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Title: Photocatalytic water splitting—The untamed dream: A review of recent advances

Abstract

Here, photocatalytic water splitting using sunlight is a promising technology capable of providing high energy yield without pollutant byproducts. Herein, we review various aspects of this technology including chemical reactions, physiochemical conditions and photocatalyst types such as metal oxides, sulfides, nitrides, nanocomposites, and doped materials followed by recent advances in computational modeling of photoactive materials. As the best-known catalyst for photocatalytic hydrogen and oxygen evolution, TiO 2 is discussed in a separate section, along with its challenges such as the wide band gap, large overpotential for hydrogen evolution, and rapid recombination of produced electron-hole pairs. Various approaches are addressed to overcome these shortcomings, such as doping with different elements, heterojunction catalysts, noble metal deposition, and surface modification. Development of a photocatalytic corrosion resistant, visible light absorbing, defect-tuned material with small particle size is the key to complete the sunlight to hydrogen cycle efficiently. Computational studies have opened new avenues to understand and predict the electronic density of states and band structure of advanced materials and could pave the way for the rational design of efficient photocatalysts for water splitting. Future directions are focused on developing innovative junction architectures, novel synthesis methods and optimizing the existing active materials to enhance chargemore » transfer, visible light absorption, reducing the gas evolution overpotential and maintaining chemical and physical stability« less

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Univ. of Connecticut, Storrs, CT (United States)
Publication Date:
Research Org.:
Univ. of Connecticut, Storrs, CT (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1361699
Grant/Contract Number:  
FG02-86ER13622
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Molecules
Additional Journal Information:
Journal Volume: 21; Journal Issue: 7; Journal ID: ISSN 1420-3049
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; water splitting; solar fuels; hydrogen; photocatalysis; photocatalysts; semiconductors; nanomaterials; metal oxides; nanotechnology

Citation Formats

Jafari, Tahereh, Moharreri, Ehsan, Amin, Alireza Shirazi, Miao, Ran, Song, Wenqiao, and Suib, Steven L. Photocatalytic water splitting—The untamed dream: A review of recent advances. United States: N. p., 2016. Web. doi:10.3390/molecules21070900.
Jafari, Tahereh, Moharreri, Ehsan, Amin, Alireza Shirazi, Miao, Ran, Song, Wenqiao, & Suib, Steven L. Photocatalytic water splitting—The untamed dream: A review of recent advances. United States. doi:10.3390/molecules21070900.
Jafari, Tahereh, Moharreri, Ehsan, Amin, Alireza Shirazi, Miao, Ran, Song, Wenqiao, and Suib, Steven L. Sat . "Photocatalytic water splitting—The untamed dream: A review of recent advances". United States. doi:10.3390/molecules21070900. https://www.osti.gov/servlets/purl/1361699.
@article{osti_1361699,
title = {Photocatalytic water splitting—The untamed dream: A review of recent advances},
author = {Jafari, Tahereh and Moharreri, Ehsan and Amin, Alireza Shirazi and Miao, Ran and Song, Wenqiao and Suib, Steven L.},
abstractNote = {Here, photocatalytic water splitting using sunlight is a promising technology capable of providing high energy yield without pollutant byproducts. Herein, we review various aspects of this technology including chemical reactions, physiochemical conditions and photocatalyst types such as metal oxides, sulfides, nitrides, nanocomposites, and doped materials followed by recent advances in computational modeling of photoactive materials. As the best-known catalyst for photocatalytic hydrogen and oxygen evolution, TiO2 is discussed in a separate section, along with its challenges such as the wide band gap, large overpotential for hydrogen evolution, and rapid recombination of produced electron-hole pairs. Various approaches are addressed to overcome these shortcomings, such as doping with different elements, heterojunction catalysts, noble metal deposition, and surface modification. Development of a photocatalytic corrosion resistant, visible light absorbing, defect-tuned material with small particle size is the key to complete the sunlight to hydrogen cycle efficiently. Computational studies have opened new avenues to understand and predict the electronic density of states and band structure of advanced materials and could pave the way for the rational design of efficient photocatalysts for water splitting. Future directions are focused on developing innovative junction architectures, novel synthesis methods and optimizing the existing active materials to enhance charge transfer, visible light absorption, reducing the gas evolution overpotential and maintaining chemical and physical stability},
doi = {10.3390/molecules21070900},
journal = {Molecules},
issn = {1420-3049},
number = 7,
volume = 21,
place = {United States},
year = {2016},
month = {7}
}

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Works referenced in this record:

CO2 emissions, energy consumption and economic growth in BRIC countries
journal, December 2010


Consumption-based accounting of CO2 emissions
journal, March 2010

  • Davis, S. J.; Caldeira, K.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 12
  • DOI: 10.1073/pnas.0906974107

Blaming cities for climate change? An analysis of urban greenhouse gas emissions inventories
journal, April 2009


Visible-light driven heterojunction photocatalysts for water splitting – a critical review
journal, January 2015

  • Moniz, Savio J. A.; Shevlin, Stephen A.; Martin, David James
  • Energy & Environmental Science, Vol. 8, Issue 3
  • DOI: 10.1039/C4EE03271C

American policy conflict in the greenhouse: Divergent trends in federal, regional, state, and local green energy and climate change policy
journal, September 2007


Irreversible climate change due to carbon dioxide emissions
journal, January 2009

  • Solomon, Susan; Plattner, Gian-Kasper; Knutti, Reto
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 6
  • DOI: 10.1073/pnas.0812721106

Determining the temperature of petroleum formation from the kinetic properties of petroleum asphaltenes
journal, July 2000

  • di Primio, Rolando; Horsfield, Brian; Guzman-Vega, Mario A.
  • Nature, Vol. 406, Issue 6792
  • DOI: 10.1038/35018046

Geothermal energy technology and current status: an overview
journal, January 2002


A review of solar photovoltaic technologies
journal, April 2011

  • Parida, Bhubaneswari; Iniyan, S.; Goic, Ranko
  • Renewable and Sustainable Energy Reviews, Vol. 15, Issue 3
  • DOI: 10.1016/j.rser.2010.11.032

Concentrated solar energy applications using Fresnel lenses: A review
journal, August 2011


Quantum efficiency modeling and system scaling-up analysis of water splitting with Cd1−xZnxS solid-solution photocatalyst
journal, June 2013


Sustainable Hydrogen Production
journal, August 2004


Efficient and affordable hydrogen production by water photo-splitting using TiO2-based photocatalysts
journal, February 2013

  • Pulido Melián, E.; González Díaz, O.; Ortega Méndez, A.
  • International Journal of Hydrogen Energy, Vol. 38, Issue 5
  • DOI: 10.1016/j.ijhydene.2012.12.005

Nanostructured materials for photocatalytic hydrogen production
journal, August 2009


On hydrogen and hydrogen energy strategies
journal, June 2005


Hydrogen production by photocatalytic steam reforming of methanol on noble metal-modified TiO2
journal, July 2010


The kinetics of methane steam reforming over a Ni/α-Al2O catalyst
journal, March 2001


