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Reactive sintering of ceramic lithium ion electrolyte membranes

Patent ·
OSTI ID:1361420
Disclosed herein are methods for making a solid lithium ion electrolyte membrane, the methods comprising combining a first reactant chosen from amorphous, glassy, or low melting temperature solid reactants with a second reactant chosen from refractory oxides to form a mixture; heating the mixture to a first temperature to form a homogenized composite, wherein the first temperature is between a glass transition temperature of the first reactant and a crystallization onset temperature of the mixture; milling the homogenized composite to form homogenized particles; casting the homogenized particles to form a green body; and sintering the green body at a second temperature to form a solid membrane. Solid lithium ion electrolyte membranes manufactured according to these methods are also disclosed herein.
Research Organization:
Corning Incorporated, Corning, NY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
EE0005757
Assignee:
Corning Incorporated
Patent Number(s):
9,673,483
Application Number:
14/599,692
OSTI ID:
1361420
Country of Publication:
United States
Language:
English

References (1)

Superionic Conductivity in a Lithium Aluminum Germanium Phosphate Glass–Ceramic journal January 2008