skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1369404
DOE Contract Number:  
SC0004993; Stanford University; AC02-76SF00515
Resource Type:
Journal Article
Journal Name:
Proceedings of the National Academy of Sciences of the United States of America
Additional Journal Information:
Journal Volume: 114; Journal Issue: 23; Journal ID: ISSN 0027-8424
Country of Publication:
United States
Language:
English

Citation Formats

Hahn, Christopher, Hatsukade, Toru, Kim, Youn-Geun, Vailionis, Arturas, Baricuatro, Jack H., Higgins, Drew C., Nitopi, Stephanie A., Soriaga, Manuel P., and Jaramillo, Thomas F. Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons. United States: N. p., 2017. Web. doi:10.1073/pnas.1618935114.
Hahn, Christopher, Hatsukade, Toru, Kim, Youn-Geun, Vailionis, Arturas, Baricuatro, Jack H., Higgins, Drew C., Nitopi, Stephanie A., Soriaga, Manuel P., & Jaramillo, Thomas F. Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons. United States. doi:10.1073/pnas.1618935114.
Hahn, Christopher, Hatsukade, Toru, Kim, Youn-Geun, Vailionis, Arturas, Baricuatro, Jack H., Higgins, Drew C., Nitopi, Stephanie A., Soriaga, Manuel P., and Jaramillo, Thomas F. Mon . "Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons". United States. doi:10.1073/pnas.1618935114.
@article{osti_1369404,
title = {Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons},
author = {Hahn, Christopher and Hatsukade, Toru and Kim, Youn-Geun and Vailionis, Arturas and Baricuatro, Jack H. and Higgins, Drew C. and Nitopi, Stephanie A. and Soriaga, Manuel P. and Jaramillo, Thomas F.},
abstractNote = {},
doi = {10.1073/pnas.1618935114},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
issn = {0027-8424},
number = 23,
volume = 114,
place = {United States},
year = {2017},
month = {5}
}

Works referenced in this record:

Anomalous moiré pattern of graphene investigated by scanning tunneling microscopy: Evidence of graphene growth on oxidized Cu(111)
journal, November 2013

  • Reckinger, Nicolas; Van Hooijdonk, Eloise; Joucken, Frédéric
  • Nano Research, Vol. 7, Issue 1
  • DOI: 10.1007/s12274-013-0382-y

Formation of copper silicides from Cu(100)/Si(100) and Cu(111)/Si(111) structures
journal, January 1990

  • Chang, Chin‐An
  • Journal of Applied Physics, Vol. 67, Issue 1
  • DOI: 10.1063/1.345194

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO 2 : New Theoretical Insights from an Improved Electrochemical Model
journal, April 2016

  • Goodpaster, Jason D.; Bell, Alexis T.; Head-Gordon, Martin
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 8
  • DOI: 10.1021/acs.jpclett.6b00358

Bond-Making and Breaking between Carbon, Nitrogen, and Oxygen in Electrocatalysis
journal, October 2014

  • Li, Hongjiao; Li, Yongdan; Koper, Marc T. M.
  • Journal of the American Chemical Society, Vol. 136, Issue 44
  • DOI: 10.1021/ja508649p

Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008


Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes
journal, June 2012

  • Schouten, Klaas Jan P.; Qin, Zisheng; Pérez Gallent, Elena
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja302668n

CO-CO coupling on Cu facets: Coverage, strain and field effects
journal, December 2016


Growth of Cu films on hydrogen terminated Si(100) and Si(111) surfaces
journal, February 1994

  • Demczyk, B. G.; Naik, R.; Auner, G.
  • Journal of Applied Physics, Vol. 75, Issue 4
  • DOI: 10.1063/1.356344

Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
journal, August 2014

  • Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R.
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja505791r

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

  • Ren, Dan; Deng, Yilin; Handoko, Albertus Denny
  • ACS Catalysis, Vol. 5, Issue 5
  • DOI: 10.1021/cs502128q

Surface reconstruction of pure-Cu single-crystal electrodes under CO-reduction potentials in alkaline solutions: A study by seriatim ECSTM-DEMS
journal, November 2016


The Evolution of the Polycrystalline Copper Surface, First to Cu(111) and Then to Cu(100), at a Fixed CO 2 RR Potential: A Study by Operando EC-STM
journal, December 2014

  • Kim, Youn-Geun; Baricuatro, Jack Hess; Javier, Alnald
  • Langmuir, Vol. 30, Issue 50
  • DOI: 10.1021/la504445g

A comparative technoeconomic analysis of renewable hydrogen production using solar energy
journal, January 2016

  • Shaner, Matthew R.; Atwater, Harry A.; Lewis, Nathan S.
  • Energy & Environmental Science, Vol. 9, Issue 7
  • DOI: 10.1039/C5EE02573G

Epitaxial growth of Cu (001) on Si (001): Mechanisms of orientation development and defect morphology
journal, November 1993

  • Hashim, I.; Park, B.; Atwater, H. A.
  • Applied Physics Letters, Vol. 63, Issue 20
  • DOI: 10.1063/1.110302

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
journal, September 2014

  • Manthiram, Karthish; Beberwyck, Brandon J.; Alivisatos, A. Paul
  • Journal of the American Chemical Society, Vol. 136, Issue 38
  • DOI: 10.1021/ja5065284

Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
journal, January 2012

  • Peterson, Andrew A.; Nørskov, Jens K.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 2
  • DOI: 10.1021/jz201461p

Epitaxial growth of Cu(111) films on Si(110) by magnetron sputtering: orientation and twin growth
journal, March 1998


Photochemical and Photoelectrochemical Reduction of CO 2
journal, May 2012


A new microfacet notation for high-Miller-index surfaces of cubic materials with terrace, step and kink structures
journal, February 1980


Solar Water Splitting Cells
journal, November 2010

  • Walter, Michael G.; Warren, Emily L.; McKone, James R.
  • Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
  • DOI: 10.1021/cr1002326

Effects of Deposition Conditions on Texture in Copper Thin Films on Si (111)
journal, January 1991

  • Knorr, D. B.; Lu, T. -M.
  • Textures and Microstructures, Vol. 13, Issue 2-3
  • DOI: 10.1155/TSM.13.155

Regulating the Product Distribution of CO Reduction by the Atomic-Level Structural Modification of the Cu Electrode Surface
journal, June 2016


New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes
journal, January 2011

  • Schouten, K. J. P.; Kwon, Y.; van der Ham, C. J. M.
  • Chemical Science, Vol. 2, Issue 10
  • DOI: 10.1039/c1sc00277e

Theoretical Insights into a CO Dimerization Mechanism in CO 2 Electroreduction
journal, May 2015

  • Montoya, Joseph H.; Shi, Chuan; Chan, Karen
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
  • DOI: 10.1021/acs.jpclett.5b00722

Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide
journal, September 2015

  • Kortlever, Ruud; Shen, Jing; Schouten, Klaas Jan P.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 20
  • DOI: 10.1021/acs.jpclett.5b01559

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

  • Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
  • Angewandte Chemie International Edition, Vol. 54, Issue 17
  • DOI: 10.1002/anie.201412214

Growth modes of epitaxial copper films on c-sapphire
journal, October 1994