Hydrogen from biomass-production by steam reforming of biomass pyrolysis oil☆
journal, December 2007


An overview of hydrogen production from biomass
journal, May 2006


A novel photocatalyst LaOF: Facile fabrication and photocatalytic hydrogen production
journal, October 2012


Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
journal, September 2014


Enhanced TiO2 photocatalysis by Cu in hydrogen production from aqueous methanol solution
journal, December 2004


Hydrogen Production from Semiconductor-based Photocatalysis via Water Splitting
journal, October 2012

  • Liao, Chi-Hung; Huang, Chao-Wei; Wu, Jeffrey C. S.
  • Catalysts, Vol. 2, Issue 4
  • DOI: 10.3390/catal2040490

Solar hydrogen production via a two-step water-splitting thermochemical cycle based on Zn/ZnO redox reactions
journal, June 2002


Photobiological hydrogen production: photochemical efficiency and bioreactor design
journal, November 2002


Advances in biological hydrogen production processes
journal, November 2008


Two-stage photo-biological production of hydrogen by marine green alga Platymonas subcordiformis
journal, July 2004


Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Photocatalysis and solar hydrogen production
journal, January 2007


Heterogeneous photocatalyst materials for water splitting
journal, January 2009

  • Kudo, Akihiko; Miseki, Yugo
  • Chem. Soc. Rev., Vol. 38, Issue 1
  • DOI: 10.1039/B800489G

Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
journal, May 1995

  • Linsebigler, Amy L.; Lu, Guangquan.; Yates, John T.
  • Chemical Reviews, Vol. 95, Issue 3
  • DOI: 10.1021/cr00035a013

Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst
journal, December 2001

  • Zou, Zhigang; Ye, Jinhua; Sayama, Kazuhiro
  • Nature, Vol. 414, Issue 6864
  • DOI: 10.1038/414625a

Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972

  • Fujishima, Akira; Honda, Kenichi
  • Nature, Vol. 238, Issue 5358, p. 37-38
  • DOI: 10.1038/238037a0

A Photo-electochemical cell with production of hydrogen and oxygen by a cell reaction
journal, May 1975


A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production
journal, April 2007

  • Ni, Meng; Leung, Michael K. H.; Leung, Dennis Y. C.
  • Renewable and Sustainable Energy Reviews, Vol. 11, Issue 3
  • DOI: 10.1016/j.rser.2005.01.009

Ordered Mesoporous Black TiO 2 as Highly Efficient Hydrogen Evolution Photocatalyst
journal, June 2014

  • Zhou, Wei; Li, Wei; Wang, Jian-Qiang
  • Journal of the American Chemical Society, Vol. 136, Issue 26
  • DOI: 10.1021/ja504802q

New Benchmark for Water Photooxidation by Nanostructured α-Fe 2 O 3 Films
journal, December 2006

  • Kay, Andreas; Cesar, Ilkay; Grätzel, Michael
  • Journal of the American Chemical Society, Vol. 128, Issue 49
  • DOI: 10.1021/ja064380l

Single-crystalline, wormlike hematite photoanodes for efficient solar water splitting
journal, September 2013

  • Kim, Jae Young; Magesh, Ganesan; Youn, Duck Hyun
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02681

Band Edge Electronic Structure of BiVO 4 : Elucidating the Role of the Bi s and V d Orbitals
journal, February 2009

  • Walsh, Aron; Yan, Yanfa; Huda, Muhammad N.
  • Chemistry of Materials, Vol. 21, Issue 3
  • DOI: 10.1021/cm802894z

Electronic Structure of Monoclinic BiVO 4
journal, September 2014

  • Cooper, Jason K.; Gul, Sheraz; Toma, Francesca M.
  • Chemistry of Materials, Vol. 26, Issue 18
  • DOI: 10.1021/cm5025074

Sulfonate-Grafted Porous Polymer Networks for Preferential CO2 Adsorption at Low Pressure
journal, November 2011

  • Lu, Weigang; Yuan, Daqiang; Sculley, Julian
  • Journal of the American Chemical Society, Vol. 133, Issue 45, p. 18126-18129
  • DOI: 10.1021/ja2087773

Highly Improved Quantum Efficiencies for Thin Film BiVO 4 Photoanodes
journal, August 2011

  • Liang, Yongqi; Tsubota, Toshiki; Mooij, Lennard P. A.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 35
  • DOI: 10.1021/jp203004v

Rapid Screening of BiVO 4 -Based Photocatalysts by Scanning Electrochemical Microscopy (SECM) and Studies of Their Photoelectrochemical Properties
journal, July 2010

  • Ye, Heechang; Lee, Joowook; Jang, Jum Suk
  • The Journal of Physical Chemistry C, Vol. 114, Issue 31
  • DOI: 10.1021/jp104343b

Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO 4
journal, November 2011

  • Zhong, Diane K.; Choi, Sujung; Gamelin, Daniel R.
  • Journal of the American Chemical Society, Vol. 133, Issue 45
  • DOI: 10.1021/ja207348x

Electrochemical deposition and photoelectrochemistry of CuWO4, a promising photoanode for water oxidation
journal, January 2011

  • Yourey, Joseph E.; Bartlett, Bart M.
  • Journal of Materials Chemistry, Vol. 21, Issue 21
  • DOI: 10.1039/c1jm11259g

Synthesis and Photoelectrochemical Properties of Fe 2 O 3 /ZnFe 2 O 4 Composite Photoanodes for Use in Solar Water Oxidation
journal, November 2011

  • McDonald, Kenneth J.; Choi, Kyoung-Shin
  • Chemistry of Materials, Vol. 23, Issue 21
  • DOI: 10.1021/cm202399g

Preparation of p-Type CaFe 2 O 4 Photocathodes for Producing Hydrogen from Water
journal, December 2010

  • Ida, Shintaro; Yamada, Keisuke; Matsunaga, Takuya
  • Journal of the American Chemical Society, Vol. 132, Issue 49
  • DOI: 10.1021/ja106930f

Low temperature grown CuBi 2 O 4 with flower morphology and its composite with CuO nanosheets for photoelectrochemical water splitting
journal, January 2014

  • Patil, Rupali; Kelkar, Sarika; Naphade, Rounak
  • J. Mater. Chem. A, Vol. 2, Issue 10
  • DOI: 10.1039/c3ta14906d

CuNb 3 O 8 : A p-Type Semiconducting Metal Oxide Photoelectrode
journal, May 2012

  • Joshi, Upendra A.; Maggard, Paul A.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 11
  • DOI: 10.1021/jz300477r

Highly Stable Water Splitting on Oxynitride TaON Photoanode System under Visible Light Irradiation
journal, April 2012

  • Higashi, Masanobu; Domen, Kazunari; Abe, Ryu
  • Journal of the American Chemical Society, Vol. 134, Issue 16
  • DOI: 10.1021/ja302059g

Enhancement of Solar Hydrogen Evolution from Water by Surface Modification with CdS and TiO 2 on Porous CuInS 2 Photocathodes Prepared by an Electrodeposition-Sulfurization Method
journal, September 2014

