Carbon Dioxide Promoted H+ Reduction Using a Bis(imino)pyridine Manganese Electrocatalyst

Mukhopadhyay, Tufan K.; MacLean, Nicholas L.; Gan, Lu; Ashley, Daniel C.; Groy, Thomas L.; Baik, Mu-Hyun; Jones, Anne K.; Trovitch, Ryan J.

doi:10.1021/acs.inorgchem.5b00315

Title: Carbon Dioxide Promoted H⁺ Reduction Using a Bis(imino)pyridine Manganese Electrocatalyst

Journal Article · Wed Apr 22 00:00:00 EDT 2015 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.5b00315· OSTI ID:1369649

Mukhopadhyay, Tufan K. ^[1]; MacLean, Nicholas L. ^[1]; Gan, Lu ^[1]; Ashley, Daniel C. ^[2]; Groy, Thomas L. ^[1]; Baik, Mu-Hyun ^[2]; Jones, Anne K. ^[1]; Trovitch, Ryan J. ^[1]

Arizona State Univ., Tempe, AZ (United States). Dept. of Chemistry and Biochemistry
Indiana Univ., Bloomington, IN (United States)

Heating a 1:1 mixture of (CO)₅MnBr and the phosphine-substituted pyridine diimine ligand, ^Ph2PPrPDI, in THF at 65 °C for 24 h afforded the diamagnetic complex [(^Ph2PPrPDI)Mn(CO)][Br] (1). Higher temperatures and longer reaction times resulted in bromide displacement of the remaining carbonyl ligand and the formation of paramagnetic (^Ph2PPrPDI)MnBr (2). The molecular structure of 1 was determined by single crystal X-ray diffraction, and density functional theory (DFT) calculations indicate that this complex is best described as low-spin Mn(I) bound to a neutral ^Ph2PPrPDI chelating ligand. The redox properties of 1 and 2 were investigated by cyclic voltammetry (CV), and each complex was tested for electrocatalytic activity in the presence of both CO₂ and Brønsted acids. Although electrocatalytic response was not observed when CO₂, H₂O, or MeOH was added to 1 individually, the addition of H2O or MeOH to CO_2-saturated acetonitrile solutions of 1 afforded voltammetric responses featuring increased current density as a function of proton source concentration ($$i$$_cat/$$i$$_p up to 2.4 for H₂O or 4.2 for MeOH at scan rates of 0.1 V/s). Bulk electrolysis using 5 mM 1 and 1.05 M MeOH in acetonitrile at -2.2 V vs Fc^+/0 over the course of 47 min gave H₂ as the only detectable product with a Faradaic efficiency of 96.7%. Electrochemical experiments indicate that CO₂ promotes 1-mediated H₂ production by lowering apparent pH. While evaluating 2 for electrocatalytic activity, this complex was found to decompose rapidly in the presence of acid. Although modest H⁺ reduction activity was realized, the experiments described herein indicate that care must be taken when evaluating Mn complexes for electrocatalytic CO₂ reduction.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Bio-Inspired Solar Fuel Production (BISfuel)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001016

OSTI ID:: 1369649

Journal Information:: Inorganic Chemistry, Vol. 54, Issue 9; Related Information: BISfuel partners with Arizona State University.; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 38 works

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