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Title: Gel-assisted crystallization of [Ir 4 (IMe) 7 (CO)H 10 ] 2+ and [Ir 4 (IMe) 8 H 9 ] 3+ clusters derived from catalytic glycerol dehydrogenation

Abstract

Two unique Ir 4clusters isolated during catalytic glycerol dehydrogenation, crystallized using aqueous and organic gel matrices and displaying remarkable structural features are described.

Authors:
 [1];  [1];  [1];  [2];  [1]
  1. Yale University; New Haven, USA
  2. The Centre for Theoretical and Computational Chemistry (CTCC); Department of Chemistry, University of Oslo; N-0315 Oslo, Norway
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Catalytic Hydrocarbon Functionalization (CCHF)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1369718
DOE Contract Number:  
SC0001298
Resource Type:
Journal Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 44; Journal Issue: 42; Related Information: CCHF partners with University of Virginia (lead); Brigham Young University; California Institute of Technology; Colorado School of Mines; University of Maryland; University of North Carolina, Chapel Hill; University of North Texas; Princeton University; The Scripps Research Institute; Yale University; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Sharninghausen, Liam S., Mercado, Brandon Q., Crabtree, Robert H., Balcells, David, and Campos, Jesús. Gel-assisted crystallization of [Ir 4 (IMe) 7 (CO)H 10 ] 2+ and [Ir 4 (IMe) 8 H 9 ] 3+ clusters derived from catalytic glycerol dehydrogenation. United States: N. p., 2015. Web. doi:10.1039/c5dt03302k.
Sharninghausen, Liam S., Mercado, Brandon Q., Crabtree, Robert H., Balcells, David, & Campos, Jesús. Gel-assisted crystallization of [Ir 4 (IMe) 7 (CO)H 10 ] 2+ and [Ir 4 (IMe) 8 H 9 ] 3+ clusters derived from catalytic glycerol dehydrogenation. United States. doi:10.1039/c5dt03302k.
Sharninghausen, Liam S., Mercado, Brandon Q., Crabtree, Robert H., Balcells, David, and Campos, Jesús. Thu . "Gel-assisted crystallization of [Ir 4 (IMe) 7 (CO)H 10 ] 2+ and [Ir 4 (IMe) 8 H 9 ] 3+ clusters derived from catalytic glycerol dehydrogenation". United States. doi:10.1039/c5dt03302k.
@article{osti_1369718,
title = {Gel-assisted crystallization of [Ir 4 (IMe) 7 (CO)H 10 ] 2+ and [Ir 4 (IMe) 8 H 9 ] 3+ clusters derived from catalytic glycerol dehydrogenation},
author = {Sharninghausen, Liam S. and Mercado, Brandon Q. and Crabtree, Robert H. and Balcells, David and Campos, Jesús},
abstractNote = {Two unique Ir4clusters isolated during catalytic glycerol dehydrogenation, crystallized using aqueous and organic gel matrices and displaying remarkable structural features are described.},
doi = {10.1039/c5dt03302k},
journal = {Dalton Transactions},
issn = {1477-9226},
number = 42,
volume = 44,
place = {United States},
year = {2015},
month = {1}
}

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