  • Zhao, Jiao; Minegishi, Tsutomu; Zhang, Li
  • Angewandte Chemie International Edition, Vol. 53, Issue 44
  • DOI: 10.1002/anie.201406483

Durable hydrogen evolution from water driven by sunlight using (Ag,Cu)GaSe 2 photocathodes modified with CdS and CuGa 3 Se 5
journal, January 2015

  • Zhang, Li; Minegishi, Tsutomu; Nakabayashi, Mamiko
  • Chemical Science, Vol. 6, Issue 2
  • DOI: 10.1039/C4SC02346C

Stable Hydrogen Evolution from CdS-Modified CuGaSe 2 Photoelectrode under Visible-Light Irradiation
journal, March 2013

  • Moriya, Makoto; Minegishi, Tsutomu; Kumagai, Hiromu
  • Journal of the American Chemical Society, Vol. 135, Issue 10
  • DOI: 10.1021/ja312653y

Hydrogen Production Using a Molybdenum Sulfide Catalyst on a Titanium-Protected n+p-Silicon Photocathode
journal, August 2012

  • Seger, Brian; Laursen, Anders B.; Vesborg, Peter C. K.
  • Angewandte Chemie International Edition, Vol. 51, Issue 36
  • DOI: 10.1002/anie.201203585

Zn-Doped p-Type Gallium Phosphide Nanowire Photocathodes from a Surfactant-Free Solution Synthesis
journal, September 2012

  • Liu, Chong; Sun, Jianwei; Tang, Jinyao
  • Nano Letters, Vol. 12, Issue 10
  • DOI: 10.1021/nl3028729

A Facile Band Alignment of Polymeric Carbon Nitride Semiconductors to Construct Isotype Heterojunctions
journal, September 2012

  • Zhang, Jinshui; Zhang, Mingwen; Sun, Rui-Qing
  • Angewandte Chemie, Vol. 124, Issue 40
  • DOI: 10.1002/ange.201205333

Photoelectrochemical Hydrogen Evolution Using Si Microwire Arrays
journal, January 2011

  • Boettcher, Shannon W.; Warren, Emily L.; Putnam, Morgan C.
  • Journal of the American Chemical Society, Vol. 133, Issue 5, p. 1216-1219
  • DOI: 10.1021/ja108801m

Evaluation of Pt, Ni, and Ni–Mo electrocatalysts for hydrogen evolution on crystalline Si electrodes
journal, January 2011

  • McKone, James R.; Warren, Emily L.; Bierman, Matthew J.
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01488a

Significant Efficiency Increase in Self-Driven Photoelectrochemical Cell for Water Photoelectrolysis
journal, January 1987

  • Kainthla, R. C.
  • Journal of The Electrochemical Society, Vol. 134, Issue 4
  • DOI: 10.1149/1.2100583

Single and Tandem Axial p-i-n Nanowire Photovoltaic Devices
journal, September 2008

  • Kempa, Thomas J.; Tian, Bozhi; Kim, Dong Rip
  • Nano Letters, Vol. 8, Issue 10, p. 3456-3460
  • DOI: 10.1021/nl8023438

Visible-light-sensitive two-step overall water-splitting based on band structure control of titanium dioxide
journal, January 2016


Efficient hydrogen production by water-splitting over Pt-deposited C–HS–TiO2 hollow spheres under visible light
journal, March 2016

  • Zhu, Zhen; Chen, Jian-You; Su, Kang-Yang
  • Journal of the Taiwan Institute of Chemical Engineers, Vol. 60
  • DOI: 10.1016/j.jtice.2015.10.001

Sub-10 nm rutile titanium dioxide nanoparticles for efficient visible-light-driven photocatalytic hydrogen production
journal, January 2015

  • Li, Landong; Yan, Junqing; Wang, Tuo
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms6881

Core/Shell Structured La- and Rh-Codoped SrTiO 3 as a Hydrogen Evolution Photocatalyst in Z-Scheme Overall Water Splitting under Visible Light Irradiation
journal, July 2014

  • Wang, Qian; Hisatomi, Takashi; Ma, Su Su Khine
  • Chemistry of Materials, Vol. 26, Issue 14
  • DOI: 10.1021/cm5011983

Synergetic Integration of Cu 1.94 S–Zn x Cd 1– x S Heteronanorods for Enhanced Visible-Light-Driven Photocatalytic Hydrogen Production
journal, March 2016

  • Chen, Yueguang; Zhao, Shu; Wang, Xian
  • Journal of the American Chemical Society, Vol. 138, Issue 13
  • DOI: 10.1021/jacs.5b12666

1,2,4-Triazole-Based Approach to Noble-Metal-Free Visible-Light Driven Water Splitting over Carbon Nitrides
journal, January 2016


Layered Perovskite Oxychloride Bi 4 NbO 8 Cl: A Stable Visible Light Responsive Photocatalyst for Water Splitting
journal, February 2016

  • Fujito, Hironori; Kunioku, Hironobu; Kato, Daichi
  • Journal of the American Chemical Society, Vol. 138, Issue 7
  • DOI: 10.1021/jacs.5b11191

A cocatalyst-free CdS nanorod/ZnS nanoparticle composite for high-performance visible-light-driven hydrogen production from water
journal, January 2016

  • Jiang, Daochuan; Sun, Zijun; Jia, Hongxing
  • Journal of Materials Chemistry A, Vol. 4, Issue 2
  • DOI: 10.1039/C5TA07420G

Hierarchical Layered WS 2 /Graphene-Modified CdS Nanorods for Efficient Photocatalytic Hydrogen Evolution
journal, April 2016


Visible light responsive noble metal-free nanocomposite of V-doped TiO2 nanorod with highly reduced graphene oxide for enhanced solar H2 production
journal, May 2016

  • Agegnehu, Abiye Kebede; Pan, Chun-Jern; Tsai, Meng-Che
  • International Journal of Hydrogen Energy, Vol. 41, Issue 16
  • DOI: 10.1016/j.ijhydene.2016.03.025

Overall water splitting by Pt/g-C 3 N 4 photocatalysts without using sacrificial agents
journal, January 2016

  • Zhang, Guigang; Lan, Zhi-An; Lin, Lihua
  • Chemical Science, Vol. 7, Issue 5
  • DOI: 10.1039/C5SC04572J

Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%
journal, March 2016

  • Wang, Qian; Hisatomi, Takashi; Jia, Qingxin
  • Nature Materials, Vol. 15, Issue 6
  • DOI: 10.1038/nmat4589

Highly Dispersed Cobalt Oxide on TaON as Efficient Photoanodes for Long-Term Solar Water Splitting
journal, April 2016

  • Gujral, Satnam Singh; Simonov, Alexandr N.; Higashi, Masanobu
  • ACS Catalysis, Vol. 6, Issue 5
  • DOI: 10.1021/acscatal.6b00629

