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Title: Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell

Abstract

ABSTRACT In this study, we conducted the first energy dispersive x-ray diffraction (EDXRD) experiments on Li/Li 1.1V 3O 8coin cells discharged to different lithiation levels in order to investigate the phase transitions upon electrochemical reduction. The phase transformation from layered Li-poor α to Li-rich α to defect rock-salt β phase was confirmed with cells of different lithiation stages. No spatial localization of phase formation was observed throughout the cathodes under the conditions of this measurement.

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1368317
Resource Type:
Journal Article
Resource Relation:
Journal Name: MRS Advances; Journal Volume: 2; Journal Issue: 07
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Zhang, Qing, Bruck, Andrea M., Bock, David C., Li, Jing, Stach, Eric A., Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C. Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell. United States: N. p., 2017. Web. doi:10.1557/adv.2017.54.
Zhang, Qing, Bruck, Andrea M., Bock, David C., Li, Jing, Stach, Eric A., Takeuchi, Esther S., Takeuchi, Kenneth J., & Marschilok, Amy C. Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell. United States. doi:10.1557/adv.2017.54.
Zhang, Qing, Bruck, Andrea M., Bock, David C., Li, Jing, Stach, Eric A., Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C. 2017. "Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell". United States. doi:10.1557/adv.2017.54.
@article{osti_1368317,
title = {Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell},
author = {Zhang, Qing and Bruck, Andrea M. and Bock, David C. and Li, Jing and Stach, Eric A. and Takeuchi, Esther S. and Takeuchi, Kenneth J. and Marschilok, Amy C.},
abstractNote = {ABSTRACT In this study, we conducted the first energy dispersive x-ray diffraction (EDXRD) experiments on Li/Li1.1V3O8coin cells discharged to different lithiation levels in order to investigate the phase transitions upon electrochemical reduction. The phase transformation from layered Li-poor α to Li-rich α to defect rock-salt β phase was confirmed with cells of different lithiation stages. No spatial localization of phase formation was observed throughout the cathodes under the conditions of this measurement.},
doi = {10.1557/adv.2017.54},
journal = {MRS Advances},
number = 07,
volume = 2,
place = {United States},
year = 2017,
month = 1
}