A high performance lithium–sulfur battery enabled by a fish-scale porous carbon/sulfur composite and symmetric fluorinated diethoxyethane electrolyte

Gao, Mengyao; Su, ChiCheung; He, Meinan; Glossmann, Tobias; Hintennach, Andreas; Feng, Zhenxing; Huang, Yaqin; Zhang, Zhengcheng

doi:10.1039/C7TA01057E

Title: A high performance lithium–sulfur battery enabled by a fish-scale porous carbon/sulfur composite and symmetric fluorinated diethoxyethane electrolyte

Journal Article · Tue Mar 07 00:00:00 EST 2017 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C7TA01057E· OSTI ID:1367284

Gao, Mengyao ^[1]; Su, ChiCheung ^[2]; He, Meinan ^[2];

^[3]; Hintennach, Andreas ^[4];

^[5];

^[6];

^[2]

Argonne National Lab. (ANL), Argonne, IL (United States); Beijing Univ. of Chemical Technology, Beijing (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Mercedes-Benz Research & Development North America, Inc., Redford, MI (United States)
Daimler AG (Mercedes-Benz Cars), Boeblingen (Germany)
Oregon State Univ., Corvallis, OR (United States)
Beijing Univ. of Chemical Technology, Beijing (China)

A high performance lithium–sulfur (Li–S) battery comprising a symmetric fluorinated diethoxyethane electrolyte coupled with a fish-scale porous carbon/S composite electrode was demonstrated. 1,2-Bis(1,1,2,2-tetrafluoroethoxy)ethane (TFEE) was first studied as a new electrolyte solvent for Li–S chemistry. When co-mixed with 1,3-dioxolane (DOL), the DOL/TFEE electrolyte suppressed the polysulfide dissolution and shuttling reaction. Lastly, when coupled with a fish-scale porous carbon/S composite electrode, the Li–S cell exhibited a significantly high capacity retention of 99.5% per cycle for 100 cycles, which is far superior to the reported numerous systems.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: Daimler AG - Mercedes-Benz; Beijing University of Chemical Technology (BUCT); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1367284

Journal Information:: Journal of Materials Chemistry. A, Vol. 5, Issue 14; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 28 works

Citation information provided by
Web of Science

References (45)

