Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes

Phillips, Mark C.; Brumfield, Brian E.; LaHaye, Nicole; Harilal, Sivanandan S.; Hartig, Kyle C.; Jovanovic, Igor

doi:10.1038/s41598-017-03865-9

Title: Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes

Journal Article · Mon Jun 19 00:00:00 EDT 2017 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-017-03865-9· OSTI ID:1367672

Phillips, Mark C. ^[1]; Brumfield, Brian E. ^[1]; LaHaye, Nicole ^[1]; Harilal, Sivanandan S. ^[1]; Hartig, Kyle C. ^[2]; Jovanovic, Igor ^[3]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering
Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Nuclear Engineering and Radiological Sciences

Here, we demonstrate measurement of uranium isotopes in femtosecond laser ablation plumes using two-dimensional fluorescence spectroscopy (2DFS). The high-resolution, tunable CW-laser spectroscopy technique clearly distinguishes atomic absorption from ²³⁵U and ²³⁸U in natural and highly enriched uranium metal samples. We present analysis of spectral resolution and analytical performance of 2DFS as a function of ambient pressure. Simultaneous measurement using time-resolved absorption spectroscopy provides information on temporal dynamics of the laser ablation plume and saturation behavior of fluorescence signals. The rapid, non-contact measurement is promising for in-field, standoff measurements of uranium enrichment for nuclear safety and security.

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Research Organization:: Univ. of Michigan, Ann Arbor, MI (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); US Department of Homeland Security (DHS)

Grant/Contract Number:: NA0002534; AC05-76RL01830

OSTI ID:: 1367672

Journal Information:: Scientific Reports, Vol. 7, Issue 1; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 45 works

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Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L. Applied Physics Reviews, Vol. 5, Issue 2 https://doi.org/10.1063/1.5016053	journal	June 2018
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Dual-Comb Spectroscopy of Laser-Induced Plasmas Bergevin, Jenna; Wu, Tsung-Han; Yeak, Jeremy CLEO: Science and Innovations, Conference on Lasers and Electro-Optics https://doi.org/10.1364/cleo_si.2017.sw1l.2	conference	January 2017
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