MoS 2 Nanosheet-Modified CuInS 2 Photocatalyst for Visible-Light-Driven Hydrogen Production from Water
journal, April 2016


A Semi-Conductive Copper-Organic Framework with Two Types of Photocatalytic Activity
journal, January 2016

  • Wu, Zhi-Lei; Wang, Chang-Hong; Zhao, Bin
  • Angewandte Chemie International Edition, Vol. 55, Issue 16
  • DOI: 10.1002/anie.201508325

Light work with water
journal, December 2001


Photoelectrochemical Water Splitting
journal, December 2007


Overall Water Splitting on Tungsten-Based Photocatalysts with Defect Pyrochlore Structure
journal, December 2004


Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts
journal, September 2011


New Insights into Defect-Mediated Heterostructures for Photoelectrochemical Water Splitting
journal, January 2016


Photocatalytic Activity of Inorganic Semiconductor Surfaces: Myths, Hype, and Reality
journal, December 2014

  • Rajeshwar, Krishnan; Thomas, Abegayl; Janáky, Csaba
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 1
  • DOI: 10.1021/jz502586p

Hydrothermal Synthesis and Photocatalytic Activity of Zinc Oxide Hollow Spheres
journal, July 2008

  • Yu, Jiaguo; Yu, Xiaoxiao
  • Environmental Science & Technology, Vol. 42, Issue 13
  • DOI: 10.1021/es800036n

Microwave assisted synthesis of sheet-like Cu/BiVO4 and its activities of various photocatalytic conditions
journal, September 2015


Crystalline Mixed Phase (Anatase/Rutile) Mesoporous Titanium Dioxides for Visible Light Photocatalytic Activity
journal, December 2014

  • Luo, Zhu; Poyraz, Altug S.; Kuo, Chung-Hao
  • Chemistry of Materials, Vol. 27, Issue 1
  • DOI: 10.1021/cm5035112

Effect of pH on the sonochemical synthesis of BiPO4 nanostructures and its electrochemical properties for pseudocapacitors
journal, January 2015


Hydrogen from photo-catalytic water splitting process: A review
journal, March 2015


Heterostructured Cu 2 O/CuO decorated with nickel as a highly efficient photocathode for photoelectrochemical water reduction
journal, January 2015

  • Dubale, Amare Aregahegn; Pan, Chun-Jern; Tamirat, Andebet Gedamu
  • Journal of Materials Chemistry A, Vol. 3, Issue 23
  • DOI: 10.1039/C5TA01961C

Enhanced visible-light activities for PEC water reduction of CuO nanoplates by coupling with anatase TiO2 and mechanism
journal, October 2015


Effect of pH on the morphology and optical properties of modified ZnO particles by SDS via a precipitation method
journal, November 2010


Effects of pH on the Hierarchical Structures and Photocatalytic Performance of BiVO 4 Powders Prepared via the Microwave Hydrothermal Method
journal, May 2013

  • Tan, Guoqiang; Zhang, Lili; Ren, Huijun
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 11
  • DOI: 10.1021/am401019m

The pH-controlled morphology transition of BiVO4 photocatalysts from microparticles to hollow microspheres
journal, April 2015


Hydrothermal synthesis of BiVO4: Structural and morphological influence on the photocatalytic activity
journal, May 2012


Efficient Methylene Blue Removal over Hydrothermally Synthesized Starlike BiVO 4
journal, February 2009

  • Sun, Songmei; Wang, Wenzhong; Zhou, Lin
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 4
  • DOI: 10.1021/ie801516u

Controllable synthesis of Bi2MoO6 and effect of morphology and variation in local structure on photocatalytic activities
journal, August 2010


Synthesis of a Highly Efficient BiOCl Single-Crystal Nanodisk Photocatalyst with Exposing {001} Facets
journal, May 2014

  • Zhang, Xing; Wang, Xin-Bo; Wang, Li-Wei
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 10
  • DOI: 10.1021/am5010392

Surface modification of semiconductor photoelectrodes
journal, January 2015

  • Guijarro, Néstor; Prévot, Mathieu S.; Sivula, Kevin
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 24
  • DOI: 10.1039/C5CP01992C

Facile synthesis of CuO nanomorphs and their morphology dependent sunlight driven photocatalytic properties
journal, September 2012


Preparation and efficient visible light-induced photocatalytic activity of m-BiVO4 with different morphologies
journal, October 2015


Novel synthesis and photocatalytic performance of BiVO4 with tunable morphologies and macroscopic structures
journal, October 2015


One-pot template-free synthesis of heterophase BiVO 4 microspheres with enhanced photocatalytic activity
journal, January 2015

  • Hu, Yin; Li, Danzhen; Sun, Fuqian
  • RSC Advances, Vol. 5, Issue 68
  • DOI: 10.1039/C5RA09785A

Synthesis of monoclinic structured BiVO4 spindly microtubes in deep eutectic solvent and their application for dye degradation
journal, September 2010


Additive-free controllable fabrication of bismuth vanadates and their photocatalytic activity toward dye degradation
journal, January 2010


Hydrothermal synthesis and photoelectric properties of BiVO4 with different morphologies: An efficient visible-light photocatalyst
journal, June 2011


Porous olive-like BiVO4: Alcoho-hydrothermal preparation and excellent visible-light-driven photocatalytic performance for the degradation of phenol
journal, June 2011


Butterfly-like BiVO 4 : Synthesis and Visible Light Photocatalytic Activity
journal, July 2015

  • Wang, Qiaoli; Jiang, Haiyan; Ding, Shuting
  • Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 46, Issue 4
  • DOI: 10.1080/15533174.2014.988801

Synthesis of buckhorn-like BiVO4 with a shell of CeO nanodots: Effect of heterojunction structure on the enhancement of photocatalytic activity
journal, July 2015


One-dimensional spindle-like BiVO4/TiO2 nanofibers heterojunction nanocomposites with enhanced visible light photocatalytic activity
journal, February 2016


A shuriken-shaped m-BiVO4/{0 0 1}–TiO2 heterojunction: Synthesis, structure and enhanced visible light photocatalytic activity
journal, July 2016


A new use for bandgap engineering
journal, January 2015


Semiconductor Composites: Strategies for Enhancing Charge Carrier Separation to Improve Photocatalytic Activity
journal, December 2013


Visible light driven type II heterostructures and their enhanced photocatalysis properties: a review
journal, January 2013

  • Wang, Yajun; Wang, Qisheng; Zhan, Xueying
  • Nanoscale, Vol. 5, Issue 18
  • DOI: 10.1039/c3nr01577g

Enhanced photoelectrochemical activity of an excitonic staircase in CdS@TiO2 and CdS@anatase@rutile TiO2 heterostructures
journal, January 2012

  • Li, Jiangtian; Hoffmann, Martin W. G.; Shen, Hao
  • Journal of Materials Chemistry, Vol. 22, Issue 38
  • DOI: 10.1039/c2jm33404f

Solar Hydrogen Generation by a CdS-Au-TiO 2 Sandwich Nanorod Array Enhanced with Au Nanoparticle as Electron Relay and Plasmonic Photosensitizer
journal, May 2014

