K-Ion Batteries Based on a P2-Type K0.6CoO2 Cathode

Kim, Haegyeom; Kim, Jae Chul; Bo, Shou-Hang; Shi, Tan; Kwon, Deok-Hwang; Ceder, Gerbrand

doi:10.1002/aenm.201700098

Title: K-Ion Batteries Based on a P2-Type K_0.6CoO₂ Cathode

Journal Article · Sat Apr 01 00:00:00 EDT 2017 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201700098· OSTI ID:1361219

Kim, Haegyeom ^[1]; Kim, Jae Chul ^[1]; Bo, Shou-Hang ^[1]; Shi, Tan ^[2]; Kwon, Deok-Hwang ^[2]; Ceder, Gerbrand ^[2]

Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley CA 94720 USA
Department of Materials Science and Engineering, University of California, Berkeley CA 94720 USA

K‐ion batteries are a potentially exciting and new energy storage technology that can combine high specific energy, cycle life, and good power capability, all while using abundant potassium resources. The discovery of novel cathodes is a critical step toward realizing K‐ion batteries (KIBs). In this work, a layered P2‐type K _0.6 CoO ₂ cathode is developed and highly reversible K ion intercalation is demonstrated. In situ X‐ray diffraction combined with electrochemical titration reveals that P2‐type K _0.6 CoO ₂ can store and release a considerable amount of K ions via a topotactic reaction. Despite the large amount of phase transitions as function of K content, the cathode operates highly reversibly and with good rate capability. The practical feasibility of KIBs is further demonstrated by constructing full cells with a graphite anode. This work highlights the potential of KIBs as viable alternatives for Li‐ion and Na‐ion batteries and provides new insights and directions for the development of next‐generation energy storage systems.

View Journal Article

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; DE‐AC02‐05CH11231

OSTI ID:: 1361219

Alternate ID(s):: OSTI ID: 1361220; OSTI ID: 1437001

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 230 works

Citation information provided by
Web of Science

References (39)

