skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Broadband antireflection and absorption enhancement of ultrathin silicon solar microcells enabled with density-graded surface nanostructures

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4881260· OSTI ID:1369862

Density-graded surface nanostructures are implemented on ultrathin silicon solar microcells by silver-nanoparticle-catalyzed wet chemical etching to enable near-zero surface reflection over a broad wavelength range of incident solar spectrum as well as non-zeroth order diffraction and light trapping for longer wavelength photons, thereby achieving augmented photon absorption for ultrathin silicon microcells in a simple, cost-effective manner. The increase of absorbed photon flux through the “black silicon (b-Si)” surface translates directly into the corresponding enhancement of photovoltaic performance, where 5.7-μm b-Si microcells with the rational design of device configuration exhibit improved energy conversion efficiency by 148% and 50% with and without a diffuse backside reflector, respectively, compared to devices from the bare silicon without b-Si implementation. Systematic studies on nanostructured morphology, optical and electrical properties of b-Si microcells, together with semi-empirical numerical modeling of photon absorption, provide key aspects of underlying materials science and physics.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Energy Nanoscience (CEN)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0001013
OSTI ID:
1369862
Journal Information:
Applied Physics Letters, Vol. 104, Issue 22; Related Information: CEN partners with University of Southern California (lead); University of Illinois, Urbana-Champaign; University of Michigan; University of Virginia; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 20 works
Citation information provided by
Web of Science

References (22)

Metal-Assisted Chemical Etching of Silicon: A Review journal September 2010
Oxidation Rate Effect on the Direction of Metal-Assisted Chemical and Electrochemical Etching of Silicon journal May 2010
A simple approximation for calculating impurity profiles for a two-step diffusion process journal January 1977
Ultrathin silicon solar microcells for semitransparent, mechanically flexible and microconcentrator module designs journal October 2008
Black silicon for solar cell applications conference June 2012
Nanophotonic light trapping in solar cells journal November 2012
Limiting efficiency of silicon solar cells journal May 1984
Black silicon layer formation for application in solar cells journal November 2006
Flexible concentrator photovoltaics based on microscale silicon solar cells embedded in luminescent waveguides journal June 2011
Performance of Ultrathin Silicon Solar Microcells with Nanostructures of Relief Formed by Soft Imprint Lithography for Broad Band Absorption Enhancement journal August 2010
Fabrication and assembly of ultrathin high-efficiency silicon solar microcells integrating electrical passivation and anti-reflection coatings journal January 2013
Efficient SERS substrates made by electroless silver deposition into patterned silicon structures journal January 2004
Metal assisted chemical etching for high aspect ratio nanostructures: A review of characteristics and applications in photovoltaics journal April 2012
Nanostructured black silicon and the optical reflectance of graded-density surfaces journal June 2009
Microstructuring of silicon with femtosecond laser pulses journal September 1998
Crystalline silicon solar module technology: Towards the 1 € per watt-peak goal journal May 2009
Fundamental limit of nanophotonic light trapping in solar cells journal September 2010
Efficient black silicon solar cell with a density-graded nanoporous surface: Optical properties, performance limitations, and design rules journal September 2009
Improved Black Silicon for Photovoltaic Applications journal April 2013
Compact monocrystalline silicon solar modules with high voltage outputs and mechanically flexible designs journal January 2010
An 18.2%-efficient black-silicon solar cell achieved through control of carrier recombination in nanostructures journal September 2012
Broadband moth-eye antireflection coatings on silicon journal February 2008

Cited By (7)

3D Graphite-Polymer Flexible Strain Sensors with Ultrasensitivity and Durability for Real-Time Human Vital Sign Monitoring and Musical Instrument Education journal April 2017
Printed assemblies of microscale triple‐junction inverted metamorphic GaInP/GaAs/InGaAs solar cells journal March 2019
Bio‐Inspired Plasmonic Photocatalysts journal December 2018
High performance III-V photoelectrodes for solar water splitting via synergistically tailored structure and stoichiometry journal July 2019
Black silicon: fabrication methods, properties and solar energy applications journal January 2014
Recent advances in antireflective surfaces based on nanostructure arrays journal January 2015
Effects of growth temperature and device structure on GaP solar cells grown by molecular beam epitaxy journal February 2015