  • Li, Jiangtian; Cushing, Scott K.; Zheng, Peng
  • Journal of the American Chemical Society, Vol. 136, Issue 23
  • DOI: 10.1021/ja503508g

Fabrication of ZnO/CdS/Cu 2 ZnSnS 4 p–n heterostructure nanorod arrays via a solution-based route
journal, January 2013


Polar interface-induced improvement in high photocatalytic hydrogen evolution over ZnO–CdS heterostructures
journal, January 2011

  • Wang, Xuewen; Yin, Lichang; Liu, Gang
  • Energy & Environmental Science, Vol. 4, Issue 10
  • DOI: 10.1039/c0ee00723d

Photocatalytic generation of hydrogen by core-shell WO3/BiVO4 nanorods with ultimate water splitting efficiency
journal, June 2015

  • Pihosh, Yuriy; Turkevych, Ivan; Mawatari, Kazuma
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep11141

A silicon-based photocathode for water reduction with an epitaxial SrTiO3 protection layer and a nanostructured catalyst
journal, December 2014

  • Ji, Li; McDaniel, Martin D.; Wang, Shijun
  • Nature Nanotechnology, Vol. 10, Issue 1
  • DOI: 10.1038/nnano.2014.277

Efficient solar water-splitting using a nanocrystalline CoO photocatalyst
journal, December 2013


CuO/ZnO coupled oxide films obtained by the electrodeposition technique and their photocatalytic activity in phenol degradation under solar irradiation
journal, September 2013

  • Paz, Diego S.; Foletto, Edson L.; Bertuol, Daniel A.
  • Water Science and Technology, Vol. 68, Issue 5
  • DOI: 10.2166/wst.2013.345

Adsorption and solar light activity of transition-metal doped TiO2 nanoparticles as semiconductor photocatalyst
journal, July 2011

  • Khakpash, N.; Simchi, A.; Jafari, T.
  • Journal of Materials Science: Materials in Electronics, Vol. 23, Issue 3
  • DOI: 10.1007/s10854-011-0466-y

Visible-Light-Sensitive Photocatalysts: Nanocluster-Grafted Titanium Dioxide for Indoor Environmental Remediation
journal, December 2015

  • Miyauchi, Masahiro; Irie, Hiroshi; Liu, Min
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 1
  • DOI: 10.1021/acs.jpclett.5b02041

Titanium-Defected Undoped Anatase TiO 2 with p-Type Conductivity, Room-Temperature Ferromagnetism, and Remarkable Photocatalytic Performance
journal, February 2015

  • Wang, Songbo; Pan, Lun; Song, Jia-Jia
  • Journal of the American Chemical Society, Vol. 137, Issue 8
  • DOI: 10.1021/ja512047k

Synergistic Photocatalytic Degradation of Phenol Using Precious Metal Supported Titanium Dioxide with Hydrogen Peroxide
journal, March 2016

  • Tian, Fei; Zhu, Rongshu; Song, Kelin
  • Environmental Engineering Science, Vol. 33, Issue 3
  • DOI: 10.1089/ees.2014.0153

Photochemical splitting of water for hydrogen production by photocatalysis: A review
journal, September 2014


Mesoporous TiO2 modified with carbon quantum dots as a high-performance visible light photocatalyst
journal, July 2016


Titanium Dioxide Nanomaterials:  Synthesis, Properties, Modifications, and Applications
journal, July 2007

  • Chen, Xiaobo; Mao, Samuel S.
  • Chemical Reviews, Vol. 107, Issue 7
  • DOI: 10.1021/cr0500535

Mechanism of O 2 Production from Water Splitting: Nature of Charge Carriers in Nitrogen Doped Nanocrystalline TiO 2 Films and Factors Limiting O 2 Production
journal, February 2011

  • Tang, Junwang; Cowan, Alexander J.; Durrant, James R.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 7
  • DOI: 10.1021/jp1080093

C-, N-, S-, and Fe-Doped TiO 2 and SrTiO 3 Nanotubes for Visible-Light-Driven Photocatalytic Water Splitting: Prediction from First Principles
journal, July 2015

  • Piskunov, Sergei; Lisovski, Oleg; Begens, Jevgenijs
  • The Journal of Physical Chemistry C, Vol. 119, Issue 32
  • DOI: 10.1021/acs.jpcc.5b03691

Photocatalytic Activity Enhancing for Titanium Dioxide by Co-doping with Bromine and Chlorine
journal, March 2004

  • Luo, Hongmei; Takata, Tsuyoshi; Lee, Yungi
  • Chemistry of Materials, Vol. 16, Issue 5
  • DOI: 10.1021/cm035090w

Enhancing the photocatalytic properties of TiO2 by coupling with carbon nanotubes and supporting gold
journal, October 2012


Photocatalytic oxidation of benzene derivatives in aqueous suspensions: Synergic effect induced by the introduction of carbon nanotubes in a TiO2 matrix
journal, November 2010


New Insight for Enhanced Photocatalytic Activity of TiO 2 by Doping Carbon Nanotubes: A Case Study on Degradation of Benzene and Methyl Orange
journal, January 2010

  • Xu, Yi-Jun; Zhuang, Yangbin; Fu, Xianzhi
  • The Journal of Physical Chemistry C, Vol. 114, Issue 6
  • DOI: 10.1021/jp909855p

Review of one-dimensional and two-dimensional nanostructured materials for hydrogen generation
journal, January 2015

  • Babu, Veluru Jagadeesh; Vempati, Sesha; Uyar, Tamer
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 5
  • DOI: 10.1039/C4CP04245J

Semiconductor-based Photocatalytic Hydrogen Generation
journal, November 2010

  • Chen, Xiaobo; Shen, Shaohua; Guo, Liejin
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr1001645

Z-Scheme Water Splitting Using Two Different Semiconductor Photocatalysts
journal, June 2013


TiO 2 /BiVO 4 Nanowire Heterostructure Photoanodes Based on Type II Band Alignment
journal, February 2016


Effect of TiO2 polymorph and alcohol sacrificial agent on the activity of Au/TiO2 photocatalysts for H2 production in alcohol–water mixtures
journal, September 2015


Nanocomposite heterojunctions as sunlight-driven photocatalysts for hydrogen production from water splitting
journal, January 2015

  • Reza Gholipour, Mohammad; Dinh, Cao-Thang; Béland, François
  • Nanoscale, Vol. 7, Issue 18
  • DOI: 10.1039/C4NR07224C

On the role of metal particle size and surface coverage for photo-catalytic hydrogen production: A case study of the Au/CdS system
journal, March 2016


Comparative investigation on photocatalytic hydrogen evolution over Cu-, Pd-, and Au-loaded mesoporous TiO2 photocatalysts
journal, October 2005


Mechanisms and Applications of Plasmon-Induced Charge Separation at TiO 2 Films Loaded with Gold Nanoparticles
journal, May 2005

