Hybrid excitations due to crystal field, spin-orbit coupling, and spin waves in LiFePO4

Yiu, Yuen; Le, Manh Duc; Toft-Peterson, Rasmus; Ehlers, Georg; McQueeney, Robert J.; Vaknin, David

doi:10.1103/PhysRevB.95.104409

Title: Hybrid excitations due to crystal field, spin-orbit coupling, and spin waves in ${LiFePO}_{4}$

Journal Article · Thu Mar 09 00:00:00 EST 2017 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.95.104409· OSTI ID:1355753

Yiu, Yuen ^[1]; Le, Manh Duc ^[2]; Toft-Peterson, Rasmus ^[3]; Ehlers, Georg ^[4]; McQueeney, Robert J. ^[1]; Vaknin, David ^[1]

Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering (DMSE)
Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Rutherford Appleton Lab., ISIS Neutron Source
Helmholtz-Zentrum Berlin (HZB), (Germany). German Research Centre for Materials and Energy
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division

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Research Organization:: Ames Lab., Ames, IA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358; AC05-00OR22725

OSTI ID:: 1355753

Alternate ID(s):: OSTI ID: 1346433; OSTI ID: 1361313

Report Number(s):: IS-J 9306; PRBMDO; TRN: US1702604

Journal Information:: Physical Review B, Vol. 95, Issue 10; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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References (34)