Electrochemical performance of lithium/sulfur batteries with protected Li anodes Lee, Yong Min; Choi, Nam-Soon; Park, Jung Hwa Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00300-8	journal	June 2003
Application of Partially Fluorinated Ether for Improving Performance of Lithium/Sulfur Batteries Lu, Hai; Yuan, Yan; Zhang, Kai Journal of The Electrochemical Society, Vol. 162, Issue 8 https://doi.org/10.1149/2.0281508jes	journal	January 2015
Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability Wang, Hailiang; Yang, Yuan; Liang, Yongye Nano Letters, Vol. 11, Issue 7, p. 2644-2647 https://doi.org/10.1021/nl200658a	journal	July 2011
Electrochemical Performance of All-Solid-State Li/S Batteries with Sulfur-Based Composite Electrodes Prepared by Mechanical Milling at High Temperature Nagao, Motohiro; Hayashi, Akitoshi; Tatsumisago, Masahiro Energy Technology, Vol. 1, Issue 2-3 https://doi.org/10.1002/ente.201200019	journal	March 2013
Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification Barchasz, Céline; Molton, Florian; Duboc, Carole Analytical Chemistry, Vol. 84, Issue 9 https://doi.org/10.1021/ac2032244	journal	April 2012
Electrochemical reactions of lithium–sulfur batteries: an analytical study using the organic conversion technique Kawase, Ayako; Shirai, Soichi; Yamoto, Yoshinari Phys. Chem. Chem. Phys., Vol. 16, Issue 20 https://doi.org/10.1039/C4CP00958D	journal	January 2014
Understanding the Effect of a Fluorinated Ether on the Performance of Lithium–Sulfur Batteries Azimi, Nasim; Xue, Zheng; Bloom, Ira ACS Applied Materials & Interfaces, Vol. 7, Issue 17 https://doi.org/10.1021/acsami.5b01412	journal	April 2015
Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries Lin, Zhan; Liu, Zengcai; Fu, Wujun Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200696	journal	June 2012
In-situ X-ray diffraction studies of lithium–sulfur batteries Cañas, Natalia A.; Wolf, Steffen; Wagner, Norbert Journal of Power Sources, Vol. 226 https://doi.org/10.1016/j.jpowsour.2012.10.092	journal	March 2013
New insight into liquid electrolyte of rechargeable lithium/sulfur battery Zhang, Sheng S. Electrochimica Acta, Vol. 97 https://doi.org/10.1016/j.electacta.2013.02.122	journal	May 2013
Porous carbon derived from rice husks as sustainable bioresources: insights into the role of micro-/mesoporous hierarchy in hosting active species for lithium–sulphur batteries Rybarczyk, Maria K.; Peng, Hong-Jie; Tang, Cheng Green Chemistry, Vol. 18, Issue 19 https://doi.org/10.1039/C6GC00612D	journal	January 2016
Mechanistic modeling of polysulfide shuttle and capacity loss in lithium–sulfur batteries Hofmann, Andreas F.; Fronczek, David N.; Bessler, Wolfgang G. Journal of Power Sources, Vol. 259 https://doi.org/10.1016/j.jpowsour.2014.02.082	journal	August 2014
Electrochemical performance of lithium/sulfur cells with three different polymer electrolytes Marmorstein, D.; Yu, T. H.; Striebel, K. A. Journal of Power Sources, Vol. 89, Issue 2 https://doi.org/10.1016/S0378-7753(00)00432-8	journal	August 2000
Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries Cuisinier, M.; Cabelguen, P. -E.; Adams, B. D. Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00372A	journal	January 2014
Pig bone derived hierarchical porous carbon and its enhanced cycling performance of lithium–sulfur batteries Wei, Shaochen; Zhang, Hao; Huang, Yaqin Energy & Environmental Science, Vol. 4, Issue 3 https://doi.org/10.1039/c0ee00505c	journal	January 2011
Improved dischargeability and reversibility of sulfur cathode in a novel ionic liquid electrolyte Yuan, L. X.; Feng, J. K.; Ai, X. P. Electrochemistry Communications, Vol. 8, Issue 4, p. 610-614 https://doi.org/10.1016/j.elecom.2006.02.007	journal	April 2006
Solvate Ionic Liquid Electrolyte for Li–S Batteries Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.111308jes	journal	January 2013
Raman Spectroscopic and X-ray Diffraction Studies of Sulfur Composite Electrodes during Discharge and Charge Yeon, Jin-Tak; Jang, Jun-Young; Han, Jung-Gu Journal of The Electrochemical Society, Vol. 159, Issue 8 https://doi.org/10.1149/2.080208jes	journal	January 2012
Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries Li, Guoxing; Sun, Jinhua; Hou, Wenpeng Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10601	journal	February 2016
Improved performance of lithium–sulfur battery with fluorinated electrolyte Azimi, Nasim; Weng, Wei; Takoudis, Christos Electrochemistry Communications, Vol. 37 https://doi.org/10.1016/j.elecom.2013.10.020	journal	December 2013
Inhibition on polysulfides dissolve during the discharge-charge by using fish-scale-based porous carbon for lithium-sulfur battery Gao, Mengyao; Li, Chengming; Liu, Naiqiang Electrochimica Acta, Vol. 149 https://doi.org/10.1016/j.electacta.2014.10.118	journal	December 2014
Ion Transport Properties of Six Lithium Salts Dissolved in γ-Butyrolactone Studied by Self-Diffusion and Ionic Conductivity Measurements Aihara, Yuichi; Bando, Toshinori; Nakagawa, Hiroe Journal of The Electrochemical Society, Vol. 151, Issue 1 https://doi.org/10.1149/1.1630592	journal	January 2004
