The surface chemistry of cerium oxide

Mullins, David R.

doi:10.1016/j.surfrep.2014.12.001

Title: The surface chemistry of cerium oxide

Journal Article · Thu Jan 29 00:00:00 EST 2015 · Surface Science Reports

DOI:https://doi.org/10.1016/j.surfrep.2014.12.001· OSTI ID:1185722

Mullins, David R. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Our review covers the structure of, and chemical reactions on, well-defined cerium oxide surfaces. Ceria, or mixed oxides containing ceria, are critical components in automotive three-way catalysts due to their well-known oxygen storage capacity. Ceria is also emerging as an important material in a number of other catalytic processes, particularly those involving organic oxygenates and the water–gas shift reaction. Ceria's acid–base properties, and thus its catalytic behavior, are closely related to its surface structure where different oxygen anion and cerium cation environments are present on the low-index structural faces. The actual structure of these various faces has been the focus of a number of theoretical and experimental investigations. Ceria is also easily reducible from CeO₂ to CeO_2-X. The presence of oxygen vacancies on the surface often dramatically alters the adsorption and subsequent reactions of various adsorbates, either on a clean surface or on metal particles supported on the surface. We conducted surface science studies on the surfaces of thin-films rather than on the surfaces of bulk single crystal oxides. The growth, characterization and properties of these thin-films are also examined.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1185722

Alternate ID(s):: OSTI ID: 1365421

Journal Information:: Surface Science Reports, Vol. 70, Issue 1; ISSN 0167-5729

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 463 works

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