Electronic structure and half-metallic transport in the ${La}_{1 - x}$ ${Ca}_{x}$ ${MnO}_{3}$ system Pickett, Warren E.; Singh, David J. Physical Review B, Vol. 53, Issue 3 https://doi.org/10.1103/PhysRevB.53.1146	journal	January 1996
Inelastic neutron scattering study of crystal field excitations of ${Nd}^{3 +}$ in NdFeAsO Xiao, Y.; Zbiri, M.; Downie, R. A. Physical Review B, Vol. 88, Issue 21 https://doi.org/10.1103/PhysRevB.88.214419	journal	December 2013
Magnetic excitations in the antiferromagnetic phase of NdCu 2 Rotter, M.; Kramp, S.; Loewenhaupt, M. Applied Physics A: Materials Science & Processing, Vol. 74, Issue 0 https://doi.org/10.1007/s003390201358	journal	December 2002
Outline of neutron scattering formalism Berk, N. F. Journal of Research of the National Institute of Standards and Technology, Vol. 98, Issue 1 https://doi.org/10.6028/jres.098.002	journal	January 1993
Li Ion Diffusion Mechanisms in LiFePO ₄ : An ab Initio Molecular Dynamics Study Yang, Jianjun; Tse, John S. The Journal of Physical Chemistry A, Vol. 115, Issue 45 https://doi.org/10.1021/jp205057d	journal	November 2011
Lithium ion conductivity in single crystal LiFePO4 Li, J.; Yao, W.; Martin, S. Solid State Ionics, Vol. 179, Issue 35-36 https://doi.org/10.1016/j.ssi.2008.06.028	journal	October 2008
Electronically conductive phospho-olivines as lithium storage electrodes Chung, Sung-Yoon; Bloking, Jason T.; Chiang, Yet-Ming Nature Materials, Vol. 1, Issue 2, p. 123-128 https://doi.org/10.1038/nmat732	journal	September 2002
Using McPhase to calculate magnetic phase diagrams of rare earth compounds Rotter, M. Journal of Magnetism and Magnetic Materials, Vol. 272-276 https://doi.org/10.1016/j.jmmm.2003.12.1394	journal	May 2004
Magnetic Structures of the Triphylite LiFePO ₄ and of Its Delithiated Form FePO ₄ Rousse, G.; Rodriguez-Carvajal, J.; Patoux, S. Chemistry of Materials, Vol. 15, Issue 21 https://doi.org/10.1021/cm0300462	journal	October 2003
Magnetic phase diagram of magnetoelectric LiMnPO $_{4}$ Toft-Petersen, Rasmus; Andersen, Niels H.; Li, Haifeng Physical Review B, Vol. 85, Issue 22 https://doi.org/10.1103/PhysRevB.85.224415	journal	June 2012
Weakly coupled antiferromagnetic planes in single-crystal ${LiCoPO}_{4}$ Vaknin, D.; Zarestky, J. L.; Miller, L. L. Physical Review B, Vol. 65, Issue 22 https://doi.org/10.1103/PhysRevB.65.224414	journal	May 2002
Experimental visualization of lithium diffusion in LixFePO4 Nishimura, Shin-ichi; Kobayashi, Genki; Ohoyama, Kenji Nature Materials, Vol. 7, Issue 9 https://doi.org/10.1038/nmat2251	journal	August 2008
Field-induced magnetic phases and electric polarization in ${LiNiPO}_{4}$ Jensen, Thomas Bagger Stibius; Christensen, Niels Bech; Kenzelmann, Michel Physical Review B, Vol. 79, Issue 9 https://doi.org/10.1103/PhysRevB.79.092412	journal	March 2009
Magnetic properties of lithium intercalation compounds Julien, C. M.; Ait-Salah, A.; Mauger, A. Ionics, Vol. 12, Issue 1 https://doi.org/10.1007/s11581-006-0007-5	journal	April 2006
Anomalous magnetic structure and spin dynamics in magnetoelectric ${LiFePO}_{4}$ Toft-Petersen, Rasmus; Reehuis, Manfred; Jensen, Thomas B. S. Physical Review B, Vol. 92, Issue 2 https://doi.org/10.1103/PhysRevB.92.024404	journal	July 2015
Search for the piezomagnetoelectric effect in LiCoPO ₄ Rivera, J. -P.; Schmid, H. Ferroelectrics, Vol. 161, Issue 1 https://doi.org/10.1080/00150199408213357	journal	November 1994
High-field magnetic phase transitions and spin excitations in magnetoelectric LiNiPO $_{4}$ Toft-Petersen, Rasmus; Jensen, Jens; Jensen, Thomas Bagger Stibius Physical Review B, Vol. 84, Issue 5 https://doi.org/10.1103/PhysRevB.84.054408	journal	August 2011
Anisotropy in magnetic properties and electronic structure of single-crystal $Li Fe P O_{4}$ Liang, Gan; Park, Keeseong; Li, Jiying Physical Review B, Vol. 77, Issue 6 https://doi.org/10.1103/PhysRevB.77.064414	journal	February 2008
Spin-waves in antiferromagnetic single-crystal $Li Fe P O_{4}$ Li, Jiying; Garlea, Vasile O.; Zarestky, Jerel L. Physical Review B, Vol. 73, Issue 2 https://doi.org/10.1103/PhysRevB.73.024410	journal	January 2006
Dynamical matrix diagonalization for the calculation of dispersive excitations Rotter, Martin; Le, Manh Duc; Boothroyd, Andrew T. Journal of Physics: Condensed Matter, Vol. 24, Issue 21 https://doi.org/10.1088/0953-8984/24/21/213201	journal	May 2012
Magnetism and its microscopic origin in iron-based high-temperature superconductors Dai, Pengcheng; Hu, Jiangping; Dagotto, Elbio Nature Physics, Vol. 8, Issue 10 https://doi.org/10.1038/nphys2438	journal	October 2012
Multiferroic magnetoelectric composites: Historical perspective, status, and future directions Nan, Ce-Wen; Bichurin, M. I.; Dong, Shuxiang Journal of Applied Physics, Vol. 103, Issue 3 https://doi.org/10.1063/1.2836410	journal	February 2008
Colossal magnetoresistance Ramirez, A. P. Journal of Physics: Condensed Matter, Vol. 9, Issue 39 https://doi.org/10.1088/0953-8984/9/39/005	journal	September 1997
A review of conduction phenomena in Li-ion batteries Park, Myounggu; Zhang, Xiangchun; Chung, Myoungdo Journal of Power Sources, Vol. 195, Issue 24 https://doi.org/10.1016/j.jpowsour.2010.06.060	journal	December 2010
Spin dynamics in the magnetoelectric effect compound ${LiCoPO}_{4}$ Tian, Wei; Li, Jiying; Lynn, Jeffrey W. Physical Review B, Vol. 78, Issue 18 https://doi.org/10.1103/PhysRevB.78.184429	journal	November 2008
The linear magnetoelectric effect in LiCoPO ₄ Revisited Rivera, J. -P. Ferroelectrics, Vol. 161, Issue 1 https://doi.org/10.1080/00150199408213364	journal	November 1994
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries Padhi, A. K. Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194 https://doi.org/10.1149/1.1837571	journal	April 1997
Spin Current and Magnetoelectric Effect in Noncollinear Magnets Katsura, Hosho; Nagaosa, Naoto; Balatsky, Alexander V. Physical Review Letters, Vol. 95, Issue 5 https://doi.org/10.1103/PhysRevLett.95.057205	journal	July 2005
Antiferromagnetism in LiFePO4 Santoro, R. P.; Newnham, R. E. Acta Crystallographica, Vol. 22, Issue 3 https://doi.org/10.1107/S0365110X67000672	journal	March 1967
The cold neutron chopper spectrometer at the Spallation Neutron Source—A review of the first 8 years of operation Ehlers, G.; Podlesnyak, A. A.; Kolesnikov, A. I. Review of Scientific Instruments, Vol. 87, Issue 9 https://doi.org/10.1063/1.4962024	journal	September 2016
A spectacularly reactive cathode Thomas, Josh Nature Materials, Vol. 2, Issue 11 https://doi.org/10.1038/nmat1010	journal	November 2003
Horace : Software for the analysis of data from single crystal spectroscopy experiments at time-of-flight neutron instruments Ewings, R. A.; Buts, A.; Le, M. D. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 834 https://doi.org/10.1016/j.nima.2016.07.036	journal	October 2016
The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides Johnston, David C. Advances in Physics, Vol. 59, Issue 6 https://doi.org/10.1080/00018732.2010.513480	journal	October 2010
Spin-orbit coupling in the first and second transition series Dunn, T. M. Transactions of the Faraday Society, Vol. 57 https://doi.org/10.1039/tf9615701441	journal	January 1961

Cited By (1)

High magnetic field phase diagram and failure of the magnetic Grüneisen scaling in ${LiFePO}_{4}$ Werner, J.; Sauerland, S.; Koo, C. Physical Review B, Vol. 99, Issue 21 https://doi.org/10.1103/physrevb.99.214432	journal	June 2019