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Layered-to-Rock-Salt Transformation in Desodiated Na _x CrO ₂ ( x 0.4) Bo, Shou-Hang; Li, Xin; Toumar, Alexandra J. Chemistry of Materials, Vol. 28, Issue 5 https://doi.org/10.1021/acs.chemmater.5b04626	journal	February 2016
Poly(anthraquinonyl sulfide) cathode for potassium-ion batteries Jian, Zelang; Liang, Yanliang; Rodríguez-Pérez, Ismael A. Electrochemistry Communications, Vol. 71 https://doi.org/10.1016/j.elecom.2016.07.011	journal	October 2016
Electrochemical investigation of the P2–NaxCoO2 phase diagram Berthelot, R.; Carlier, D.; Delmas, C. Nature Materials, Vol. 10, Issue 1 https://doi.org/10.1038/nmat2920	journal	December 2010
Amorphous iron phosphate: potential host for various charge carrier ions Mathew, Vinod; Kim, Sungjin; Kang, Jungwon NPG Asia Materials, Vol. 6, Issue 10 https://doi.org/10.1038/am.2014.98	journal	October 2014
Non-Aqueous K-Ion Battery Based on Layered K _0.3 MnO ₂ and Hard Carbon/Carbon Black Vaalma, Christoph; Giffin, Guinevere A.; Buchholz, Daniel Journal of The Electrochemical Society, Vol. 163, Issue 7 https://doi.org/10.1149/2.0921607jes	journal	January 2016
Nanocubic KTi ₂ (PO ₄ ) ₃ electrodes for potassium-ion batteries Han, Jin; Niu, Yubin; Bao, Shu-juan Chemical Communications, Vol. 52, Issue 78 https://doi.org/10.1039/C6CC06177J	journal	January 2016
Insights into Diffusion Mechanisms in P2 Layered Oxide Materials by First-Principles Calculations Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand Chemistry of Materials, Vol. 26, Issue 18 https://doi.org/10.1021/cm501563f	journal	September 2014
K ₂ Ti ₄ O ₉ : A Promising Anode Material for Potassium Ion Batteries Kishore, Brij; G., Venkatesh; Munichandraiah, N. Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0421613jes	journal	January 2016
Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P. Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0201514jes	journal	January 2015
Potassium Secondary Batteries Eftekhari, Ali; Jian, Zelang; Ji, Xiulei ACS Applied Materials & Interfaces, Vol. 9, Issue 5 https://doi.org/10.1021/acsami.6b07989	journal	October 2016
Understanding sodium-ion diffusion in layered P2 and P3 oxides via experiments and first-principles calculations: a bridge between crystal structure and electrochemical performance Guo, Shaohua; Sun, Yang; Yi, Jin NPG Asia Materials, Vol. 8, Issue 4 https://doi.org/10.1038/am.2016.53	journal	April 2016
Tin-based composite anodes for potassium-ion batteries Sultana, Irin; Ramireddy, Thrinathreddy; Rahman, Md Mokhlesur Chemical Communications, Vol. 52, Issue 59 https://doi.org/10.1039/C6CC03649J	journal	January 2016
Study on the Reversible Electrode Reaction of Na _{1– x} Ni _0.5 Mn _0.5 O ₂ for a Rechargeable Sodium-Ion Battery Komaba, Shinichi; Yabuuchi, Naoaki; Nakayama, Tetsuri Inorganic Chemistry, Vol. 51, Issue 11 https://doi.org/10.1021/ic300357d	journal	May 2012
A Layered P2- and O3-Type Composite as a High-Energy Cathode for Rechargeable Sodium-Ion Batteries Guo, Shaohua; Liu, Pan; Yu, Haijun Angewandte Chemie, Vol. 127, Issue 20 https://doi.org/10.1002/ange.201411788	journal	April 2015
Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries Zhou, Yong-Ning; Ma, Jun; Hu, Enyuan Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6381	journal	November 2014
Thermodynamic functions of transfer of single ions from water to nonaqueous and mixed solvents: Part 3 - Standard potentials of selected electrodes Marcus, Y. Pure and Applied Chemistry, Vol. 57, Issue 8 https://doi.org/10.1351/pac198557081129	journal	January 1985
Layered lithium transition metal oxide cathodes towards high energy lithium-ion batteries He, Ping; Yu, Haijun; Li, De Journal of Materials Chemistry, Vol. 22, Issue 9 https://doi.org/10.1039/c2jm14305d	journal	January 2012
Exploration of K ₂ Ti ₈ O ₁₇ as an anode material for potassium-ion batteries Han, Jin; Xu, Maowen; Niu, Yubin Chemical Communications, Vol. 52, Issue 75 https://doi.org/10.1039/C6CC05102B	journal	January 2016
Oxocarbon Salts for Fast Rechargeable Batteries Zhao, Qing; Wang, Jianbin; Lu, Yong Angewandte Chemie, Vol. 128, Issue 40 https://doi.org/10.1002/ange.201607194	journal	September 2016
Recent Progress in Electrode Materials for Sodium-Ion Batteries Kim, Hyungsub; Kim, Haegyeom; Ding, Zhang Advanced Energy Materials, Vol. 6, Issue 19 https://doi.org/10.1002/aenm.201600943	journal	July 2016
Direct Synthesis of Few-Layer F-Doped Graphene Foam and Its Lithium/Potassium Storage Properties Ju, Zhicheng; Zhang, Shuai; Xing, Zheng ACS Applied Materials & Interfaces, Vol. 8, Issue 32 https://doi.org/10.1021/acsami.6b04763	journal	August 2016
Magnetic nature of $K_{x} Co O_{2}$ near the antiferromagnetic phase with $x = 0.5$ : Positive muon spin rotation and relaxation Sugiyama, Jun; Ikedo, Yutaka; Russo, Peter L. Physical Review B, Vol. 76, Issue 10 https://doi.org/10.1103/PhysRevB.76.104412	journal	September 2007
First-principles investigation of phase stability in ${Li}_{x} {CoO}_{2}$ Van der Ven, A.; Aydinol, M. K.; Ceder, G. Physical Review B, Vol. 58, Issue 6 https://doi.org/10.1103/PhysRevB.58.2975	journal	August 1998
Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
Layered P2/O3 Intergrowth Cathode: Toward High Power Na-Ion Batteries Lee, Eungje; Lu, Jun; Ren, Yang Advanced Energy Materials, Vol. 4, Issue 17 https://doi.org/10.1002/aenm.201400458	journal	July 2014
Potassium secondary cell based on Prussian blue cathode Eftekhari, Ali Journal of Power Sources, Vol. 126, Issue 1-2, p. 221-228 https://doi.org/10.1016/j.jpowsour.2003.08.007	journal	February 2004
A comparative study of graphite electrodes using the co-intercalation phenomenon for rechargeable Li, Na and K batteries Kim, Haegyeom; Yoon, Gabin; Lim, Kyungmi Chemical Communications, Vol. 52, Issue 85 https://doi.org/10.1039/C6CC05362A	journal	January 2016
Durable potassium ion battery electrodes from high-rate cointercalation into graphitic carbons Cohn, Adam P.; Muralidharan, Nitin; Carter, Rachel Journal of Materials Chemistry A, Vol. 4, Issue 39 https://doi.org/10.1039/C6TA06797B	journal	January 2016
Electrochemical properties of P2-phase Na0.74CoO2 compounds as cathode material for rechargeable sodium-ion batteries Ding, J. J.; Zhou, Y. N.; Sun, Q. Electrochimica Acta, Vol. 87 https://doi.org/10.1016/j.electacta.2012.09.058	journal	January 2013
Carbon Electrodes for K-Ion Batteries Jian, Zelang; Luo, Wei; Ji, Xiulei Journal of the American Chemical Society, Vol. 137, Issue 36 https://doi.org/10.1021/jacs.5b06809	journal	September 2015
Role of Nitrogen-Doped Graphene for Improved High-Capacity Potassium Ion Battery Anodes Share, Keith; Cohn, Adam P.; Carter, Rachel ACS Nano, Vol. 10, Issue 10 https://doi.org/10.1021/acsnano.6b05998	journal	October 2016
Organic electrode for non-aqueous potassium-ion batteries Chen, Yanan; Luo, Wei; Carter, Marcus Nano Energy, Vol. 18 https://doi.org/10.1016/j.nanoen.2015.10.015	journal	November 2015
Electrochemical Intercalation of Potassium into Graphite Zhao, Jin; Zou, Xiaoxi; Zhu, Yujie Advanced Functional Materials, Vol. 26, Issue 44 https://doi.org/10.1002/adfm.201602248	journal	September 2016
Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries Hwang, Jang-Yeon; Oh, Seung-Min; Myung, Seung-Taek Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7865	journal	April 2015
Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors Komaba, Shinichi; Hasegawa, Tatsuya; Dahbi, Mouad Electrochemistry Communications, Vol. 60 https://doi.org/10.1016/j.elecom.2015.09.002	journal	November 2015
Hard Carbon Microspheres: Potassium-Ion Anode Versus Sodium-Ion Anode Jian, Zelang; Xing, Zhenyu; Bommier, Clement Advanced Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1002/aenm.201501874	journal	November 2015
Potassium Ion Batteries with Graphitic Materials Luo, Wei; Wan, Jiayu; Ozdemir, Burak Nano Letters, Vol. 15, Issue 11 https://doi.org/10.1021/acs.nanolett.5b03667	journal	October 2015
Structure and Properties of Alkali Cobalt Double Oxides A _0.6 CoO ₂ (A = Li, Na, and K) Pollet, Michaël; Blangero, Maxime; Doumerc, Jean-Pierre Inorganic Chemistry, Vol. 48, Issue 20 https://doi.org/10.1021/ic900386q	journal	October 2009

