Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I)

Schliesser, Jacob; Lilova, Kristina; Pierce, Eric M.; Wu, Lili; Missimer, David M.; Woodfield, Brian F.; Navrotsky, Alexandra

doi:10.1016/j.jct.2017.05.035

Title: Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na₈Al₆Si₆O₂₄X₂ (X = SO₄, ReO₄, Cl, I)

Journal Article · Thu Jun 01 00:00:00 EDT 2017 · Journal of Chemical Thermodynamics

DOI:https://doi.org/10.1016/j.jct.2017.05.035· OSTI ID:1361348

Schliesser, Jacob ^[1]; Lilova, Kristina ^[2]; Pierce, Eric M. ^[3]; Wu, Lili ^[2]; Missimer, David M. ^[4]; Woodfield, Brian F. ^[1]; Navrotsky, Alexandra ^[2]

Brigham Young Univ., Provo, UT (United States)
Univ. of California, Davis, CA (United States). Peter A. Rock Thermochemistry Lab.
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

Heat capacities of sulfate, perrhenate, chloride, and iodide sodalites with the ideal formula Na₈Al₆Si₆O₂₄X₂ (X = SO₄, ReO₄, Cl, I) were measured from 2 K to 300 K using a Quantum Design Physical Property Measurement System (PPMS). From the heat capacity data, the standard thermodynamic functions were determined. All four sodalites undergo a phase transition below room temperature for which thermodynamic parameters were determined. Additionally, the heat capacity of one of the constituent compounds (NaReO₄) was measured.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE Office of Environmental Management (EM)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1361348

Alternate ID(s):: OSTI ID: 1550146

Journal Information:: Journal of Chemical Thermodynamics, Vol. 114; ISSN 0021-9614

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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Title: Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na8Al6Si6O24X2 (X = SO4, ReO4, Cl, I)

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Title: Low temperature heat capacity and thermodynamic functions of anion bearing sodalites Na₈Al₆Si₆O₂₄X₂ (X = SO₄, ReO₄, Cl, I)