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Title: "Wine-Dark Sea" in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability

Abstract

A highly soluble, readily accessible, redox-active organic material, 2,1,3-benzothiadiazole, is demonstrated as a novel anolyte material to enable exceptional cyclability in a full-cell organic redox flow battery. This material discovery represents a significant progress toward promising next-generation energy storage.

Authors:
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Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1363993
Report Number(s):
PNNL-SA-120607
Journal ID: ISSN 2380-8195; 49376; KC0208010
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: ACS Energy Letters; Journal Volume: 2; Journal Issue: 5
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; redox flow batteries; organic; anolyte; radical; stability; Environmental Molecular Sciences Laboratory

Citation Formats

Duan, Wentao, Huang, Jinhua, Kowalski, Jeffrey A., Shkrob, Ilya A., Vijayakumar, M., Walter, Eric, Pan, Baofei, Yang, Zheng, Milshtein, Jarrod D., Li, Bin, Liao, Chen, Zhang, Zhengcheng, Wang, Wei, Liu, Jun, Moore, Jeffery S., Brushett, Fikile R., Zhang, Lu, and Wei, Xiaoliang. "Wine-Dark Sea" in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability. United States: N. p., 2017. Web. doi:10.1021/acsenergylett.7b00261.
Duan, Wentao, Huang, Jinhua, Kowalski, Jeffrey A., Shkrob, Ilya A., Vijayakumar, M., Walter, Eric, Pan, Baofei, Yang, Zheng, Milshtein, Jarrod D., Li, Bin, Liao, Chen, Zhang, Zhengcheng, Wang, Wei, Liu, Jun, Moore, Jeffery S., Brushett, Fikile R., Zhang, Lu, & Wei, Xiaoliang. "Wine-Dark Sea" in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability. United States. doi:10.1021/acsenergylett.7b00261.
Duan, Wentao, Huang, Jinhua, Kowalski, Jeffrey A., Shkrob, Ilya A., Vijayakumar, M., Walter, Eric, Pan, Baofei, Yang, Zheng, Milshtein, Jarrod D., Li, Bin, Liao, Chen, Zhang, Zhengcheng, Wang, Wei, Liu, Jun, Moore, Jeffery S., Brushett, Fikile R., Zhang, Lu, and Wei, Xiaoliang. Wed . ""Wine-Dark Sea" in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability". United States. doi:10.1021/acsenergylett.7b00261.
@article{osti_1363993,
title = {"Wine-Dark Sea" in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability},
author = {Duan, Wentao and Huang, Jinhua and Kowalski, Jeffrey A. and Shkrob, Ilya A. and Vijayakumar, M. and Walter, Eric and Pan, Baofei and Yang, Zheng and Milshtein, Jarrod D. and Li, Bin and Liao, Chen and Zhang, Zhengcheng and Wang, Wei and Liu, Jun and Moore, Jeffery S. and Brushett, Fikile R. and Zhang, Lu and Wei, Xiaoliang},
abstractNote = {A highly soluble, readily accessible, redox-active organic material, 2,1,3-benzothiadiazole, is demonstrated as a novel anolyte material to enable exceptional cyclability in a full-cell organic redox flow battery. This material discovery represents a significant progress toward promising next-generation energy storage.},
doi = {10.1021/acsenergylett.7b00261},
journal = {ACS Energy Letters},
number = 5,
volume = 2,
place = {United States},
year = {Wed Apr 19 00:00:00 EDT 2017},
month = {Wed Apr 19 00:00:00 EDT 2017}
}