In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries Nelson, Johanna; Misra, Sumohan; Yang, Yuan Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja2121926	journal	March 2012
Improved lithium–sulfur cells with a treated carbon paper interlayer Zu, Chenxi; Su, Yu-Sheng; Fu, Yongzhu Physical Chemistry Chemical Physics, Vol. 15, Issue 7 https://doi.org/10.1039/c2cp43394j	journal	January 2013
New Approaches for High Energy Density Lithium–Sulfur Battery Cathodes Evers, Scott; Nazar, Linda F. Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar3001348	journal	June 2012
Discharge behavior of lithium/sulfur cell with TEGDME based electrolyte at low temperature Ryu, Ho-Suk; Ahn, Hyo-Jun; Kim, Ki-Won Journal of Power Sources, Vol. 163, Issue 1, p. 201-206 https://doi.org/10.1016/j.jpowsour.2005.12.061	journal	December 2006
N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide-based organic electrolyte for high performance lithium–sulfur batteries Wang, Lina; Byon, Hye Ryung Journal of Power Sources, Vol. 236 https://doi.org/10.1016/j.jpowsour.2013.02.068	journal	August 2013
A new direction for the performance improvement of rechargeable lithium/sulfur batteries Zhang, Sheng S.; Read, Jeffrey A. Journal of Power Sources, Vol. 200 https://doi.org/10.1016/j.jpowsour.2011.10.076	journal	February 2012
Lithium-air and lithium-sulfur batteries Bruce, Peter G.; Hardwick, Laurence J.; Abraham, K. M. MRS Bulletin, Vol. 36, Issue 7 https://doi.org/10.1557/mrs.2011.157	journal	July 2011
Lithium-ion batteries. A look into the future Scrosati, Bruno; Hassoun, Jusef; Sun, Yang-Kook Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01388b	journal	January 2011
Recent advances in lithium–sulfur batteries Chen, Lin; Shaw, Leon L. Journal of Power Sources, Vol. 267 https://doi.org/10.1016/j.jpowsour.2014.05.111	journal	December 2014
Lithium phosphorous oxynitride as a passive layer for anodes in lithium secondary batteries Chung, Kwang-il; Kim, Woo-Seong; Choi, Yong-Kook Journal of Electroanalytical Chemistry, Vol. 566, Issue 2 https://doi.org/10.1016/j.jelechem.2003.11.035	journal	May 2004
Advances in Li–S batteries Ji, Xiulei; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826 https://doi.org/10.1039/b925751a	journal	January 2010
Lithium batteries: Status, prospects and future Scrosati, Bruno; Garche, Jürgen Journal of Power Sources, Vol. 195, Issue 9 https://doi.org/10.1016/j.jpowsour.2009.11.048	journal	May 2010
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions Zhang, Sheng S. Journal of Power Sources, Vol. 231, p. 153-162 https://doi.org/10.1016/j.jpowsour.2012.12.102	journal	June 2013
N-Methyl-(n-butyl)pyrrolidinium bis(trifluoromethanesulfonyl)imide-LiTFSI–poly(ethylene glycol) dimethyl ether mixture as a Li/S cell electrolyte Shin, Joon Ho; Cairns, Elton J. Journal of Power Sources, Vol. 177, Issue 2, p. 537-545 https://doi.org/10.1016/j.jpowsour.2007.11.043	journal	March 2008
Binary electrolyte based on tetra(ethylene glycol) dimethyl ether and 1,3-dioxolane for lithium–sulfur battery Chang, Duck-Rye; Lee, Suck-Hyun; Kim, Sun-Wook Journal of Power Sources, Vol. 112, Issue 2 https://doi.org/10.1016/S0378-7753(02)00418-4	journal	November 2002
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D. Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21892e	journal	January 2012
A novel porous nanocomposite of sulfur/carbon obtained from fish scales for lithium–sulfur batteries Zhao, Shengrong; Li, Chengming; Wang, Weikun Journal of Materials Chemistry A, Vol. 1, Issue 10 https://doi.org/10.1039/c3ta01220d	journal	January 2013
Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium–Sulfur Batteries Gordin, Mikhail L.; Dai, Fang; Chen, Shuru ACS Applied Materials & Interfaces, Vol. 6, Issue 11 https://doi.org/10.1021/am501665s	journal	May 2014
Insight into lithium–metal anodes in lithium–sulfur batteries with a fluorinated ether electrolyte Zu, Chenxi; Azimi, Nasim; Zhang, Zhengcheng Journal of Materials Chemistry A, Vol. 3, Issue 28 https://doi.org/10.1039/C5TA03195H	journal	January 2015
Moving to a Solid-State Configuration: A Valid Approach to Making Lithium-Sulfur Batteries Viable for Practical Applications Hassoun, Jusef; Scrosati, Bruno Advanced Materials, Vol. 22, Issue 45, p. 5198-5201 https://doi.org/10.1002/adma.201002584	journal	September 2010
Carbon coated lithium sulfide particles for lithium battery cathodes Jeong, Sangsik; Bresser, Dominic; Buchholz, Daniel Journal of Power Sources, Vol. 235 https://doi.org/10.1016/j.jpowsour.2013.01.084	journal	August 2013
Sparingly Solvating Electrolytes for High Energy Density Lithium–Sulfur Batteries Cheng, Lei; Curtiss, Larry A.; Zavadil, Kevin R. ACS Energy Letters, Vol. 1, Issue 3 https://doi.org/10.1021/acsenergylett.6b00194	journal	August 2016
A strategic approach to recharging lithium-sulphur batteries for long cycle life Su, Yu-Sheng; Fu, Yongzhu; Cochell, Thomas Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3985	journal	December 2013

