Encapsulation of large dye molecules in hierarchically superstructured metal–organic frameworks

Yue, Yanfeng; Binder, Andrew J.; Song, Ruijing; Cui, Yuanjing; Chen, Jihua; Hensley, Dale K.; Dai, Sheng

doi:10.1039/C4DT02516D

Title: Encapsulation of large dye molecules in hierarchically superstructured metal–organic frameworks

Journal Article · Wed Oct 01 00:00:00 EDT 2014 · Dalton Transactions

DOI:https://doi.org/10.1039/C4DT02516D· OSTI ID:1364272

Yue, Yanfeng ^[1]; Binder, Andrew J. ^[2]; Song, Ruijing ^[3]; Cui, Yuanjing ^[3]; Chen, Jihua ^[4]; Hensley, Dale K. ^[4]; Dai, Sheng ^[5]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Zhejiang Univ., Hangzhou (China).. Dept. of Materials Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

Microporous metal–organic frameworks (MOFs) represent a new family of microporous materials, offering potential applications in gas separation and storage, catalysis, and membranes. We expect that the engineering of hierarchical superstructured MOFs, i.e., fabricating mesopores in microporous frameworks during the crystallization stage will serve a myriad of applications for molecular adsorption, drug delivery, and catalysis. But, MOFs with mesopores are rarely studied because of the lack of a simple, effective way to construct mesoscale cavities in the structures. We report the use of a perturbation-assisted nanofusion technique to construct hierarchically superstructured MOFs. In particular, the mesopores in the MOF structure enabled the confinement of large dye species, resulting in fluorescent MOF materials, which can serve as a new type of ratiometric luminescent sensors for typical volatile organic compounds.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1364272

Journal Information:: Dalton Transactions, Vol. 43, Issue 48; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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