  • Tian, Yang; Tatsuma, Tetsu
  • Journal of the American Chemical Society, Vol. 127, Issue 20
  • DOI: 10.1021/ja042192u

Anisotropic Growth of TiO 2 onto Gold Nanorods for Plasmon-Enhanced Hydrogen Production from Water Reduction
journal, January 2016

  • Wu, Binghui; Liu, Deyu; Mubeen, Syed
  • Journal of the American Chemical Society, Vol. 138, Issue 4
  • DOI: 10.1021/jacs.5b11341

Metal Semiconductor Heterostructures for Photocatalytic Conversion of Light Energy
journal, March 2015

  • Dutta, Sumit Kumar; Mehetor, Shyamal Kumar; Pradhan, Narayan
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 6
  • DOI: 10.1021/acs.jpclett.5b00113

A Perspective on Mesoporous TiO 2 Materials
journal, July 2013

  • Li, Wei; Wu, Zhangxiong; Wang, Jinxiu
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm4014859

Mesoporous TiO 2 Single Crystals: Facile Shape-, Size-, and Phase-Controlled Growth and Efficient Photocatalytic Performance
journal, October 2013

  • Zheng, Xiaoli; Kuang, Qin; Yan, Keyou
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 21
  • DOI: 10.1021/am403482g

Synthesis of TiO2 nanowires and their photocatalytic activity for hydrogen evolution
journal, March 2008

  • Jitputti, Jaturong; Suzuki, Yoshikazu; Yoshikawa, Susumu
  • Catalysis Communications, Vol. 9, Issue 6, p. 1265-1271
  • DOI: 10.1016/j.catcom.2007.11.016

Electrospun TiO 2 Fiber Composite Photoelectrodes for Water Splitting
journal, November 2013

  • Regonini, D.; Teloeken, A. C.; Alves, A. K.
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 22
  • DOI: 10.1021/am403437q

Ag 6 Si 2 O 7 : a Silicate Photocatalyst for the Visible Region
journal, June 2014

  • Lou, Zaizhu; Huang, Baibiao; Wang, Zeyan
  • Chemistry of Materials, Vol. 26, Issue 13
  • DOI: 10.1021/cm500657n

Harnessing single-active plasmonic nanostructures for enhanced photocatalysis under visible light
journal, January 2015

  • Cheng, Hefeng; Fuku, Kojirou; Kuwahara, Yasutaka
  • Journal of Materials Chemistry A, Vol. 3, Issue 10
  • DOI: 10.1039/C4TA06484D

Au/TiO 2 Superstructure-Based Plasmonic Photocatalysts Exhibiting Efficient Charge Separation and Unprecedented Activity
journal, December 2013

  • Bian, Zhenfeng; Tachikawa, Takashi; Zhang, Peng
  • Journal of the American Chemical Society, Vol. 136, Issue 1
  • DOI: 10.1021/ja410994f

Panchromatic Photoproduction of H 2 with Surface Plasmons
journal, February 2015


The case for plasmon-derived hot carrier devices
journal, January 2015


A Fully Integrated Nanosystem of Semiconductor Nanowires for Direct Solar Water Splitting
journal, May 2013

  • Liu, Chong; Tang, Jinyao; Chen, Hao Ming
  • Nano Letters, Vol. 13, Issue 6
  • DOI: 10.1021/nl401615t

An autonomous photosynthetic device in which all charge carriers derive from surface plasmons
journal, February 2013

  • Mubeen, Syed; Lee, Joun; Singh, Nirala
  • Nature Nanotechnology, Vol. 8, Issue 4
  • DOI: 10.1038/nnano.2013.18

Spatially Mapping Energy Transfer from Single Plasmonic Particles to Semiconductor Substrates via STEM/EELS
journal, April 2015


Efficient Coupling of Solar Energy to Catalytic Hydrogenation by Using Well-Designed Palladium Nanostructures
journal, October 2014


Au nano dumbbells catalyzed the cutting of graphene oxide sheets upon plasmon-enhanced reduction
journal, January 2016

  • Wang, Xiaotian; Zhu, Mingyun; Fu, Wanlin
  • RSC Advances, Vol. 6, Issue 52
  • DOI: 10.1039/C6RA05888D

Pt–Au Triangular Nanoprisms with Strong Dipole Plasmon Resonance for Hydrogen Generation Studied by Single-Particle Spectroscopy
journal, May 2016


Functional Gold Nanorods: Synthesis, Self-Assembly, and Sensing Applications
journal, June 2012

  • Vigderman, Leonid; Khanal, Bishnu P.; Zubarev, Eugene R.
  • Advanced Materials, Vol. 24, Issue 36
  • DOI: 10.1002/adma.201201690

Facile synthesis of Ag nanocubes and Au nanocages
journal, September 2007


Tunable plasmons in atomically thin gold nanodisks
journal, March 2014

  • Manjavacas, A.; García de Abajo, F. J.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4548

Controlling the Edge Length of Gold Nanoprisms via a Seed-Mediated Approach
journal, June 2006

  • Millstone, J. E.; Métraux, G. S.; Mirkin, C. A.
  • Advanced Functional Materials, Vol. 16, Issue 9
  • DOI: 10.1002/adfm.200600066

Plasmon-Enhanced Formic Acid Dehydrogenation Using Anisotropic Pd–Au Nanorods Studied at the Single-Particle Level
journal, January 2015

  • Zheng, Zhaoke; Tachikawa, Takashi; Majima, Tetsuro
  • Journal of the American Chemical Society, Vol. 137, Issue 2
  • DOI: 10.1021/ja511719g

A combined scanning tunneling microscopy and electron energy loss spectroscopy study on the formation of thin, well-ordered β-Ga2O3 films on CoGa(001)
journal, March 1998

  • Schmitz, G.; Gassmann, P.; Franchy, R.
  • Journal of Applied Physics, Vol. 83, Issue 5
  • DOI: 10.1063/1.367014

Electronic structure of α-Al2O3: Ab initio simulations and comparison with experiment
journal, April 2007


Optical investigation of charge-transfer transitions in spinel Co3O4
journal, June 2003


The origin of the stereochemically active Pb(II) lone pair: DFT calculations on PbO and PbS
journal, May 2005


Electronic structures of rocksalt, litharge, and herzenbergite SnO by density functional theory
journal, December 2004


SnO films and their oxidation to SnO2: Raman scattering, IR reflectivity and X-ray diffraction studies
journal, November 1984


Some electrical properties of Bi2O3 thin films
journal, February 1978


Mesoporous bismuth titanate with visible-light photocatalytic activity
journal, January 2008

  • Kong, Lingdong; Chen, Haihan; Hua, Weiming
  • Chemical Communications, Issue 40
  • DOI: 10.1039/b808911f

Role of Sn 2+ in the Band Structure of SnM 2 O 6 and Sn 2 M 2 O 7 (M = Nb and Ta) and Their Photocatalytic Properties
journal, February 2008

  • Hosogi, Yasuhiro; Shimodaira, Yoshiki; Kato, Hideki
  • Chemistry of Materials, Vol. 20, Issue 4
  • DOI: 10.1021/cm071588c