Similar Records

Self-Templated Formation of P2-type K_0.6CoO₂ Microspheres for High Reversible Potassium-Ion Batteries

Journal Article · Tue Jan 02 00:00:00 EST 2018 · Nano Letters · OSTI ID:1361219

Deng, Tao; Fan, Xiulin; Luo, Chao; +6 more

Layered P2‐Type K _0.65 Fe _0.5 Mn _0.5 O ₂ Microspheres as Superior Cathode for High‐Energy Potassium‐Ion Batteries

Journal Article · Wed May 30 00:00:00 EDT 2018 · Advanced Functional Materials · OSTI ID:1361219

Deng, Tao; Fan, Xiulin; Chen, Ji; +6 more

Oxygen redox chemistry in P2-Na_0.6Li_0.11Fe_0.27Mn_0.62O₂ cathode for high-energy Na-ion batteries

Journal Article · Fri Jan 01 00:00:00 EST 2021 · Journal of Materials Chemistry. A · OSTI ID:1361219

Cao, Ming-Hui; Li, Ren-Yan; Lin, Shi-Ya; +7 more

Related Subjects

25 ENERGY STORAGE

Title: K-Ion Batteries Based on a P2-Type K0.6CoO2 Cathode

Citation Formats

References (39)

Similar Records

Related Subjects

Title: K-Ion Batteries Based on a P2-Type K_0.6CoO₂ Cathode