Greener process to synthesize water-soluble Mn.sup.2+-doped CdSSe(ZnS) core(shell) nanocrystals for ratiometric temperature sensing, nanocrystals, and methods implementing nanocrystals

Yang, Haw; Hsia, Chih-Hao

Greener process to synthesize water-soluble Mn.sup.2+-doped CdSSe(ZnS) core(shell) nanocrystals for ratiometric temperature sensing, nanocrystals, and methods implementing nanocrystals

Patent · 04 July 2017

OSTI ID:1368199

Yang, Haw; Hsia, Chih-Hao

Novel Mn.sup.2+-doped quantum dots are provided. These Mn.sup.2+-doped quantum dots exhibit excellent temperature sensitivity in both organic solvents and water-based solutions. Methods of preparing the Mn.sup.2+-doped quantum dots are provided. The Mn.sup.2+-doped quantum dots may be prepared via a stepwise procedure using air-stable and inexpensive chemicals. The use of air-stable chemicals can significantly reduce the cost of synthesis, chemical storage, and the risk associated with handling flammable chemicals. Methods of temperature sensing using Mn.sup.2+-doped quantum dots are provided. The stepwise procedure provides the ability to tune the temperature-sensing properties to satisfy specific needs for temperature sensing applications. Water solubility may be achieved by passivating the Mn.sup.2+-doped quantum dots, allowing the Mn.sup.2+-doped quantum dots to probe the fluctuations of local temperature in biological environments.

View Patent

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-05CH11231

Assignee:: The Trustees of Princeton University

Patent Number(s):: 9,696,317

Application Number:: 14/352,610

OSTI ID:: 1368199

Country of Publication:: United States

Language:: English

References (28)