Visible Light Induced Photoelectrochemical Properties of n-BiVO 4 and n-BiVO 4 /p-Co 3 O 4
journal, January 2008

  • Long, ; Kisch, Horst
  • The Journal of Physical Chemistry C, Vol. 112, Issue 2
  • DOI: 10.1021/jp075605x

Photoelectrochemical decomposition of water on nanocrystalline BiVO4 film electrodes under visible light
journal, January 2003

  • Sayama, Kazuhiro; Nomura, Atsushi; Zou, Zhigang
  • Chemical Communications, Issue 23
  • DOI: 10.1039/b310428a

α-Fe 2 O 3 as a photocatalytic material: A review
journal, June 2015


Continuous Representation of the Proton and Electron Kinetic Parameters in the pH–Potential Space for Water Oxidation on Hematite
journal, March 2015

  • Haghighat, Shima; Dawlaty, Jahan M.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 12
  • DOI: 10.1021/acs.jpcc.5b00053

An Optically Transparent Iron Nickel Oxide Catalyst for Solar Water Splitting
journal, July 2015

  • Morales-Guio, Carlos G.; Mayer, Matthew T.; Yella, Aswani
  • Journal of the American Chemical Society, Vol. 137, Issue 31
  • DOI: 10.1021/jacs.5b05544

Tuning The Photoactivity of Zirconia Nanotubes-Based Photoanodes via Ultrathin Layers of ZrN: An Effective Approach toward Visible-Light Water Splitting
journal, March 2016

  • Amer, Ahmad W.; El-Sayed, Mostafa A.; Allam, Nageh K.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 13
  • DOI: 10.1021/acs.jpcc.6b01144

WO 3 −Fe 2 O 3 Photoanodes for Water Splitting: A Host Scaffold, Guest Absorber Approach
journal, July 2009

  • Sivula, Kevin; Formal, Florian Le; Grätzel, Michael
  • Chemistry of Materials, Vol. 21, Issue 13
  • DOI: 10.1021/cm900565a

Efficient CoO nanowire array photocatalysts for H 2 generation
journal, October 2014

  • Zhan, Xueying; Wang, Zhenxing; Wang, Fengmei
  • Applied Physics Letters, Vol. 105, Issue 15
  • DOI: 10.1063/1.4898681

Size-Dependent Valence and Conduction Band-Edge Energies of Semiconductor Nanocrystals
journal, June 2011

  • Jasieniak, Jacek; Califano, Marco; Watkins, Scott E.
  • ACS Nano, Vol. 5, Issue 7
  • DOI: 10.1021/nn201681s

Time-Resolved Infrared Absorption Study of SrTiO 3 Photocatalysts Codoped with Rhodium and Antimony
journal, September 2013

  • Furuhashi, Koji; Jia, Qingxin; Kudo, Akihiko
  • The Journal of Physical Chemistry C, Vol. 117, Issue 37
  • DOI: 10.1021/jp407040p

Defect Engineering of Photocatalysts by Doping of Aliovalent Metal Cations for Efficient Water Splitting
journal, October 2009

  • Takata, Tsuyoshi; Domen, Kazunari
  • The Journal of Physical Chemistry C, Vol. 113, Issue 45
  • DOI: 10.1021/jp908621e

Organic-inorganic composite of g-C3N4–SrTiO3:Rh photocatalyst for improved H2 evolution under visible light irradiation
journal, August 2012


Ta 2 O 5 Nanowires: a novel synthetic method and their solar energy utilization
journal, January 2012

  • Lü, Xujie; Ding, Shangjun; Lin, Tianquan
  • Dalton Trans., Vol. 41, Issue 2
  • DOI: 10.1039/C1DT11124H

Well-dispersed mesoporous Ta2O5 submicrospheres: Enhanced photocatalytic activity by tuning heating rate at calcination
journal, August 2013


Superior H 2 production by hydrophilic ultrafine Ta 2 O 5 engineered covalently on graphene
journal, May 2014


Gray Ta 2 O 5 Nanowires with Greatly Enhanced Photocatalytic Performance
journal, December 2015

  • Zhu, Guilian; Lin, Tianquan; Cui, Houlei
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 1
  • DOI: 10.1021/acsami.5b07685

Carbon Nanotube/CdS Core–Shell Nanowires Prepared by a Simple Room-Temperature Chemical Reduction Method
journal, January 2004


Hollow Cobalt-Based Bimetallic Sulfide Polyhedra for Efficient All-pH-Value Electrochemical and Photocatalytic Hydrogen Evolution
journal, January 2016

  • Huang, Zhen-Feng; Song, Jiajia; Li, Ke
  • Journal of the American Chemical Society, Vol. 138, Issue 4
  • DOI: 10.1021/jacs.5b11986

Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting
journal, January 2014

  • Ran, Jingrun; Zhang, Jun; Yu, Jiaguo
  • Chem. Soc. Rev., Vol. 43, Issue 22
  • DOI: 10.1039/C3CS60425J

Core/Shell Semiconductor Nanocrystals
journal, January 2009


Noble Metal-Free Reduced Graphene Oxide-Zn x Cd 1– x S Nanocomposite with Enhanced Solar Photocatalytic H 2 -Production Performance
journal, January 2012

  • Zhang, Jun; Yu, Jiaguo; Jaroniec, Mietek
  • Nano Letters, Vol. 12, Issue 9
  • DOI: 10.1021/nl301831h

Cadmium Sulfide Quantum Dots Supported on Gallium and Indium Oxide for Visible-Light-Driven Hydrogen Evolution from Water
journal, July 2014


Stable photocatalytic hydrogen evolution from water over ZnO–CdS core–shell nanorods
journal, August 2010


Efficient visible-light-driven photocatalytic hydrogen production using CdS@TaON core–shell composites coupled with graphene oxide nanosheets
journal, January 2012

  • Hou, Jungang; Wang, Zheng; Kan, Wenbin
  • Journal of Materials Chemistry, Vol. 22, Issue 15
  • DOI: 10.1039/c2jm15791h

Graphene–inorganic nanocomposites
journal, January 2012


Au plasmonics in a WS 2 -Au-CuInS 2 photocatalyst for significantly enhanced hydrogen generation
journal, November 2015

  • Cheng, Zhongzhou; Wang, Zhenxing; Shifa, Tofik Ahmed
  • Applied Physics Letters, Vol. 107, Issue 22
  • DOI: 10.1063/1.4937008

Highly Efficient Water Splitting into H 2 and O 2 over Lanthanum-Doped NaTaO 3 Photocatalysts with High Crystallinity and Surface Nanostructure
journal, March 2003

  • Kato, Hideki; Asakura, Kiyotaka; Kudo, Akihiko
  • Journal of the American Chemical Society, Vol. 125, Issue 10
  • DOI: 10.1021/ja027751g

GaN:ZnO Solid Solution as a Photocatalyst for Visible-Light-Driven Overall Water Splitting
journal, June 2005

