Photoionization Efficiencies of Five Polycyclic Aromatic Hydrocarbons
Abstract
We have measured photoionization-efficiency curves for pyrene, fluoranthene, chrysene, perylene, and coronene in the photon energy range of 7.5-10.2 eV and derived their photoionization cross-section curves in this energy range. All measurements were performed using tunable vacuum ultraviolet (VUV) radiation generated at the Advanced Light Source synchrotron at Lawrence Berkeley National Laboratory. The VUV radiation was used for photoionization, and detection was performed using a time-of-flight mass spectrometer. We measured the photoionization efficiency of 2,5-dimethylfuran simultaneously with those of pyrene, fluoranthene, chrysene, perylene, and coronene to obtain references of the photon flux during each measurement from the known photoionization cross-section curve of 2,5-dimethylfuran.
- Authors:
-
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Univ. of Michigan, Ann Arbor, MI (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-CA), Livermore, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1365806
- Alternate Identifier(s):
- OSTI ID: 1458499
- Report Number(s):
- SAND-2017-5881J
Journal ID: ISSN 1089-5639; 653851
- Grant/Contract Number:
- AC04-94AL85000; AC02-05CH11231
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
- Additional Journal Information:
- Journal Volume: 121; Journal Issue: 23; Journal ID: ISSN 1089-5639
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Johansson, K. Olof, Campbell, Matthew F., Elvati, Paolo, Schrader, Paul E., Zádor, Judit, Richards-Henderson, Nicole K., Wilson, Kevin R., Violi, Angela, and Michelsen, Hope A. Photoionization Efficiencies of Five Polycyclic Aromatic Hydrocarbons. United States: N. p., 2017.
Web. doi:10.1021/acs.jpca.7b02991.
Johansson, K. Olof, Campbell, Matthew F., Elvati, Paolo, Schrader, Paul E., Zádor, Judit, Richards-Henderson, Nicole K., Wilson, Kevin R., Violi, Angela, & Michelsen, Hope A. Photoionization Efficiencies of Five Polycyclic Aromatic Hydrocarbons. United States. https://doi.org/10.1021/acs.jpca.7b02991
Johansson, K. Olof, Campbell, Matthew F., Elvati, Paolo, Schrader, Paul E., Zádor, Judit, Richards-Henderson, Nicole K., Wilson, Kevin R., Violi, Angela, and Michelsen, Hope A. 2017.
"Photoionization Efficiencies of Five Polycyclic Aromatic Hydrocarbons". United States. https://doi.org/10.1021/acs.jpca.7b02991. https://www.osti.gov/servlets/purl/1365806.
@article{osti_1365806,
title = {Photoionization Efficiencies of Five Polycyclic Aromatic Hydrocarbons},
author = {Johansson, K. Olof and Campbell, Matthew F. and Elvati, Paolo and Schrader, Paul E. and Zádor, Judit and Richards-Henderson, Nicole K. and Wilson, Kevin R. and Violi, Angela and Michelsen, Hope A.},
abstractNote = {We have measured photoionization-efficiency curves for pyrene, fluoranthene, chrysene, perylene, and coronene in the photon energy range of 7.5-10.2 eV and derived their photoionization cross-section curves in this energy range. All measurements were performed using tunable vacuum ultraviolet (VUV) radiation generated at the Advanced Light Source synchrotron at Lawrence Berkeley National Laboratory. The VUV radiation was used for photoionization, and detection was performed using a time-of-flight mass spectrometer. We measured the photoionization efficiency of 2,5-dimethylfuran simultaneously with those of pyrene, fluoranthene, chrysene, perylene, and coronene to obtain references of the photon flux during each measurement from the known photoionization cross-section curve of 2,5-dimethylfuran.},
doi = {10.1021/acs.jpca.7b02991},
url = {https://www.osti.gov/biblio/1365806},
journal = {Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory},
issn = {1089-5639},
number = 23,
volume = 121,
place = {United States},
year = {Thu May 18 00:00:00 EDT 2017},
month = {Thu May 18 00:00:00 EDT 2017}
}
Web of Science
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