Insights into the dual-electrode characteristics of layered Na0.5Ni0.25Mn0.75O2 materials for sodium-ion batteries

Manikandan, Palanisamy; Kim, Hyunwoo; Heo, Seongwoo; Lee, Eungje; Kim, Youngsik

doi:10.1021/acsami.6b15355

Title: Insights into the dual-electrode characteristics of layered Na_0.5Ni_0.25Mn_0.75O₂ materials for sodium-ion batteries

Journal Article · Thu Mar 09 00:00:00 EST 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.6b15355· OSTI ID:1369041

Manikandan, Palanisamy; Kim, Hyunwoo; Heo, Seongwoo; Lee, Eungje; Kim, Youngsik

Sodium-ion batteries are now close to replacing lithium-ion batteries because they provide superior alternative energy storage solutions that are in great demand, particularly for large-scale applications. To that end, the present study is focused on the properties of a new type of dual-electrode material, Na_0.5Ni_0.25Mn_0.75O₂, synthesized using a mixed hydroxycarbonate route. Cyclic voltammetry confirms that redox couples, at high and low voltage ranges, are facilitated by the unique features and properties of this dual-electrode, through sodium ion deintercalation/intercalation into the layered Na_0.5Ni_0.25Mn_0.25O₂ material. This material provides superior performance for Na-ion batteries, as evidenced by the fabricated sodium cell that yielded initial charge discharge capacities of 125/218 mAh g^-1 in the voltage range of 1.5-4.4 V at 0.5 C. At a low voltage range (1.5-2.6 V), the anode cell delivered discharge charge capacities of 100/99 mAh g^-1 with 99% capacity retention, which corresponds to highly reversible redox reaction of the Mn^4+/3+ reduction and the Mn^3+/4+ oxidation observed at 1.85 and 2.06 V, respectively. The symmetric Na-ion cell, fabricated using Na_0.5Ni_0.25Mn_0.25O₂, yielded initial charge discharge capacities of 196/187 μAh at 107 μA. Lastly, these results encourage the further development of new types of futuristic sodium-ion battery-based energy storage systems.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: Ulsan National Institute of Science and Technology (UNIST); National Research Foundation of Korea (NRF); Argonne National Laboratory, Laboratory Directed Research and Development (LDRD); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1369041

Journal Information:: ACS Applied Materials and Interfaces, Vol. 9, Issue 12; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 31 works

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36 MATERIALS SCIENCE
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Chargedischarge cycling
Dual electrode
Layered P2-type structure
Mixed hydroxy-carbonate
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Title: Insights into the dual-electrode characteristics of layered Na0.5Ni0.25Mn0.75O2 materials for sodium-ion batteries

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Title: Insights into the dual-electrode characteristics of layered Na_0.5Ni_0.25Mn_0.75O₂ materials for sodium-ion batteries