skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Rapid oxidative hydrogen evolution from a family of square-planar nickel hydride complexes

Abstract

One-electron oxidation in a family of square planar nickel hydride complexes leads to facile H 2evolution.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [2];  [1]; ORCiD logo [2]
  1. Department of Chemistry; Stanford University; Stanford, USA
  2. Department of Chemistry; University of Rochester; Rochester, USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Electrocatalysis, Transport Phenomena and Materials for Innovative Energy Storage (CETM)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1369918
DOE Contract Number:  
SC0001055
Resource Type:
Journal Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 1; Related Information: CETM partners with General Electric Global Research (lead); Lawrence Berkeley National Laboratory; Stanford University; Yale University; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Ramakrishnan, Srinivasan, Chakraborty, Sumit, Brennessel, William W., Chidsey, Christopher E. D., and Jones, William D. Rapid oxidative hydrogen evolution from a family of square-planar nickel hydride complexes. United States: N. p., 2016. Web. doi:10.1039/c5sc03189c.
Ramakrishnan, Srinivasan, Chakraborty, Sumit, Brennessel, William W., Chidsey, Christopher E. D., & Jones, William D. Rapid oxidative hydrogen evolution from a family of square-planar nickel hydride complexes. United States. doi:10.1039/c5sc03189c.
Ramakrishnan, Srinivasan, Chakraborty, Sumit, Brennessel, William W., Chidsey, Christopher E. D., and Jones, William D. Fri . "Rapid oxidative hydrogen evolution from a family of square-planar nickel hydride complexes". United States. doi:10.1039/c5sc03189c.
@article{osti_1369918,
title = {Rapid oxidative hydrogen evolution from a family of square-planar nickel hydride complexes},
author = {Ramakrishnan, Srinivasan and Chakraborty, Sumit and Brennessel, William W. and Chidsey, Christopher E. D. and Jones, William D.},
abstractNote = {One-electron oxidation in a family of square planar nickel hydride complexes leads to facile H2evolution.},
doi = {10.1039/c5sc03189c},
journal = {Chemical Science},
issn = {2041-6520},
number = 1,
volume = 7,
place = {United States},
year = {2016},
month = {1}
}

Works referenced in this record:

Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
journal, July 2008

  • Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
  • Organometallics, Vol. 27, Issue 13, p. 3082-3093
  • DOI: 10.1021/om701294a

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
journal, May 2009

  • Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396
  • DOI: 10.1021/jp810292n

Oxidative Addition of N−C and N−H Bonds to Zerovalent Nickel, Palladium, and Platinum
journal, November 2004

  • Ozerov, Oleg V.; Guo, Chengyun; Fan, Lei
  • Organometallics, Vol. 23, Issue 23, p. 5573-5580
  • DOI: 10.1021/om0493513

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965


Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993

  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
  • DOI: 10.1063/1.464913

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
journal, November 2006

  • Zhao, Yan; Truhlar, Donald G.
  • The Journal of Chemical Physics, Vol. 125, Issue 19, Article No. 194101
  • DOI: 10.1063/1.2370993

Inhomogeneous Electron Gas
journal, November 1964