Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]

Ma, Tianyuan; Xu, Gui -Liang; Zeng, Xiaoqiao; Li, Yan; Ren, Yang; Sun, Chengjun; Heald, Steve M.; Jorne, Jacob; Amine, Khalil; Chen, Zonghai

doi:10.1016/j.jpowsour.2016.11.022

Title: Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]

Journal Article · Wed Dec 07 00:00:00 EST 2016 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2016.11.022· OSTI ID:1369033

Ma, Tianyuan ^[1]; Xu, Gui -Liang ^[2]; Zeng, Xiaoqiao ^[2]; Li, Yan ^[2]; Ren, Yang ^[2]; Sun, Chengjun ^[2]; Heald, Steve M. ^[2]; Jorne, Jacob ^[3]; Amine, Khalil ^[2]; Chen, Zonghai ^[2]

Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Rochester, Rochester, NY (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Rochester, Rochester, NY (United States)

In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the soild state synthesis of Na_xMnO₂, with particular interest on the synthesis of P2 type Na_2/3MnO₂. It was found that there were multi intermediate phases formed before NaMnO₂ appeared at about 600 °C. And the final product after cooling process is a combination of O'3 NaMnO₂ with P2 Na_2/3MnO₂. A P2 type Na_2/3MnO₂ was synthesized at reduced temperature (600 °C). The influence of Na₂CO₃ impurity on the electrochemical performance of P2 Na_2/3MnO₂ was thoroughly investigated in our work. It was found that the content of Na₂CO₃ can be reduced by optimizing Na₂CO₃/MnCO₃ ratio during the solid state reaction or other post treatment such as washing with water. Lastly, we expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1369033

Alternate ID(s):: OSTI ID: 1397470

Journal Information:: Journal of Power Sources, Vol. 341, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 21 works

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Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries Xu, Gui-Liang; Amine, Rachid; Abouimrane, Ali Advanced Energy Materials, Vol. 8, Issue 14 https://doi.org/10.1002/aenm.201702403	journal	February 2018
Excellent cyclability of P2-type Na–Co–Mn–Si–O cathode material for high-rate sodium-ion batteries Wang, Lijun; Wang, Yanzhi; Yang, Xiaheng Journal of Materials Science, Vol. 54, Issue 19 https://doi.org/10.1007/s10853-019-03807-y	journal	July 2019
A Novel Graphene Oxide Wrapped Na ₂ Fe ₂ (SO ₄ ) ₃ /C Cathode Composite for Long Life and High Energy Density Sodium-Ion Batteries Chen, Mingzhe; Cortie, David; Hu, Zhe Advanced Energy Materials, Vol. 8, Issue 27 https://doi.org/10.1002/aenm.201800944	journal	August 2018
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures Wang, Shenghan; Sun, Chenglin; Wang, Ning Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c8ta12441h	journal	January 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
25 ENERGY STORAGE
in situ XANES
P2 type Na2/3MnO2
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ion battery
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Title: Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]

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