Cited By (10)

Development and Challenges of Functional Electrolytes for High-Performance Lithium-Sulfur Batteries Wang, Lili; Ye, Yusheng; Chen, Nan Advanced Functional Materials, Vol. 28, Issue 38 https://doi.org/10.1002/adfm.201800919	journal	July 2018
Solid-State Lithium/Selenium-Sulfur Chemistry Enabled via a Robust Solid-Electrolyte Interphase Xu, Gui-Liang; Sun, Hui; Luo, Chao Advanced Energy Materials, Vol. 9, Issue 2 https://doi.org/10.1002/aenm.201802235	journal	November 2018
The Relationship between the Relative Solvating Power of Electrolytes and Shuttling Effect of Lithium Polysulfides in Lithium-Sulfur Batteries Su, Chi-Cheung; He, Meinan; Amine, Rachid Angewandte Chemie, Vol. 130, Issue 37 https://doi.org/10.1002/ange.201807367	journal	August 2018
The Relationship between the Relative Solvating Power of Electrolytes and Shuttling Effect of Lithium Polysulfides in Lithium-Sulfur Batteries Su, Chi-Cheung; He, Meinan; Amine, Rachid Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201807367	journal	August 2018
Monitoring Polysulfide Solubility and Diffusion in Fluorinated Ether‐Based Electrolytes by Operando Raman Spectroscopy Bouchal, Roza; Boulaoued, Athmane; Johansson, Patrik Batteries & Supercaps, Vol. 3, Issue 5 https://doi.org/10.1002/batt.201900188	journal	January 2020
Nano-MgO/AB decorated separator to suppress shuttle effect of lithium–sulfur battery Sun, Wenhao; Sun, Xiaogang; Peng, Qifan Nanoscale Advances, Vol. 1, Issue 4 https://doi.org/10.1039/c8na00420j	journal	January 2019
Advances and challenges of green materials for electronics and energy storage applications: from design to end-of-life recovery Gao, Mengyao; Shih, Chien-Chung; Pan, Shu-Yuan Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/c8ta07246a	journal	January 2018
A hybrid ionic liquid-based electrolyte for high-performance lithium–sulfur batteries Lu, Hai; Zhu, Yan; Zheng, Bin New Journal of Chemistry, Vol. 44, Issue 2 https://doi.org/10.1039/c9nj03790j	journal	January 2020
Recent advances in polysulfide mediation of lithium-sulfur batteries via facile cathode and electrolyte modification Fang, Chen; Zhang, Guangzhao; Lau, Jonathan APL Materials, Vol. 7, Issue 8 https://doi.org/10.1063/1.5110525	journal	August 2019
A Rational Balance Design of Hybrid Electrolyte Based on Ionic Liquid and Fluorinated Ether in Lithium Sulfur Batteries Lu, Hai; Chen, Zhen; Yuan, Yan Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0321912jes	journal	January 2019

Similar Records

A Fluorinated Ether Electrolyte Enabled High Performance Prelithiated Graphite/Sulfur Batteries

Journal Article · Fri Feb 03 00:00:00 EST 2017 · ACS Applied Materials and Interfaces · OSTI ID:1367284

Chen, Shuru; Yu, Zhaoxin; Gordin, Mikhail L.; +3 more

Structural Dependence of the Sulfur Reduction Mechanism in Carbon-Based Cathodes for Lithium–Sulfur Batteries

Journal Article · Thu Aug 17 00:00:00 EDT 2017 · Journal of Physical Chemistry. C · OSTI ID:1367284

Burgos, Juan C.; Balbuena, Perla B.; Montoya, Javier A.

An in situ generated polymer electrolyte via anionic ring-opening polymerization for lithium–sulfur batteries

Journal Article · Mon Nov 15 00:00:00 EST 2021 · Journal of Materials Chemistry. A · OSTI ID:1367284

Meisner, Quinton J.; Jiang, Sisi; Cao, Pengfei; +3 more

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
1
2-bis(1
1
2
2-tetrafluoroethoxy) ethane
fish-scale porous carbon/sulfur composite
fluorinated electrolyte
lithium-sulfur battery
suppression of lithium polysulfide dissolution

Title: A high performance lithium–sulfur battery enabled by a fish-scale porous carbon/sulfur composite and symmetric fluorinated diethoxyethane electrolyte

Citation Formats

References (45)

Cited By (10)

Similar Records

Related Subjects