  • Maeda, Kazuhiko; Takata, Tsuyoshi; Hara, Michikazu
  • Journal of the American Chemical Society, Vol. 127, Issue 23
  • DOI: 10.1021/ja0518777

Template-free synthesis of Ta3N5 nanorod arrays for efficient photoelectrochemical water splitting
journal, January 2013

  • Zhen, Chao; Wang, Lianzhou; Liu, Gang
  • Chemical Communications, Vol. 49, Issue 29
  • DOI: 10.1039/c3cc40760h

Mg–Zr Cosubstituted Ta 3 N 5 Photoanode for Lower-Onset-Potential Solar-Driven Photoelectrochemical Water Splitting
journal, September 2015

  • Seo, Jeongsuk; Takata, Tsuyoshi; Nakabayashi, Mamiko
  • Journal of the American Chemical Society, Vol. 137, Issue 40
  • DOI: 10.1021/jacs.5b08329

A metal-free polymeric photocatalyst for hydrogen production from water under visible light
journal, November 2008

  • Wang, Xinchen; Maeda, Kazuhiko; Thomas, Arne
  • Nature Materials, Vol. 8, Issue 1
  • DOI: 10.1038/nmat2317

Iodine Modified Carbon Nitride Semiconductors as Visible Light Photocatalysts for Hydrogen Evolution
journal, October 2013


Synthesis of Transition Metal-Modified Carbon Nitride Polymers for Selective Hydrocarbon Oxidation
journal, September 2010


Two-dimensional covalent carbon nitride nanosheets: synthesis, functionalization, and applications
journal, January 2015

  • Zhang, Jinshui; Chen, Yan; Wang, Xinchen
  • Energy & Environmental Science, Vol. 8, Issue 11
  • DOI: 10.1039/C5EE01895A

Visible Light-Driven Pure Water Splitting by a Nature-Inspired Organic Semiconductor-Based System
journal, August 2014

  • Martin, David James; Reardon, Philip James Thomas; Moniz, Savio J. A.
  • Journal of the American Chemical Society, Vol. 136, Issue 36
  • DOI: 10.1021/ja506386e

Synthesis and efficient visible light photocatalytic H2 evolution of a metal-free g-C3N4/graphene quantum dots hybrid photocatalyst
journal, September 2016


Visible-light activation of TiO2 photocatalysts: Advances in theory and experiments
journal, December 2015

  • Etacheri, Vinodkumar; Di Valentin, Cristiana; Schneider, Jenny
  • Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 25
  • DOI: 10.1016/j.jphotochemrev.2015.08.003

Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers
journal, December 2005

  • Nazeeruddin, Mohammad K.; De Angelis, Filippo; Fantacci, Simona
  • Journal of the American Chemical Society, Vol. 127, Issue 48
  • DOI: 10.1021/ja052467l

Density functional theory study on electron and hole transport properties of organic pentacene derivatives with electron-withdrawing substituent
journal, August 2011

  • Chai, Shuo; Wen, Shu-Hao; Huang, Jin-Dou
  • Journal of Computational Chemistry, Vol. 32, Issue 15
  • DOI: 10.1002/jcc.21904

Alignment of the dye’s molecular levels with the TiO 2 band edges in dye-sensitized solar cells: a DFT–TDDFT study
journal, September 2008


Complex redox chemistry on the RuO2() surface: experiment and theory
journal, May 2002


Transient Structures and Kinetics of the Ferrioxalate Redox Reaction Studied by Time-Resolved EXAFS, Optical Spectroscopy, and DFT
journal, September 2007

  • Chen, Jie; Zhang, Hua; Tomov, Ivan V.
  • The Journal of Physical Chemistry A, Vol. 111, Issue 38
  • DOI: 10.1021/jp0733466

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965


Inhomogeneous Electron Gas
journal, November 1964


Perspective on density functional theory
journal, April 2012

  • Burke, Kieron
  • The Journal of Chemical Physics, Vol. 136, Issue 15
  • DOI: 10.1063/1.4704546

Reproducibility in density functional theory calculations of solids
journal, March 2016


Band widths and gaps from the Tran-Blaha functional: Comparison with many-body perturbation theory
journal, February 2013


A simple effective potential for exchange
journal, June 2006

  • Becke, Axel D.; Johnson, Erin R.
  • The Journal of Chemical Physics, Vol. 124, Issue 22
  • DOI: 10.1063/1.2213970

Accurate Band Gaps of Semiconductors and Insulators with a Semilocal Exchange-Correlation Potential
journal, June 2009


Density Functional Theory and Beyond for Band-Gap Screening: Performance for Transition-Metal Oxides and Dichalcogenides
journal, June 2013

  • Li, Wenqing; Walther, Christian F. J.; Kuc, Agnieszka
  • Journal of Chemical Theory and Computation, Vol. 9, Issue 7
  • DOI: 10.1021/ct400235w

A Theoretical Study on the Mechanism of Photocatalytic Oxygen Evolution on BiVO 4 in Aqueous Solution
journal, December 2012

  • Yang , Jingxiu; Wang , Donge; Zhou, Xin
  • Chemistry - A European Journal, Vol. 19, Issue 4
  • DOI: 10.1002/chem.201202365

Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4
journal, February 2013

  • Li, Rengui; Zhang, Fuxiang; Wang, Donge
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2401

Mapping Quantum Yield for (Fe–Zn–Sn–Ti)O x Photoabsorbers Using a High Throughput Photoelectrochemical Screening System
journal, February 2014

  • Xiang, Chengxiang; Haber, Joel; Marcin, Martin
  • ACS Combinatorial Science, Vol. 16, Issue 3
  • DOI: 10.1021/co400081w

Screening procedure for structurally and electronically matched contact layers for high-performance solar cells: hybrid perovskites
journal, January 2016

  • Butler, Keith T.; Kumagai, Yu; Oba, Fumiyasu
  • Journal of Materials Chemistry C, Vol. 4, Issue 6
  • DOI: 10.1039/C5TC04091D

First principles high throughput screening of oxynitrides for water-splitting photocatalysts
journal, January 2013

  • Wu, Yabi; Lazic, Predrag; Hautier, Geoffroy
  • Energy Environ. Sci., Vol. 6, Issue 1
  • DOI: 10.1039/C2EE23482C

An atlas of two-dimensional materials
journal, January 2014

  • Miró, Pere; Audiffred, Martha; Heine, Thomas
  • Chem. Soc. Rev., Vol. 43, Issue 18
  • DOI: 10.1039/C4CS00102H

Unique 3D heterojunction photoanode design to harness charge transfer for efficient and stable photoelectrochemical water splitting
journal, January 2015

  • Hou, Jungang; Cheng, Huijie; Takeda, Osamu
  • Energy & Environmental Science, Vol. 8, Issue 4
  • DOI: 10.1039/C4EE03707C

Semiconductor Photocatalysis — Past, Present, and Future Outlook
journal, February 2012

  • Serpone, N.; Emeline, A. V.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 5
  • DOI: 10.1021/jz300071j

    Works referencing / citing this record:

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