Fluorescence intensity ratio technique for optical fiber point temperature sensing Wade, S. A.; Collins, S. F.; Baxter, G. W. Journal of Applied Physics, Vol. 94, Issue 8 https://doi.org/10.1063/1.1606526	journal	January 2003
An Accessible Approach to Preparing Water-Soluble Mn²⁺-Doped (CdSSe)ZnS (Core)Shell Nanocrystals for Ratiometric Temperature Sensing Hsia, Chih-Hao; Wuttig, Anna; Yang, Haw ACS Nano, Vol. 5, Issue 12, p. 9511-9522 https://doi.org/10.1021/nn2025622	journal	November 2011
CdSe Quantum Dots for Two-Photon Fluorescence Thermal Imaging Maestro, Laura Martinez; Rodríguez, Emma Martín; Rodríguez, Francisco Sanz Nano Letters, Vol. 10, Issue 12, p. 5109-5115 https://doi.org/10.1021/nl1036098	journal	December 2010
Optical-fiber temperature sensor based on upconversion-excited fluorescence Berthou, H.; Jörgensen, C. K. Optics Letters, Vol. 15, Issue 19 https://doi.org/10.1364/OL.15.001100	journal	January 1990
Alloyed Semiconductor Quantum Dots: Tuning the Optical Properties without Changing the Particle Size Bailey, Robert E.; Nie, Shuming Journal of the American Chemical Society, Vol. 125, Issue 23, p. 7100-7106 https://doi.org/10.1021/ja035000o	journal	June 2003
Formation of High-Quality CdTe, CdSe, and CdS Nanocrystals Using CdO as Precursor Peng, Z. Adam; Peng, Xiaogang Journal of the American Chemical Society, Vol. 123, Issue 1, p. 183-184 https://doi.org/10.1021/ja003633m	journal	January 2001
Ratiometric Temperature Sensing with Semiconducting Polymer Dots Ye, Fangmao; Wu, Changfeng; Jin, Yuhui Journal of the American Chemical Society, Vol. 133, Issue 21, p. 8146-8149 https://doi.org/10.1021/ja202945g	journal	June 2011
Thermogenesis detection of single living cells via quantum dots Yang, Jui-Ming; Yang, Haw; Lin, Liwei 2010 IEEE 23rd International Conference on Micro Electro Mechanical Systems (MEMS) https://doi.org/10.1109/MEMSYS.2010.5442368	conference	January 2010
On Doping CdS/ZnS Core/Shell Nanocrystals with Mn Yang, Yongan; Chen, Ou; Angerhofer, Alexander Journal of the American Chemical Society, Vol. 130, Issue 46, p. 15649-15661 https://doi.org/10.1021/ja805736k	journal	November 2008
Composition-Tunable Zn_xCd₁_-_xSe Nanocrystals with High Luminescence and Stability Zhong, Xinhua; Han, Mingyong; Dong, Zhili Journal of the American Chemical Society, Vol. 125, Issue 28, p. 8589-8594 https://doi.org/10.1021/ja035096m	journal	July 2003
Noninjection Synthesis of CdS and Alloyed CdS_xSe_1−x Nanocrystals Without Nucleation Initiators Zou, Yu; Li, Dongsheng; Yang, Deren Nanoscale Research Letters, Vol. 5, Issue 6, p. 966-971 https://doi.org/10.1007/s11671-010-9593-2	journal	April 2010
Measurement of Energy Transfer Time in Colloidal Mn-Doped Semiconductor Nanocrystals Chen, Hsiang-Yun; Chen, Tai-Yen; Son, Dong Hee The Journal of Physical Chemistry C, Vol. 114, Issue 10, p. 4418-4423 https://doi.org/10.1021/jp100352m	journal	March 2010
Large-Scale Synthesis of Nearly Monodisperse CdSe/CdS Core/Shell Nanocrystals Using Air-Stable Reagents via Successive Ion Layer Adsorption and Reaction Li, J. Jack; Wang, Y. Andrew; Guo, Wenzhuo Journal of the American Chemical Society, Vol. 125, Issue 41, p. 12567-12575 https://doi.org/10.1021/ja0363563	journal	October 2003
Noninjection, One-Pot Synthesis of Photoluminescent Colloidal Homogeneously Alloyed CdSeS Quantum Dots Ouyang, Jianying; Vincent, Maxime; Kingston, David The Journal of Physical Chemistry C, Vol. 113, Issue 13, p. 5193-5200 https://doi.org/10.1021/jp8110138	journal	March 2009
Quantum dot bioconjugates for imaging, labelling and sensing Medintz, Igor L.; Uyeda, H. Tetsuo; Goldman, Ellen R. Nature Materials, Vol. 4, Issue 6, p. 435-446 https://doi.org/10.1038/nmat1390	journal	June 2005
Quantum Dot Nano Thermometers Reveal Heterogeneous Local Thermogenesis in Living Cells Yang, Jui-Ming; Yang, Haw; Lin, Liwei ACS Nano, Vol. 5, Issue 6, p. 5067-5071 https://doi.org/10.1021/nn201142f	journal	May 2011
Radial-Position-Controlled Doping in CdS/ZnS Core/Shell Nanocrystals Yang, Yongan; Chen, Ou; Angerhofer, Alexander Journal of the American Chemical Society, Vol. 128, Issue 38, p. 12428-12429 https://doi.org/10.1021/ja064818h	journal	September 2006
Mysteries of TOPSe Revealed: Insights into Quantum Dot Nucleation Evans, Christopher M.; Evans, Meagan E.; Krauss, Todd D. Journal of the American Chemical Society, Vol. 132, Issue 32, p. 10973-10975 https://doi.org/10.1021/ja103805s	journal	August 2010
Multifunctional Compact Zwitterionic Ligands for Preparing Robust Biocompatible Semiconductor Quantum Dots and Gold Nanoparticles Susumu, Kimihiro; Oh, Eunkeu; Delehanty, James B. Journal of the American Chemical Society, Vol. 133, Issue 24, p. 9480-9496 https://doi.org/10.1021/ja201919s	journal	June 2011
Quantum-dot-tagged microbeads for multiplexed optical coding of biomolecules Han, Mingyong; Gao, Xiaohu; Su, Jack Z. Nature Biotechnology, Vol. 19, Issue 7, p. 631-635 https://doi.org/10.1038/90228	journal	July 2001
Chiral highly luminescent CdS quantum dots Moloney, Mícheál P.; Gun'ko, Yurii K.; Kelly, John M. Chemical Communications, Vol. 0, Issue 38, p. 3900-3902 https://doi.org/10.1039/B704636G	journal	January 2007
Zwitterionic Biocompatible Quantum Dots for Wide pH Stability and Weak Nonspecific Binding to Cells Breus, Vladimir V.; Heyes, Colin D.; Tron, Kyrylo ACS Nano, Vol. 3, Issue 9, p. 2573-2580 https://doi.org/10.1021/nn900600w	journal	August 2009
Phosphine-Free Synthesis of CdSe Nanocrystals Jasieniak, Jacek; Bullen, Craig; van Embden, Joel The Journal of Physical Chemistry B, Vol. 109, Issue 44, p. 20665-20668 https://doi.org/10.1021/jp054289o	journal	November 2005
Mn 2 + as a Radial Pressure Gauge in Colloidal Core/Shell Nanocrystals Ithurria, Sandrine; Guyot-Sionnest, Philippe; Mahler, Benoit Physical Review Letters, Vol. 99, Issue 26 https://doi.org/10.1103/PhysRevLett.99.265501	journal	December 2007
High quality CdSeS nanocrystals synthesized by facile single injection process and their electroluminescence Jang, Eunjoo; Jun, Shinae; Pu, Lyongsun Chemical Communications, Vol. 0, Issue 24, p. 2964-2965 https://doi.org/10.1039/B310853H	journal	January 2003
Crystal field, phonon coupling and emission shift of Mn2+ in ZnS:Mn nanoparticles Chen, Wei; Sammynaiken, Ramaswami; Huang, Yining Journal of Applied Physics, Vol. 89, Issue 2 https://doi.org/10.1063/1.1332795	journal	January 2001
Tunable Dual Emission in Doped Semiconductor Nanocrystals Vlaskin, Vladimir A.; Janssen, Nils; van Rijssel, Jos Nano Letters, Vol. 10, Issue 9, p. 3670-3674 https://doi.org/10.1021/nl102135k	journal	September 2010
Quantum Dots and Their Multimodal Applications: A Review Bera, Debasis; Qian, Lei; Tseng, Teng-Kuan Materials, Vol. 3, Issue 4 https://doi.org/10.3390/ma3042260	journal	March 2010

Similar Records

An accessible approach to preparing water-soluble Mn²⁺-doped (CdSSe)ZnS (core)shell nanocrystals for ratiometric temperature sensing

Journal Article · 2011 · ACS Nano · OSTI ID:1324582

Room temperature biosynthesis of greatly stable fluorescent ZnO quantum dots for the selective detection of Cr{sup 3+} ions

Journal Article · 2017 · Materials Research Bulletin · OSTI ID:22730445

Color stable manganese-doped phosphors

Patent · 2012 · OSTI ID:1058909

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Greener process to synthesize water-soluble Mn.sup.2+-doped CdSSe(ZnS) core(shell) nanocrystals for ratiometric temperature sensing, nanocrystals, and methods implementing nanocrystals

Citation Formats

References (28)

Similar Records

Related Subjects