kalbáč, Martin; Kavan, Ladislav
  • Chemistry of Materials, Vol. 17, Issue 5, p. 1248-1255
  • DOI: 10.1021/cm048249t

Morphological Dependence of Lithium Insertion in Nanocrystalline TiO 2 (B) Nanoparticles and Nanosheets
journal, July 2012

  • Dylla, Anthony G.; Xiao, Penghao; Henkelman, Graeme
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 15
  • DOI: 10.1021/jz300766a

TiO2(B) a new form of titanium dioxide and the potassium octatitanate K2Ti8O17
journal, August 1980


Transition from “Supercapacitor” to “Battery” Behavior in Electrochemical Energy Storage
journal, January 1991

  • Conway, B. E.
  • Journal of The Electrochemical Society, Vol. 138, Issue 6, p. 1539-1548
  • DOI: 10.1149/1.2085829

Mesoporous TiO2-B Microspheres with Superior Rate Performance for Lithium Ion Batteries
journal, July 2011

  • Liu, Hansan; Bi, Zhonghe; Sun, Xiao-Guang
  • Advanced Materials, Vol. 23, Issue 30, p. 3450-3454
  • DOI: 10.1002/adma.201100599

Li + Ion Insertion in TiO 2 (Anatase). 2. Voltammetry on Nanoporous Films
journal, September 1997

  • Lindström, Henrik; Södergren, Sven; Solbrand, Anita
  • The Journal of Physical Chemistry B, Vol. 101, Issue 39
  • DOI: 10.1021/jp970490q

Novel Synthesis of the TiO 2 (B) Multilayer Templated Films
journal, April 2009

  • Procházka, Jan; Kavan, Ladislav; Zukalová, Markéta
  • Chemistry of Materials, Vol. 21, Issue 8
  • DOI: 10.1021/cm801819q

High Lithium Electroactivity of Nanometer-Sized Rutile TiO2
journal, June 2006

  • Hu, Y.-S.; Kienle, L.; Guo, Y.-G.
  • Advanced Materials, Vol. 18, Issue 11, p. 1421-1426
  • DOI: 10.1002/adma.200502723